THE VIBRATIONAL CONSTANTS OF ACETYLENE

1948 ◽  
Vol 26a (5) ◽  
pp. 279-291 ◽  
Author(s):  
Norma Morgenroth Nordin ◽  
R. N. H. Haslam

On the basis of the work done by Darling and Dennison on the water vapor molecule, the vibrational constants of acetylene are calculated, taking into account the resonance interaction arising from the near equality of the fundamentals ν1 and ν3. Seventeen band centers are known experimentally. The band centers depend on the 10 constants χi, χik and γ which are functions of the potential constants. The expressions for the vibrational energies of the band centers are set up, those for interacting doublets or triplets being found by perturbation methods. The 10 constants are determined and the positions of eight bands calculated to check the results. The agreement is very satisfactory. The positions of 10 other bands not yet observed are predicted.

2016 ◽  
Vol 18 (26) ◽  
pp. 17414-17427 ◽  
Author(s):  
Tianlei Zhang ◽  
Chen Yang ◽  
Xukai Feng ◽  
Jiaxin Kang ◽  
Liang Song ◽  
...  

Catalyst X (X = H2O, (H2O)2and (H2O)3) is incorporated into the channel of H2S +3O2formation and the catalytic effect of water, water dimers and water trimers is mainly taken from the contribution of a single water vapor molecule.


2019 ◽  
Vol 21 (43) ◽  
pp. 24042-24053 ◽  
Author(s):  
Tianlei Zhang ◽  
Mingjie Wen ◽  
Yongqi Zhang ◽  
Xinguang Lan ◽  
Bo Long ◽  
...  

In the incorporation of the catalyst (H2O)n (n = 1–3) into the HO2 + HO2 → H2O2 + 3O2 reaction, the catalytic effect of water, water dimers and water trimers is mainly derived from the contribution of a single water vapor molecule by a stepwise route.


1976 ◽  
Vol 19 (11) ◽  
pp. 1522-1524
Author(s):  
O. K. Voitsekhovskaya ◽  
Yu. S. Makushkin ◽  
O. N. Sulakshina

1931 ◽  
Vol 38 (9) ◽  
pp. 1784-1784 ◽  
Author(s):  
E. K. Plyler

1940 ◽  
Vol 57 (2) ◽  
pp. 128-139 ◽  
Author(s):  
Byron T. Darling ◽  
David M. Dennison

Author(s):  
Sebastien Gueydon

Abstract With their light weights, small components like braces and heave plates and steady trim angle caused by the wind loads acting on the rotor, semisubmersible foundations used as support platform for wind turbines exhibit a complex behaviour where viscous loading play an important role. The work done by the Offshore Code Comparison Collaboration Continued with Correlation (OC5) project has shown that standard engineering tools were not always able to predict accurately the motions of the DeepCwind semisubmersible that were measured in a basin. The correct amplitude of the motions at the natural periods of this system appeared to be difficult to obtain with simulations (especially the low frequency surge, and the pitch resonant motion). In view of the complexity of the system, it was not possible to clearly identify the causes of the differences between the simulations and the model-test results. A follow-on validation campaign was therefore performed at the Maritime Research Institute Netherlands (MARIN) under the MARINET2 project with the same floating substructure, with a focus on better understanding the hydrodynamic loads and reducing uncertainty in the tests by minimizing the system complexity. The wind turbine was replaced by a stiff tower with resembling inertia properties. The mooring system was simplified by using taut-spring lines with equivalent linear stiffness in surge. This paper reviews the new tests done with the simplified set-up and examines the differences with previous tests done with more complex test set-ups. The main motivation of this work is to study how variations of an experimental set-up can affect the outcome of tests in a wave basin. To start with, the main parameters of the systems (inertia, hydrostatics, and mooring stiffness) for all set-ups are characterized to check how similar they are. Then the level of damping in all systems is compared. Finally, the paper looks at how well the motion responses of this semisubmersible in waves correlate between all these campaigns.


1956 ◽  
Vol 40 (333) ◽  
pp. 199-200

The International Commission on the Teaching of Mathematics, which is one of the Commissions set up by the International Mathematical Union, has been conducting an enquiry into the teaching of mathematics between the ages of 16 and 21. A full report has already been published on this aspect of teaching so far as Germany is concerned and a questionnaire was sent to all countries participating in the work of the commission. The British National Committee for Mathematics appointed Dr. E. A. Maxwell to represent Britain on the International Commission and a sub-committee consisting of Dr. Maxwell, Miss M. L. Cartwright, A. P. Rollett and G. L. Parsons to prepare the answers to the questionnaire. This sub-committee also received a good deal of help from the Department of Education of Cambridge University in connection with questions relating to the general system of education. The sub-committee confined their replies for the most part to work done in schools. With the replies were sent various relevant pamphlets published by the Ministry of Education, specimen timetables from various types of schools, a large number of examination papers and syllabuses and reports of the Mathematical Association. The questionnaire was framed for dealing with state systems of education similar to that in Germany and covered the whole educational system. We give only those parts of it relating to the technical aspects of the enquiry.


2010 ◽  
Vol 3 (3) ◽  
pp. 2389-2432
Author(s):  
C. Straub ◽  
A. Murk ◽  
N. Kaempfer

Abstract. In this paper a new 22 GHz water vapor spectro-radiometer which has been specifically designed for profile measurement campaigns of the middle atmosphere is presented. The instrument is of a compact design and has a simple set up procedure. It can be operated as a standalone instrument as it maintains its own weather station and a calibration scheme that does not rely on other instruments or the use of liquid nitrogen. The optical system of MIAWARA-C combines a choked gaussian horn antenna with a parabolic mirror which reduces the size of the instrument in comparison with currently existing radiometers. For the data acquisition a correlation receiver is used together with a digital cross correlating spectrometer. The complete backend section, including the computer, is located in the same housing as the instrument. The receiver section is temperature stabilized to avoid gain fluctuations. Calibration of the instrument is achieved through a balancing scheme with the sky used as the cold load and the tropospheric properties are determined by performing regular tipping curves. Since MIAWARA-C is used in measurement campaigns it is important to be able to determine the elevation pointing in a simple manner as this is a crucial parameter in the calibration process. Here we present two different methods; scanning the sky and the Sun. Finally, we report on the first spectra and retrieved water vapor profiles acquired during the Lapbiat campaign at Sodankylä Geophysical Observatory. The performance of MIAWARA-C is validated here by comparison of the presented profiles against the equivalent profiles from the Microwave Limb Sounder on the EOS/Aura satellite.


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