Surface-recombination and doping effects on the minority carriers in polycrystalline silicon
A scanning laser microscope was used in a spatially resolved photoconductivity experiment to determine the minority-carrier diffusion length (L) and surface-recombination velocity at grain boundaries (SGB) in (i) n- and p-type Wacker polysilicon and (ii) neutron-transmutation-doped Metron polysilicon as a function of beam intensity. Different values of L were measured on opposite sides of the grain boundaries. For the Metron samples, L was measured at the same grain boundary using a series of samples doped to different levels. These samples had dopant concentrations between 1013 and 1017 atoms/cm3. L was found to decrease from 50 to 5 μm, with decreasing beam intensity, reaching a constant value at low beam intensities. L was also found to remain relatively unchanged for low dopant concentrations. The SGB values were found to increase with increasing beam intensity in both Wacker and Metron samples, ranging between 104 and 105 cm/s. L was also measured with a light-beam-induced-current technique (perpendicular geometry) and found to be in close agreement with values obtained using the photoconductivity technique.