Synthesis of Dicalcium Silicate in the Presence of Dust from Electrostatic Precipitators of Cement Kilns

2020 ◽  
Vol 93 (6) ◽  
pp. 813-820
Author(s):  
N. P. Kudeyarova ◽  
N. P. Bushueva ◽  
O. A. Panova
Author(s):  
C. J. Chan ◽  
K. R. Venkatachari ◽  
W. M. Kriven ◽  
J. F. Young

Dicalcium silicate (Ca2SiO4) is a major component of Portland cement. It has also been investigated as a potential transformation toughener alternative to zirconia. It has five polymorphs: α, α'H, α'L, β and γ. Of interest is the β-to-γ transformation on cooling at about 490°C. This transformation, accompanied by a 12% volume increase and a 4.6° unit cell shape change, is analogous to the tetragonal-to-monoclinic transformation in zirconia. Due to the processing methods used, previous studies into the particle size effect were limited by a wide range of particle size distribution. In an attempt to obtain a more uniform size, a fast quench rate involving a laser-melting/roller-quenching technique was investigated.The laser-melting/roller-quenching experiment used precompacted bars of stoichiometric γ-Ca2SiO4 powder, which were synthesized from AR grade CaCO3 and SiO2xH2O. The raw materials were mixed by conventional ceramic processing techniques, and sintered at 1450°C. The dusted γ-Ca2SiO4 powder was uniaxially pressed into 0.4 cm x 0.4 cm x 4 cm bars under 34 MPa and cold isostatically pressed under 172 MPa. The γ-Ca2SiO4 bars were melted by a 10 KW-CO2 laser.


2013 ◽  
Vol 864-867 ◽  
pp. 1923-1928
Author(s):  
Yue Xu ◽  
Jian Xi Li ◽  
Li Li Kan

A new kind of high strength cementitious material is made from phosphogypsum (PG), active carbon and fly-ash. Through the orthogonal research, it was showed that the calcination temperature, retention time, dosage of active carbon and fly ash on the compressive strength of cementitious binder are the most important. The result also showed that, in the conditions of temperature 1200°C, time retention 30 min, dosage of active carbon 10%, dosage of fly ash 5%, the compressive strength of the cementitious material for 3d and 28d could reach to 46.35MPa and 92.70MPa, the content of sulfur trioxide was 11.60% accordingly. A lot of active mineral materials, such as dicalcium silicate, tricalcium silicate, tricalcium aluminate were formed in the calcination. The C-S-H gel, calcium hydroxide and ettringite were found in 3d and 28d hydrates. It is found that the lime saturation ratio and silica modulus need to be control between 0.40~0.65 and 4~8 in order to produce high strength cementitious material.


Author(s):  
Thiago Soeiro ◽  
Jurgen Biela ◽  
Jonas Muhlethaler ◽  
Jorgen Linner ◽  
Per Ranstad ◽  
...  

2008 ◽  
Vol 28 (11) ◽  
pp. 2375-2385 ◽  
Author(s):  
G. Genon ◽  
E. Brizio
Keyword(s):  

2002 ◽  
Vol 85 (9) ◽  
pp. 2171-2176 ◽  
Author(s):  
Nakshatra B. Singh ◽  
Sarita Rai ◽  
Neelam Singh
Keyword(s):  

2014 ◽  
Vol 2 (24) ◽  
pp. 3830-3838 ◽  
Author(s):  
Xianyan Yang ◽  
Min Liu ◽  
Yu Zhao ◽  
Hongyu Jia ◽  
Sanzhong Xu ◽  
...  

Gypsum-introduced, CaO-rich dicalcium silicate-based cements exhibit multifunctional physicochemical and biological properties and meet some challenging criteria in root canal therapy.


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