Etats de valence de NS dans le domaine 2250–3800 Å

1973 ◽  
Vol 51 (20) ◽  
pp. 2143-2161 ◽  
Author(s):  
Alain Jenouvrier ◽  
Bernard Pascat

Five red-degraded transitions, A2Δ–X2Π, G2Σ−–X2Π, H2Π–X2Π, I2Σ+–X2Π, and B2Π–X2Π of 14N32S, have been observed in the region 2250–3800 Å. The complete rotational analysis of these transitions leads to a coherent attribution of the electronic transitions and reveals many perturbations in the rotational structures. All the levels of the A2Δ state are perturbed and the perturbing state is presumably a [Formula: see text] state.The most important results are given in the tables of molecular constants. An energy level diagram and potential curves show the relative positions of the different observed states.

1976 ◽  
Vol 54 (18) ◽  
pp. 1909-1923 ◽  
Author(s):  
Michel Vervloet ◽  
Alain Jenouvrier

Five electronic transitions, C2Σ+–X2Π, I2Σ+–X2Π, E2Π–X2Π, J2Σ+–X2Π, and F2Δ–X2Π of NS have been observed in the region 1750–2400 Å. The complete analysis of these transitions has been carried out. The molecular constants of the C2Σ+, E2Π, J2Σ+, and F2Δ Rydberg states are given. Many perturbations in the rotational structures (ν = 1 and 2 of C2Σ+, ν = 0 of E2Π) and predissociations in the levels ν = 0 J2Σ+ and F2Δ are observed. The perturbation in the level ν = 0 of the E2Π state is described, the perturbing level being ν = 11 of the H2Π valence state.The most important results are given in the tables of constants. An energy level diagram and potential curves show the relative position of the different states. All the observed states of NS are finally compared with those of PO.


2015 ◽  
Vol 16 (1) ◽  
pp. 74-78 ◽  
Author(s):  
O. M. Bordun ◽  
I. Y. Kukharskyy ◽  
B. O. Bordun

Photoexcitation spectra and luminescence of thin films of ZnGa2O4 under photo-, cathode and X-ray excitation were investigated. Luminescence spectra were factorized on ultimate constituents using Alentsev-Fock method. Emission bands with maximums at 3.35, 2.85, 2.50 and 2.38 eV were referred to the luminescence at the expense of electronic transitions between 4Т2, 4Т1, 2Е and 4А2 terms in octahedral complexes (GaO6)9–. It was proposed an energy level diagram with corresponding electronic transitions in such structure. Luminescence band with maximum at 1.75 eV is attributed to oxygen vacancies.


Author(s):  
Frank S. Levin

Chapter 7 illustrates the results obtained by applying the Schrödinger equation to a simple pedagogical quantum system, the particle in a one-dimensional box. The wave functions are seen to be sine waves; their wavelengths are evaluated and used to calculate the quantized energies via the de Broglie relation. An energy-level diagram of some of the energies is constructed; on it are illustrations of the corresponding wave functions and probability distributions. The wave functions are seen to be either symmetric or antisymmetric about the midpoint of the line representing the box, thereby providing a lead-in to the later exploration of certain symmetry properties of multi-electron atoms. It is next pointed out that the Schrödinger equation for this system is identical to Newton’s equation describing the vibrations of a stretched musical string. The different meaning of the two solutions is discussed, as is the concept and structure of linear superpositions of them.


2021 ◽  
Vol 26 ◽  
pp. 102101
Author(s):  
Vaishali Kale ◽  
Y.M. Hunge ◽  
Shalaka A. Kamble ◽  
Madhuri Deshmukh ◽  
S.V. Bhoraskar ◽  
...  

1967 ◽  
Vol 22 (12) ◽  
pp. 2015-2023 ◽  
Author(s):  
G. Messerle ◽  
L. Krauss

Homogeneous rotational perturbations (Δ Λ = 0) were found in the DESLANDRES-D’AZAMBUJA bands (c1Πg — b1Πu) for v′ ≧ 3. The rotational analysis showed that the c1Πg state is perturbed by an hitherto unknown c′1Πg state. Vibrational levels of the c′1Πg state were determined from ν = 0 up to ν = 5. Furthermore some additional vibrational levels of the c1Πg state could be identified up to ν = 8.The detection of the c′1Πg state explains the observed strong vibrational perturbation of the c1Πg state. The mutual position of the two 1Πg potential curves is plotted approximately.


1974 ◽  
Vol 52 (9) ◽  
pp. 813-820 ◽  
Author(s):  
René Stringat ◽  
Jean-Paul Bacci ◽  
Marie-Hélène Pischedda

The strongly perturbed 1Π–X1Σ+ system of C80Se has been observed in the emission spectrum of a high frequency discharge through selenium and carbon traces in a neon atmosphere. The analysis of five bands yields, for the molecular constants of the ground state, the values Be″ = 0.5750 cm−1, [Formula: see text], αe″ = 0.00379 cm−1, re″ = 1.676 Å, ΔG″(1/2) = 1025.64 cm−1, and ΔG″(3/2) = 1015.92 cm−1. The numerous perturbations in the 1Π state prohibit the simple evaluation of the constants of the perturbed state and of the perturbing ones.


2020 ◽  
Vol 44 (3) ◽  
pp. 870-883 ◽  
Author(s):  
Lakshmi Kumari ◽  
Asit Kumar Kar

Energy level diagram of FRET process in Cd(1−x)ZnxS nanomaterials between donor (ZnS) and acceptor (CdS): the smaller ZnS materials transfer energy nonradiatively to the larger CdS materials when there is sufficient spectral overlap between them.


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