A vibrational and rotational analysis of the band system of HDCO

1984 ◽  
Vol 62 (10) ◽  
pp. 973-977 ◽  
Author(s):  
D. J. Clouthier ◽  
A. M. Craig ◽  
F. W. Birss

The vibronic bands of the [Formula: see text] system of HDCO have been identified by magnetic rotation and absorption spectroscopy. Rotational analyses have been carried out for four bands. The excited state geometry and a Coriolis perturbation in the 210 band are discussed.


1973 ◽  
Vol 51 (17) ◽  
pp. 1810-1814 ◽  
Author(s):  
F. W. Birss ◽  
Ronald Y. Dong ◽  
D. A. Ramsay

The 0–0 band of the [Formula: see text] system of propynal near 4145 Å has been photographed under high resolution and a rotational analysis carried out. The principal molecular constants for the ã3A″ state are (in cm−1):[Formula: see text]Altogether, 1237 lines have been assigned to transitions with ΔKa = 0. The dominant transition moment involves mixing of the ã3A″ state with higher 1A′ states.A simple magnetic rotation spectrum has been obtained and the assignments of the lines discussed.



1959 ◽  
Vol 37 (2) ◽  
pp. 136-143 ◽  
Author(s):  
Nand Lal Singh

The fine structures of three of the β bands of PO which occur near 3200 Å have been analyzed. The analysis shows that the upper state of this band system is a 2Σ and not a 2Π state as previously believed. The rotational constants of both electronic states have been determined and it is found that the ground state constants, previously determined from the γ bands, are incorrect.



1982 ◽  
Vol 77 (7) ◽  
pp. 3319-3328 ◽  
Author(s):  
Robert A. Goldbeck ◽  
Allen J. Twarowski ◽  
Eric L. Russell ◽  
Jane K. Rice ◽  
Robert R. Birge ◽  
...  


2006 ◽  
Vol 259 (1) ◽  
pp. 154-157 ◽  
Author(s):  
M.M. Kozak ◽  
D. Goebel ◽  
W. Kowalsky ◽  
R. Caspary






1972 ◽  
Vol 50 (12) ◽  
pp. 1402-1408 ◽  
Author(s):  
S. M. Japar

The 2800 Å band system of p-dibromobenzene has been photographed under high resolution and an extended vibrational analysis has been carried out. The analysis is not inconsistent with the assignment of the system to a 1B2u ← 1Ag transition, by analogy with other p-dihalogenated benzenes. The observed spectrum can be explained in terms of a number of strong type-B vibronic bands and a considerably smaller number of type-A vibronic bands. The extensive sequence structure is adequately accounted for, and can be related to observations on other halogenated benzene molecules. Thirteen ground state and nine excited state fundamental vibrational frequencies have been assigned.





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