Cu(I)–PNF, an organic-based nanocatalyst, catalyzed C–O and C–S cross-coupling reactions

2019 ◽  
Vol 97 (1) ◽  
pp. 46-52 ◽  
Author(s):  
Zahra Taherinia ◽  
Arash Ghorbani-Choghamarani
Keyword(s):  
Catalytic Activity ◽  
Self Assembly ◽  
Water Solubility ◽  
High Efficiency ◽  
Low Cost ◽  
Cross Coupling ◽  
Coupling Reactions ◽  
Catalytic Systems ◽  
Highly Efficient ◽  
Cross Coupling Reactions

Peptide nanofiber has been prepared via a self-assembly protocol and decorated with Cu(I) to prepare a nanostructural catalyst. The catalytic activity of this prepared nanomaterial (Cu(I)–PNF) was examined in C–O and C–S cross-coupling reactions. Compared with conventional copper–ligand catalytic systems, CuNP–PNF has unique advantages such as water solubility, high efficiency, and low cost, which makes it a highly efficient and beneficial catalyst to reuse in cross-coupling reactions.

A highly efficient catalyst for Suzuki–Miyaura coupling reaction of benzyl chloride under mild conditions

RSC Advances ◽  
2014 ◽  
Vol 4 (69) ◽  
pp. 36437-36443 ◽  
Author(s):  
Zhenhong Guan ◽  
Buyi Li ◽  
Guoliang Hai ◽  
Xinjia Yang ◽  
Tao Li ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Benzyl Chloride ◽  
Coupling Reaction ◽  
Cross Coupling ◽  
Coupling Reactions ◽  
Efficient Catalyst ◽  
Microporous Polymers ◽  
Mild Conditions ◽  
Highly Efficient ◽  
Cross Coupling Reactions

Microporous polymers with built-in triphenylphosphine palladium exhibit highly efficient catalytic activity for cross-coupling reactions of benzyl chloride under mild conditions.

A ruthenium-grafted triazine functionalized mesoporous polymer: a highly efficient and multifunctional catalyst for transfer hydrogenation and the Suzuki–Miyaura cross-coupling reactions

2014 ◽  
Vol 43 (19) ◽  
pp. 7057-7068 ◽  
Author(s):  
Noor Salam ◽  
Sudipta K. Kundu ◽  
Anupam Singha Roy ◽  
Paramita Mondal ◽  
Kajari Ghosh ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Cross Coupling ◽  
Transfer Hydrogenation ◽  
Organic Polymer ◽  
Coupling Reactions ◽  
Mesoporous Polymer ◽  
Highly Efficient ◽  
Cross Coupling Reactions ◽  
Multifunctional Catalyst

A new ruthenium grafted mesoporous organic polymer has been synthesized and it showed excellent catalytic activity in transfer hydrogenation and C–C cross-coupling reactions.

scholarly journals Modified ultradispersed diamonds based catalytic systems in cross-coupling reactions

2021 ◽  
Vol 57 (1) ◽  
pp. 7-14
Author(s):  
A. A. Lugovski ◽  
G. A. Gusakov ◽  
M. P. Samtsov ◽  
V. A. Parhomenko ◽  
S. V. Adamchyk
Keyword(s):  
Catalytic Activity ◽  
Coupling Reaction ◽  
Cross Coupling ◽  
Model Systems ◽  
High Catalytic Activity ◽  
Coupling Reactions ◽  
Catalytic Systems ◽  
Cross Coupling Reactions ◽  
Cross Coupling Reaction ◽  
Metallic Palladium

Methods for preparation of nanocomposites of modified detonation nanodiamonds (DND) with metallic palladium have been developed and their catalytic activity in the Suzuki-Miyaura cross-coupling reaction in various reaction media has been studied. Methods for the regeneration of palladium-containing nanocomposites from the reaction mixture have been developed. The high catalytic activity of nanocomposites is confirmed by kinetic analysis based on the results of chromatographic analysis of the reaction mixture and is comparable to the literature data about similar catalytic systems. Regenerated nanocomposites showed the retention of catalytic activity for 3 consecutive cross-coupling cycles on model systems.

scholarly journals Microflowers formed by complexation-driven self-assembly between palladium(ii) and bis-theophyllines: immortal catalyst for C–C cross-coupling reactions

RSC Advances ◽  
2021 ◽  
Vol 11 (56) ◽  
pp. 35311-35320
Author(s):  
Katsuya Kaikake ◽  
Naoki Jou ◽  
Go Shitara ◽  
Ren-Hua Jin
Keyword(s):  
Catalytic Activity ◽  
Self Assembly ◽  
Palladium Complex ◽  
Coupling Reaction ◽  
Cross Coupling ◽  
High Catalytic Activity ◽  
Coupling Reactions ◽  
Cross Coupling Reactions

Bis-theophylline-palladium complex exhibit high catalytic activity in the C–C coupling reaction with excellent recyclability in the presence of NaCl.

Dual Nickel/Palladium-Catalyzed Reductive Cross-Coupling Reactions Between Two Phenol Derivatives

2020 ◽  
Author(s):  
Baojian Xiong ◽  
Yue Li ◽  
Yin Wei ◽  
Søren Kramer ◽  
Zhong Lian
Keyword(s):  
Functional Group ◽  
Low Cost ◽  
Cross Coupling ◽  
Coupling Reactions ◽  
Phenol Derivatives ◽  
Cross Coupling Reactions ◽  
Palladium Catalyzed ◽  
One Step ◽  
Aryl Tosylates ◽  
Low Sensitivity

Cross-coupling between substrates that can be easily derived from phenols is highly attractive due to the abundance and low cost of phenols. Here, we report a dual nickel/palladium-catalyzed reductive cross-coupling between aryl tosylates and aryl triflates; both substrates can be accessed in just one step from readily available phenols. The reaction has a broad functional group tolerance and substrate scope (>60 examples). Furthermore, it displays low sensitivity to steric effects demonstrated by the synthesis of a 2,2’disubstituted biaryl and a fully substituted aryl product. The widespread presence of phenols in natural products and pharmaceuticals allow for straightforward late-stage functionalization, illustrated with examples such as Ezetimibe and tyrosine. NMR spectroscopy and DFT calculations indicate that the nickel catalyst is responsible for activating the aryl triflate, while the palladium catalyst preferentially reacts with the aryl tosylate.

Lewis Acid-Promoted Suzuki Reaction using Palladium Chloride Anchored on a Polymer as a Catalyst

2008 ◽  
Vol 61 (8) ◽  
pp. 610 ◽  
Author(s):  
Guozhi Fan ◽  
Hanjun Zhang ◽  
Siqing Cheng ◽  
Zhandong Ren ◽  
Zhijun Hu ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Lewis Acid ◽  
Lewis Acids ◽  
Heterogeneous Catalysts ◽  
Suzuki Reaction ◽  
Cross Coupling ◽  
Palladium Chloride ◽  
Coupling Reactions ◽  
Cross Coupling Reactions ◽  
Recoverable Catalyst

Palladium chloride anchored on polystyrene modified by 5-amino-1,10-phenanthroline was prepared and used as an efficient recoverable catalyst for Suzuki cross-coupling reactions. The heterogeneous catalysts can be easily separated from the reaction mixture and reused for five cycles without significant Pd leaching and loss of catalytic activity. Rate enhancement in the Suzuki reaction by Lewis acids was also studied.

scholarly journals Copper’s rapid ascent in visible-light photoredox catalysis

Science ◽  
2019 ◽  
Vol 364 (6439) ◽  
pp. eaav9713 ◽  
Author(s):  
Asik Hossain ◽  
Aditya Bhattacharyya ◽  
Oliver Reiser
Keyword(s):  
Visible Light ◽  
Organic Dyes ◽  
Low Cost ◽  
Cross Coupling ◽  
Coupling Reactions ◽  
Photoredox Catalysis ◽  
Cross Coupling Reactions ◽  
Rapid Ascent ◽  
Catalyzed Reactions ◽  
Metal Catalyzed

Visible-light photoredox catalysis offers a distinct activation mode complementary to thermal transition metal catalyzed reactions. The vast majority of photoredox processes capitalizes on precious metal ruthenium(II) or iridium(III) complexes that serve as single-electron reductants or oxidants in their photoexcited states. As a low-cost alternative, organic dyes are also frequently used but in general suffer from lower photostability. Copper-based photocatalysts are rapidly emerging, offering not only economic and ecological advantages but also otherwise inaccessible inner-sphere mechanisms, which have been successfully applied to challenging transformations. Moreover, the combination of conventional photocatalysts with copper(I) or copper(II) salts has emerged as an efficient dual catalytic system for cross-coupling reactions.

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