Unusual formation of N-(1-isoquinolinyl)benzamide from 1-o-and 1-m-chlorobenzoylisoquinolines

1977 ◽  
Vol 55 (3) ◽  
pp. 435-437 ◽  
Author(s):  
D. Prasad Aysola ◽  
Martin S. Gibson
Keyword(s):  
Unusual Formation

Syntheses of 1-o- and 1-m-chlorobenzoylisoquinolines are described, (a) from 2-benzoyl-1,2-dihydroisoquinoline-1-carbonitrile and the appropriate chlorobenzaldehyde, and (b) from 2-o- and 2-m-chlorobenzoyl-2-dihydroisoquinoline-1-carbonitrile. Treatment of either ketone with potassamide - potassium tert-butoxide in ammonia gives N-(1-isoquinolinyObenzamide. The mechanism of this reaction is discussed.

An Unusual Formation of the Superficial Palmar Arch and its Clinical Significance

2017 ◽  
Vol 3 (1) ◽  
Author(s):  
Georgi Kotov ◽  
Alexandar Iliev ◽  
Georgi P. Georgiev ◽  
Boycho Landzhov
Keyword(s):  
Clinical Significance ◽  
Superficial Palmar Arch ◽  
Palmar Arch ◽  
Unusual Formation

Unusual formation of α-Fe2O3 hexagonal nanoplatelets in N-doped sandwiched graphene chamber for high-performance lithium-ions batteries

Nano Energy ◽  
2013 ◽  
Vol 2 (2) ◽  
pp. 257-267 ◽  
Author(s):  
Xi Wang ◽  
Wei Tian ◽  
Dequan Liu ◽  
Chunyi Zhi ◽  
Yoshio Bando ◽  
...  
Keyword(s):  
High Performance ◽  
Lithium Ions ◽  
Unusual Formation

scholarly journals Frontispiece: Unusual Formation of CoSe@carbon Nanoboxes, which have an Inhomogeneous Shell, for Efficient Lithium Storage

2016 ◽  
Vol 55 (33) ◽  
Author(s):  
Han Hu ◽  
Jintao Zhang ◽  
Buyuan Guan ◽  
Xiong Wen David Lou
Keyword(s):  
Lithium Storage ◽  
Inhomogeneous Shell ◽  
Unusual Formation

XIII. A description of a very unusual formation of the human heart

1798 ◽  
Vol 88 ◽  
pp. 346-356 ◽  
Keyword(s):  
Human Body ◽  
Human Heart ◽  
Natural Form ◽  
Perfect Knowledge ◽  
Learned Societies ◽  
Circulation Of The Blood ◽  
Unusual Formation

T he heart is an organ of so much importance in the animal oeconomy, and is so immediately concerned in the support of life, that any unusual deviation from its natural form and situation in the human body, has always been considered as a subject of some interest by the physiologist; such deviations have, therefore, not unfrequently been submitted to the consideration of this and other learned Societies. Many circumstances respecting the circulation of the blood, and respiration, wholly unknown to our ancestors, have lately been ascertained; but we are not as yet arrived at a perfect knowledge of these important actions. Difficulties yet remain; more information may still be acquired; and the reasoning upon these subjects will be less liable to fallacy, in proportion to the number of facts which have been observed, and the accuracy of the observations.

scholarly journals Unusual formation of (E)-11-(aminomethylene)-8,9,10,11-tetrahydropyrido[2′,3′:4,5]pyrimido[1,2-a]azepin-5(7H)-one and its crystal structure

2017 ◽  
Vol 73 (10) ◽  
pp. 1497-1500
Author(s):  
Khamid U. Khodjaniyazov ◽  
Utkir S. Makhmudov ◽  
Kambarali K. Turgunov ◽  
Burkhon Z. Elmuradov
Keyword(s):  
Crystal Structure ◽  
Structural Analysis ◽  
Aqueous Ammonia ◽  
Boat Conformation ◽  
X Ray ◽  
First Time ◽  
Twist Boat ◽  
Unusual Formation

Selective C-formylation of 8,9,10,11-tetrahydropyrido[2′,3′:4,5]pyrimido[1,2-a]-azepin-5(7H)-one has been studied for the first time. It was revealed that formylation proceeds by the formation of an intermediate salt, which due to the re-amination process on treatment with aqueous ammonia transformed into the corresponding (E)-11-(aminomethylene)-8,9,10,11-tetrahydropyrido[2′,3′:4,5]-pyrimido[1,2-a]azepin-5(7H)-one, C13H14N4O, as anE-isomer. Formylation was carried out by Vilsmeier–Haack reagent and the structure of the synthesized compound was confirmed by X-ray structural analysis, spectroscopic and LC–MS methods. In the molecule, the seven-membered pentamethylene ring adopts a twist-boat conformation.

A general benzylic C–H activation and C–C coupling reaction of zirconocenes mediated by C–N bond cleavage in tert-butylisocyanide – unusual formation of iminoacyl complexes

2019 ◽  
Vol 48 (44) ◽  
pp. 16525-16533
Author(s):  
Perdita Arndt ◽  
Melanie Reiß ◽  
Anke Spannenberg ◽  
Claas Schünemann ◽  
Fabian Reiß ◽  
...  
Keyword(s):  
Bond Cleavage ◽  
Coupling Reaction ◽  
Unusual Formation

Reactions of the zirconocene alkyne complex [rac-(ebthi)Zr(η2-Me3SiC2SiMe3)] (rac-(ebthi) = rac-1,2-ethylene-1,1′-bis(η5-tetrahydroindenyl)) with tert-butylisocyanide and methylbenzenes were investigated.

scholarly journals Unusual Formation of Point-Defect Complexes in the Ultrawide-Band-Gap Semiconductor β−Ga2O3

2019 ◽  
Vol 9 (4) ◽  
Author(s):  
Jared M. Johnson ◽  
Zhen Chen ◽  
Joel B. Varley ◽  
Christine M. Jackson ◽  
Esmat Farzana ◽  
...  
Keyword(s):  
Point Defect ◽  
Band Gap ◽  
Defect Complexes ◽  
Unusual Formation

Renal High-Molecular-Weight Renin: Unusual Formation in the Aged Stroke-Prone Spontaneously Hypertensive Rats

1986 ◽  
Vol 9 (3) ◽  
pp. 177-186 ◽  
Author(s):  
Satoko Itoh ◽  
Motoharu Tanaka ◽  
Fumihiko Ikemoto ◽  
Kenjiro Yamamoto ◽  
Nobuko Morita ◽  
...  
Keyword(s):  
Molecular Weight ◽  
High Molecular Weight ◽  
Spontaneously Hypertensive Rats ◽  
Hypertensive Rats ◽  
Spontaneously Hypertensive ◽  
Unusual Formation
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