NITROGEN PARTITIONING AND ISOTOPIC FRACTIONATION IN GRANITIC ROCKS AND MINERALS: A CASE STUDY OF THE DEVONIAN LOCH DOON PLUTON, SW SCOTLAND

2020 ◽  
Author(s):  
Toby Boocock ◽  
◽  
Grant Bybee ◽  
Christian Schroeder ◽  
Ramona König ◽  
...  
Keyword(s):  
Isotopic Fractionation ◽  
Nitrogen Partitioning ◽  
Granitic Rocks

Fingerprinting the provenance of building stones: a case study on the Louvigné and Lanhélin granitic rocks (Armorican massif, France)

2014 ◽  
Vol 185 (1) ◽  
pp. 13-31 ◽  
Author(s):  
Claudine Malfilatre ◽  
Erwan Hallot ◽  
Philippe Boulvais ◽  
Marc Poujol ◽  
Annick Chauvin ◽  
...  
Keyword(s):  
Building Stone ◽  
Granitic Rocks ◽  
Magnetic Characteristics ◽  
Building Stones ◽  
Intrinsic Variability ◽  
Geological Unit ◽  
Qualitative Variables ◽  
Identity Cards ◽  
Armorican Massif

Abstract Two examples of granitic stones from Brittany (western France) commercialized under the names of “gris-bleu de Louvigné” and “bleu de Lanhélin” were characterized in order to explore how the provenance of a building stone can be traced back with a maximum of confidence. For this purpose, petrographical, geochemical and magnetic characteristics, representing more than 70 quantitative and qualitative variables, were compiled for a total of 32 samples. We have defined two reference populations for these building stones and have extracted their discriminative characteristics. We have then compared four randomly selected samples and two foreign commercial counterparts of these stones to the reference populations. Discriminative variables differ from one case of comparison to the other, which indicates that a combination of various tools and variables will be generally required to unequivocally fingerprint the origin of a given granitic stone. Where several quarries are mining a single geological unit within a composite intrusion, the provenance of a granitic rock can be defined at the scale of the intrusion. In addition, stones coming from two different intrusions from the same batholith can be distinguished. We conclude that the provenance of any granitic building stone is identifiable, especially if the intrinsic variability of a population of samples representative of that stone has been previously circumscribed. This study underlines that the compilation of databases for building stone identity cards is an essential first step toward the creation of official labels guaranteeing stone provenances.

Petrological, geochronological, and geochemical potential accounting for continental subduction and exhumation: A case study of felsic granulites from South Altyn Tagh, northwestern China

2020 ◽  
Vol 132 (11-12) ◽  
pp. 2611-2630
Author(s):  
Yunshuai Li ◽  
Jianxin Zhang ◽  
Shengyao Yu ◽  
Yanguang Li ◽  
Hu Guo ◽  
...  
Keyword(s):  
High Pressure ◽  
Rare Earth ◽  
Rare Earth Element ◽  
Earth Element ◽  
Granitic Rocks ◽  
Geodynamic Evolution ◽  
Altyn Tagh ◽  
Rare Earth Element Distribution ◽  
Ultrahigh Temperature

Abstract Deciphering the formation and geodynamic evolution of high-pressure (HP) granulites in a collisional orogeny can provide crucial constraints on the geodynamic evolution of subduction-exhumation. To fully exploit the geodynamic potential of metamorphic rocks, it is necessary to constrain the metamorphic ages, although it is difficult to link zircon and monazite ages to metamorphic evolution. A good case study for understanding these geodynamic processes is felsic granulites in the Bashiwake area, South Altyn Tagh. Petrographic observations suggest that the studied felsic granulites have suffered multi-stage metamorphism, and the distinct metamorphic events were documented by compositional zoning and high Y + heavy rare earth element (HREE) concentrations in the large garnet porphyroblast. Zircon U-Pb dating yielded two major age clusters: one age cluster at ca. 900 Ma represents the age of the protolith for the felsic granulite, and another age cluster at ca. 500 Ma represents the post-UHT (ultrahigh temperature) stage based on the rare earth element distribution coefficients between zircon and garnet. Meanwhile, in situ monazites U-Pb dating yielded a weighted mean 206Pb/238U age of 482 ± 3.5 Ma, and the monazite U-Pb age was interpreted to be in agreement with the metamorphic zircon rims data, which together with zircon recorded the cooling time after the UHT stage. Whole-rock major and trace elements as well as Sr-Nd isotopes suggest that the protolith of the felsic granulite derived from partial melting of ancient crustal materials with the addition of mantle materials. Integrating these results along with previous studies, we propose that the felsic granulites metamorphosed from the Neoproterozoic granitic rocks, and the granitic rocks with associated mafic-ultramafic rocks suffered a common high-pressure–ultrahigh temperature (HP-UHT) metamorphism and subsequent granulite-facies metamorphism. A tentative model of subduction-relamination was proposed for the geodynamic evolution of the Bashiwake unit, South Altyn Tagh.

scholarly journals Carbon and Hydrogen Isotopic Reversals in Highly Mature Coal-Derived Gases: A Case Study of Paleozoic Gases in the Southern Ordos Basin, China

Geofluids ◽  
2019 ◽  
Vol 2019 ◽  
pp. 1-23
Author(s):  
Dan Liu
Keyword(s):  
Source Rock ◽  
Vitrinite Reflectance ◽  
Ordos Basin ◽  
Isotopic Fractionation ◽  
Carbon Isotopic ◽  
Wet Gas ◽  
The Ordos Basin ◽  
Almost All ◽  
Mixing Of Gases

The compositional carbon isotopic seriesδ13C-CH4<δ13C-C2H6<δ13C-C3H8<δ13C-C4H10is common in thermogenic gases. With the exploration of deeper strata, however, isotopic reversals (δ13C-CH4>δ13C-C2H6>δ13C-C3H8) in overmature unconventional shale gases and conventional (coal-derived) gases have been identified. Paleozoic gases in the southern Ordos Basin, China, with partial or complete isotopic reversals, were studied as examples of isotopic fractionation in overmature coal-derived gases. Isotopic compositions of gases of different maturities from the Ordos Basin and shale gases from around the world were compared. Results indicate that carbon isotopic series are related to maturity. Complete isotopic reversal occurs mostly in regions with vitrinite reflectanceRo>2.4%. Where2.4%>Ro>2.0%, almost all gases display partial isotopic reversal, withδ13C-CH4>δ13C-C2H6orδ13C-C2H6>δ13C-C3H8. Carbon isotopic reversal in coal-derived gases is not caused by abiotic origin, the mixing of gases from different types of source rock, abiotic polymerization, wet gas cracking, and other mechanisms that contribute to reversal in shale gases. Based on the unique structure of coaly source rock and the geology of the Ordos Basin, closed-system aromatization-polycondensation reactions are considered the most likely cause of carbon isotopic reversal. During the reactions, isotopically light gases are generated by recombination of previously formed hydrocarbons and residual kerogen-coal. Hydrogen isotopic reversal in the southern Ordos Basin might also be caused by aromatization-polycondensation reactions.

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