SOLVENT SHIFTS IN CHARGE-TRANSFER SPECTRA. INFLUENCE OF DONOR STRENGTH
Keyword(s):
The charge-transfer transition energies for a series of methylbenzene–tetracyanoethylene complexes in four solvents are reported. The charge-transfer transition energies are found to decrease with increasing solvent refractive index. The magnitude of the decrease appears to be a function of donor strength. It is inferred that the excited state dipole moment decreases with increasing donor strength for these complexes.
1975 ◽
Vol 30
(3)
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pp. 287-291
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1998 ◽
Vol 69
(8)
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pp. 2875-2887
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2015 ◽
Vol 1068
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pp. 123-127
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Keyword(s):
The Dipole Moment and Polarizability in then–π*Excited State of Acetone from Spectral Solvent Shifts
1966 ◽
Vol 39
(5)
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pp. 936-939
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1998 ◽
Vol 94
(24)
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pp. 3573-3576
Keyword(s):
1983 ◽
Vol 87
(22)
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pp. 4348-4351
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1971 ◽
Vol 55
(9)
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pp. 4668-4669
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