Investigation of the influence of gradual substitution K ↔ Rb on the structure and phase transition in K x Rb1 − x Pb2Br5 solid solutions

2009 ◽  
Vol 51 (3) ◽  
pp. 589-592 ◽  
Author(s):  
L. I. Isaenko ◽  
S. V. Mel’nikova ◽  
A. A. Merkulov ◽  
V. M. Pashkov ◽  
A. Yu. Tarasova
Keyword(s):  
Phase Transition ◽  
Solid Solutions

Spontaneous phase transition from relaxor to macrodomain ferroelectric state in single-crystal PbSc0.5Nb0.5O3-BaSc0.5Nb0.5O3 solid solutions

2000 ◽  
Vol 42 (1) ◽  
pp. 161-164 ◽  
Author(s):  
I. P. Raevskii ◽  
V. V. Eremkin ◽  
V. G. Smotrakov ◽  
E. S. Gagarina ◽  
M. A. Malitskaya
Keyword(s):  
Phase Transition ◽  
Single Crystal ◽  
Solid Solutions ◽  
Ferroelectric State ◽  
Spontaneous Phase

Diffused phase transition boosted dye degradation with Ba (ZrxTi1−x)O3 solid solutions through piezoelectric effect

Nano Energy ◽  
2021 ◽  
Vol 89 ◽  
pp. 106474
Author(s):  
Mengde Zhu ◽  
Siqi Li ◽  
Hongfang Zhang ◽  
Ju Gao ◽  
K.W. Kwok ◽  
...  
Keyword(s):  
Phase Transition ◽  
Solid Solutions ◽  
Piezoelectric Effect ◽  
Dye Degradation ◽  
Diffused Phase Transition

scholarly journals Растворимость теллура в кристаллах TlGaTe-=SUB=-2-=/SUB=-, TlInTe-=SUB=-2-=/SUB=- и электрофизические свойства твердых растворов

2018 ◽  
Vol 60 (9) ◽  
pp. 1656
Author(s):  
А.И. Наджафов ◽  
Н.А. Алиева ◽  
К.Г. Халилова
Keyword(s):  
Phase Transition ◽  
Electrical Conductivity ◽  
Solid Solutions ◽  
Physicochemical Analysis ◽  
Lattice Parameters ◽  
Temperature Dependences ◽  
Complex Methods

AbstractThe complex methods of the physicochemical analysis are used to study TlGaTe_2–Te and TlInTe_2–Te alloys in which the tellurium solubility region up to 5.0 at % is observed. The temperature dependences of the lattice parameters and the electrical conductivity of TlGaTe_2 + x and TlInTe_2 + x have been studied in different crystallographic directions. The TlGaTe_2 + x and TlInTe_2 + x solid solutions undergo a phase transition at a temperature of 498 K. The transition nature is interpreted.

scholarly journals Manifestation of magnetoelastic interactions in Raman spectra of HoxNd1−xFe3(BO3)4 crystals

2018 ◽  
Vol 08 (02) ◽  
pp. 1850011 ◽  
Author(s):  
A. S. Krylov ◽  
S. N. Sofronova ◽  
I. A. Gudim ◽  
S. N. Krylova ◽  
Rajesh Kumar ◽  
...  
Keyword(s):  
Phase Transition ◽  
Raman Spectra ◽  
Structural Phase Transition ◽  
Solid Solutions ◽  
Order Parameter ◽  
Soft Mode ◽  
Magnetic Phase ◽  
Structural Phase ◽  
Exchange Interactions ◽  
Magnetoelastic Interaction

Raman spectra of Ho[Formula: see text]NdxFe(BO3)4 ([Formula: see text], 0.75, 0.5, 0.25) have been studied in temperature range 10–400[Formula: see text]K. Two compositions ([Formula: see text], [Formula: see text]) demonstrate structural phase transition with soft mode restoration. The addition of Nd atoms increases interatomic spacing and decreases the temperature of structural phase transition. The solid solutions ([Formula: see text], 0.5, 0.25) demonstrate the emergence of the peaks corresponding to magnetoelastic interaction below Néel temperature. The order parameter of the magnetic phase transition has been determined. The equal concentrations of holmium and neodymium atoms prevent magnon soft modes condensation caused by exchange interactions in Fe–O–Fe chains are observed. Calculations confirm the data obtained in the experiment.

Phase transitions of (1−x) PbZrO3 + x (Na1/2Bi1/2)TiO3 (0.01 ≤ x ≤ 0.15) solid solutions

1999 ◽  
Vol 14 (1) ◽  
pp. 83-89 ◽  
Author(s):  
Jung-Kun Lee ◽  
Hyuk-Joon Youn ◽  
Kug Sun Hong
Keyword(s):  
Phase Transition ◽  
Phase Transitions ◽  
Solid Solutions ◽  
Temperature Phase ◽  
X Ray Diffraction ◽  
Scanning Calorimetry ◽  
Two Phase ◽  
Phase Transition Temperatures ◽  
Temperature Phase Transition ◽  
Increasing Temperature

Morphotropic phase boundaries and temperature dependent phase transitions of (1 – x) PbZrO3 + x (Na1/2Bi1/2)TiO3 (0.01 ≤ x ≤ 0.15) solid solutions were investigated by x-ray diffraction, differential scanning calorimetry (DSC), and dielectric property analysis. Two morphotropic phase transitions at room temperature were found at x = 0.1 and 0.13, which were from antiferroelectric orthorhombic (with 4 × 4 × 2 superlattice [orthorhombic (I)]) to antiferroelectric orthorhombic (with 2 × 2 × 2 superlattice [orthorhombic (II)]) and from orthorhombic (II) to ferroelectric rhombohedral, respectively. With increasing temperature, the samples with 0.01 ≤ x < 0.1 showed two phase transitions, i.e., from orthorhombic (I) to orthorhombic (II) and from orthorhombic (II) to cubic. The other samples had only one phase transition with increasing temperature. Phase transition temperatures of all the samples were measured using DSC, and a phase diagram for the solid solutions was constructed. A model illustrating the antiparallel shift of Pb ions in the orthorhombic (II) phase was also proposed.

High-temperature X-ray powder diffraction study of the tetragonal-cubic phase transition in nanocrystalline, compositionally homogeneous ZrO2–CeO2 solid solutions

2008 ◽  
Vol 23 (S1) ◽  
pp. S70-S74 ◽  
Author(s):  
L. M. Acuña ◽  
R. O. Fuentes ◽  
D. G. Lamas ◽  
I. O. Fábregas ◽  
N. E. Walsöe de Reca ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Phase Transition ◽  
High Temperature ◽  
Powder Diffraction ◽  
Solid Solutions ◽  
Tetragonal Phase ◽  
Room Temperature ◽  
Cubic Phase ◽  
X Ray ◽  
First Order

Crystal structure of compositionally homogeneous, nanocrystalline ZrO2–CeO2 solutions was investigated by X-ray powder diffraction as a function of temperature for compositions between 50 and 65 mol % CeO2. ZrO2-50 and 60 mol % CeO2 solid solutions, which exhibit the t′-form of the tetragonal phase at room temperature, transform into the cubic phase in two steps: t′-to-t″ followed by t″-to-cubic. But the ZrO2-65 mol % CeO2, which exhibits the t″-form, transforms directly to the cubic phase. The results suggest that t′-to-t″ transition is of first order, but t″-to-cubic seems to be of second order.

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