The high moisture content of lignite restricts its extensive and efficient use. Furthermore, the reabsorption of lignite is also a factor that affects lignite spontaneous combustion. Therefore, it is of great importance to study the process and mechanism of water molecule desorption and adsorption on lignite and coke (25–950°C) to achieve the clean and efficient utilization of lignite and environmental protection. Proton nuclear magnetic resonance (1H-NMR), thermogravimetric analysis, and other techniques were used in this study to explore the water molecule absorption and desorption processes of lignite pyrolysis at different temperatures (25–950°C) and the special contributions of ether bonds to water molecule adsorption. A mechanism of lignite water molecule adsorption was proposed. The results showed that ether bonds played a special role in the water molecule adsorption by pyrolyzed lignite. The ether bond content was greater in the coal samples at 300 and 950°C, which changed the trend of lignite water molecule absorption and the distribution of water (T2) detected in the 1H-NMR experiments and delayed the escape of water molecules during moisture desorption. The total amount of adsorbed water decreased first and then increased in the coal samples as the pyrolysis temperature increased. However, the maximum adsorption interactions of each coal sample increased first and then decreased. This was the result of the interactions between the pores and the oxygen-containing functional groups. Based on the above analysis, water molecule adsorption mechanism models of lignite and coke were constructed. This study offers a new approach for investigating the water molecule adsorption and adsorption mechanisms of lignite and coke.
We investigated H2O molecule adsorption that had an effect on the luminescence properties of the CsI(Na) crystal using experiments and first-principle calculations. We measured the emission spectra of the CsI(Na) crystal at different exposure times under gamma ray excitation. The experimental results showed that the energy resolution of the CsI(Na) crystal was worse when the crystal surface adsorbed more H2O molecules, and the crystal surface deliquescence decreased the luminescence efficiency of the CsI(Na) crystal. We studied the band structure, density of states, and optical properties changes caused by H2O molecule adsorption on the CsI(Na) (010) surface. The generalized gradient approximation (GGA) was used to describe the exchange and correlation potential between the electrons. Our calculation results showed that the band gap width of the CsI(Na) (010) surface decreased after adsorbing H2O molecules, while three new peaks appeared in the valence band, and the absorption coefficient decreased from 90,000 cm−1 to 65,000 cm−1, and the reflection coefficient decreased from 0.195 to 0.105. Further, the absorption coefficient was reduced by at least 25% because of H2O molecule adsorption, which led to the luminescence degradation of the CsI(Na) crystal.
Identifying the Atomic Layer Stacking of Mo2C MXene by Probe Molecule Adsorption
