The Influence of N,N'-Dialkylthioureas on the Two-Step Electroreduction of Zn(II) Ions
1998 ◽
Vol 63
(6)
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pp. 749-760
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Keyword(s):
A two-step reduction of Zn(II) ions at the dropping mercury electrode in 1 M NaClO4/0.001 M HClO4 in the presence of N,N'-dialkylthioureas was examined in wide potential and frequency ranges, using the impedance method. The rate constant of the first electron transfer increases with increasing concentration of N,N'-dialkylthioureas, whereas that of the second electron transfer depends largely on the double layer effects, particularly, on the orientation of molecules on the electrode surface.
1999 ◽
Vol 64
(4)
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pp. 585-594
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Keyword(s):
1991 ◽
Vol 56
(1)
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pp. 152-156
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1987 ◽
Vol 109
(7)
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pp. 1916-1920
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1968 ◽
Vol 16
(1)
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pp. 83-87
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Keyword(s):
2009 ◽
Vol 113
(20)
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pp. 8964-8971
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1995 ◽
Vol 385
(1)
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pp. 95-103
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2007 ◽
Vol 17
(6)
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pp. 157-161
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Keyword(s):
1963 ◽
Vol 40
(6)
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pp. 306-309
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Keyword(s):
1959 ◽
Vol 55
(0)
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pp. 324-330
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Keyword(s):
1982 ◽
Vol 312
(2)
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pp. 121-125
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