Excess molar volumes of mixtures containing methyl alkanoates (acetate, propanoate, and butanoate) with normal alkanols (from ethanol to pentan-1-ol)

1989 ◽  
Vol 67 (6) ◽  
pp. 1120-1124 ◽  
Author(s):  
J. Ortega ◽  
P. Susial
Keyword(s):  
Binary Mixtures ◽  
Excess Molar Volumes ◽  
Molar Volumes ◽  
Vibrating Tube Densimeter

Measurements of νE for binary mixtures of CmH2m+1CO2CH3 (m = 1,2,3) + CnH2n+1(OH) (n = 2,3,4,5) are reported. The results have been determined by using the densities obtained in a vibrating tube densimeter at 298.15 K, they are positive for all these systems. The data have also been compared with available literature values with a discussion on these mixtures. Keywords: excess molar mixtures, methyl alkanoates, normal alkanols.

Excess molar volumes of binary mixtures of 2-hexanone with n-alkane at 298.15 K

1985 ◽  
Vol 63 (12) ◽  
pp. 3354-3356 ◽  
Author(s):  
J. Ortega ◽  
M. I. Paz-Andrade ◽  
E. Rodriguez-Nunez ◽  
E. Jimenez
Keyword(s):  
Binary Mixtures ◽  
Alkyl Group ◽  
Composition Range ◽  
Excess Molar Volumes ◽  
Entire Composition Range ◽  
Molar Volumes ◽  
Hexane System ◽  
Vibrating Tube Densimeter

The excess molar volumes, [Formula: see text], of 2-hexanone (MBK) with n-hexane, n-heptane, n-octane, n-nonane, n-decane, n-undecane, n-dodecane, and n-tridecane have been obtained at 298.15 K from densities measured with a vibrating tube densimeter. The [Formula: see text] are positive over the entire composition range in all mixtures, with the exception of the MBK + n-hexane system, where an inversion of the sign of [Formula: see text] is observed. In other systems, [Formula: see text] increases with increasing size of the alkyl group in n-alkane.

scholarly journals Densities and excess molar volumes of alcohol + cyclohexylamine mixtures

2009 ◽  
Vol 74 (11) ◽  
pp. 1303-1318 ◽  
Author(s):  
Ivona Radovic ◽  
Mirjana Kijevcanin ◽  
Aleksandar Tasic ◽  
Bojan Djordjevic ◽  
Slobodan Serbanovic
Keyword(s):  
Binary Mixtures ◽  
Atmospheric Pressure ◽  
Excess Molar Volumes ◽  
Molar Volumes ◽  
System 2 ◽  
Vibrating Tube Densimeter

Densities of binary mixtures of 1-propanol, or 2-butanol, or 1-pentanol + cyclohexylamine were measured at temperatures from 288.15 to 313.15 K and atmospheric pressure, while the densities for the system 2-methyl-2-propanol + cyclohexylamine were measured at temperatures from 303.15 to 323.15 K and atmospheric pressure. All measurements were performed using an Anton Paar DMA 5000 digital vibrating-tube densimeter. From the experimental densities, the excess molar volumes, VE, were calculated.

scholarly journals Densities, refractive indices and viscosities of the binary mixtures of dimethyl phthalate or dimethyl adipate with tetrahydrofuran

2014 ◽  
Vol 79 (1) ◽  
pp. 77-87 ◽  
Author(s):  
Andjela Knezevic-Stevanovic ◽  
Jelena Smiljanic ◽  
Slobodan Serbanovic ◽  
Ivona Radovic ◽  
Mirjana Kijevcanin
Keyword(s):  
Binary Mixtures ◽  
Atmospheric Pressure ◽  
Excess Molar Volumes ◽  
Refractive Indices ◽  
Dimethyl Phthalate ◽  
Molar Volumes ◽  
Viscosity Deviations ◽  
Dimethyl Adipate ◽  
Vibrating Tube Densimeter

Densities, refractive indices and viscosities of the binary mixtures of dimethyl phthalate (or dimethyl adipate) + tetrahydrofuran have been measured at eight temperatures (288.15 to 323.15 K) and atmospheric pressure. All measurements were performed using an Anton Paar DMA 5000 digital vibrating-tube densimeter, Anton Paar RXA 156 refractometer and Anton Paar SVM 3000/G2 digital Stabinger viscometer, respectively. From the experimental densities, refractive indices and viscosities, the excess molar volumes, VE, deviations of refractive indices, DnD, and viscosity deviations, Dh, were calculated.

Excess volumes and refractive indices in the benzene-tert-amyl methyl ether and cyclohexane-tert-amyl methyl ether systems at 298.15 K

1987 ◽  
Vol 52 (12) ◽  
pp. 2839-2843 ◽  
Author(s):  
Jan Linek
Keyword(s):  
Methyl Ether ◽  
Excess Molar Volumes ◽  
Excess Volumes ◽  
Refractive Indices ◽  
Molar Volumes ◽  
Vibrating Tube Densimeter ◽  
Ether System

Excess molar volumes in the benzene-tert-amyl methyl ether and cyclohexane-tert-amyl methyl ether systems were measured by a vibrating-tube densimeter at 298.15 K and compared with the data for the methanol-tert-amyl methyl ether system determined previously. Besides, the refractive indices in both the systems were measured at the same temperature.

Excess molar volumes of n-alkanol (C1-C5) binary mixtures with acetonitrile

1986 ◽  
Vol 31 (2) ◽  
pp. 152-154 ◽  
Author(s):  
Jagjit S. Sandhu ◽  
Ashok K. Sharma ◽  
Ramesh K. Wadi
Keyword(s):  
Binary Mixtures ◽  
Excess Molar Volumes ◽  
Molar Volumes

scholarly journals Prediction of excess molar volumes of selected binary mixtures from refractive index data

2014 ◽  
Vol 79 (6) ◽  
pp. 707-718 ◽  
Author(s):  
Jelena Vuksanovic ◽  
Divna Bajic ◽  
Gorica Ivanis ◽  
Emila Zivkovic ◽  
Ivona Radovic ◽  
...  
Keyword(s):  
Refractive Index ◽  
Binary Mixtures ◽  
Excess Molar Volumes ◽  
Mixing Rules ◽  
Mixing Rule ◽  
Molar Volumes ◽  
Index Data ◽  
Peg 400 ◽  
Benzene Toluene ◽  
Refractive Index Data

The excess molar volumes of twenty two binary mixtures containing various groups of organic compounds: alcohols (ethanol, 1-propanol, 1,2-propanediol, 1,3-propanediol and glycerol), ketone (acetone), ester (butyl lactate), lactam (N-methyl-2-pyrrolidone), PEGs (PEG 200, PEG 400) and aromatics (benzene, toluene and pyridine) were predicted from the refractive index data, using three types of equations coupled with several mixing rules for refractive index calculations: the Lorentz-Lorenz, Dale-Gladstone, Eykman, Arago-Biot, Newton, and Oster. The obtained results were analysed in terms of the applied equation and mixing rule and the nature of interactions between the mixtures? components.

Densities, excess molar volumes, and refractive indices of ethyl acetate and aromatic hydrocarbon binary mixtures

2002 ◽  
Vol 34 (7) ◽  
pp. 995-1004 ◽  
Author(s):  
J.M. Resa ◽  
C. González ◽  
S. Ortiz de Landaluce ◽  
J. Lanz
Keyword(s):  
Aromatic Hydrocarbon ◽  
Ethyl Acetate ◽  
Binary Mixtures ◽  
Excess Molar Volumes ◽  
Refractive Indices ◽  
Molar Volumes
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