Feasibility of Mechanochemically Stimulated Thermal Synthesis of Lithium Monoaluminates from AlO(OH) + Li2CO3 Mixtures

2021 ◽  
Vol 57 (7) ◽  
pp. 720-726
Author(s):  
N. V. Eremina ◽  
I. A. Borodulina
Keyword(s):  
2019 ◽  
Author(s):  
javier enriquez ◽  
Ignacio Chi-Duran ◽  
Carolina Manquian ◽  
Felipe Herrera ◽  
Ruben Fritz ◽  
...  

Non-centrosymmetric single-crystal metal-organic frameworks (MOF) are promising candidates for phase-matched nonlinear optical communication, but typical hydrothermal synthesis produces small crystals with relatively low transmittance and poor phase matching. We study the effect of the metal-to-ligand molar ratio and reaction pH on the hydro-thermal synthesis of the non-centrosymmetric Zn(3-ptz)<sub>2</sub> and Zn(OH)(3-ptz) MOFs with <i>in-situ </i>ligand formation. In acidic environments, we find that decreasing the amount of ligand below the stoichiometric molar ratio 1:2 also produces highly transparent single-crystal octahedrons of <b>Zn(3-ptz)<sub>2</sub></b>. In alkaline environments, we obtain long rod-like <b>Zn(OH)(3-ptz) </b>crystals whose length exceeds previous reports by up to four orders of magnitude. Potential applications of these results in the development of MOF-based nonlinear optical devices are discussed.


Author(s):  
Jianguo Liu ◽  
Shu Wang ◽  
Longzhe Jin ◽  
Tianyang Wang ◽  
Zihao Zhou ◽  
...  

AbstractCoal dust is a primary threat to underground coal miners. The most common approach to control coal dust is hydraulic methods, such as water spray and coal seam water injection. To improve the dust suppressant efficiency of hydraulic methods, a novel chemical composite dust suppressant, called NCZ, was prepared in this study using calcium chloride (CaCl2), magnesium chloride (MgCl2), and nonionic surfactants using a thermal synthesis method. The water-retaining properties of NCZ powder and its solutions were characterized using the water absorption rate (WAR) and evaporation rate (ER), respectively, and the wetting abilities of the NCZ solutions on coal dust were tested using the initial contact angle (ICA) and sink rate (SR). The results indicate that the NCZ solutions have anti-evaporation effects, and the ER of the solution with a 20.0 wt% NCZ is reduced by 11.7% compared with that of clean water. Furthermore, NCZ solutions have remarkable enhancement effects on the wettability of coal dust. The ICA and SR of clean water and the NCZ solution at 20.0 wt% are 141.9° and 0 mg/s, and 29.3° and 1.46 mg/s, respectively. Finally, quantitative relationships between the solution surface tension and the ICA and IR were established using the least squares method. This study provides a new product for dust suppression in underground mines, which is significant for the optimum applied concentration of dust suppressant in mining operations.


ChemInform ◽  
2010 ◽  
Vol 24 (9) ◽  
pp. no-no
Author(s):  
L. P. TURCHANINOVA ◽  
E. N. SUKHOMAZOVA ◽  
N. A. KORCHEVIN ◽  
E. N. DERYAGINA ◽  
M. G. VORONKOV

1998 ◽  
Vol 35 (1-2) ◽  
pp. 116-119 ◽  
Author(s):  
Shuhong Yu ◽  
Yitai Qian ◽  
Lei Shu ◽  
Yi Xie ◽  
Li Yang ◽  
...  

1989 ◽  
Vol 111 (1) ◽  
pp. 405-406 ◽  
Author(s):  
Lisa S. Crocker ◽  
D. Michael Heinekey ◽  
Gayle K. Schulte

2006 ◽  
Vol 3 (3) ◽  
pp. 253-257 ◽  
Author(s):  
H. Sepehrian ◽  
A. R. Khanchi ◽  
M. K. Rofouei ◽  
S. Waqif Husain

ChemInform ◽  
2005 ◽  
Vol 36 (40) ◽  
Author(s):  
Qixun Guo ◽  
Yi Xie ◽  
Lei Zhu ◽  
Chengqi Yi ◽  
Hongwei Hou

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