A Stereospecific Synthesis of L-Desosamine
Keyword(s):
L-Desosamine (3,4,6-trideoxy-3-dimethylamino-L-xylo-hexose), the enantiomer of a widely distributed antibiotics component, was synthesized by borohydride reduction of methyl 3,4,6-trideoxy-3-nitro-α-L-erythro-hex-3-enopyranoside followed by catalytic hydrogenation of the nitro group, N,N-dimethylation of the resulting saturated amino glycoside, and acid hydrolysis of the glycosidic bond.
1980 ◽
Vol 58
(16)
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pp. 1751-1758
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1982 ◽
Vol 47
(1)
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pp. 173-189
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2004 ◽
Vol 26
(5)
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pp. 473-483
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1982 ◽
Vol 47
(10)
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pp. 2786-2805
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1968 ◽
Vol 46
(19)
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pp. 3061-3069
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