scholarly journals New paradigm for glassy-like anomalies in solids from fundamental symmetries

2021 ◽  
Vol 35 (04) ◽  
pp. 2130002
Author(s):  
Matteo Baggioli ◽  
Alessio Zaccone

Glasses and disordered materials are known to display anomalous features in the density of states, in the specific heat and in thermal transport. Nevertheless, in recent years, the question whether these properties are really anomalous (and peculiar of disordered systems) or rather more universal than previously thought, has emerged. New experimental and theoretical observations have questioned the origin of the boson peak (BP) and the linear in T specific heat exclusively from disorder and two-level systems (TLS). The same properties have been indeed observed in ordered or minimally disordered compounds and in incommensurate structures for which the standard explanations are not applicable. Using the formal analogy between phason modes (e.g., in quasicrystals and incommensurate lattices) and diffusions, and between amplitude modes and optical phonons, we suggest the existence of a more universal physics behind these properties. In particular, we strengthen the idea that linear in T specific heat is linked to low energy diffusive modes resulting from fundamental symmetries, and that a BP excess can be induced in crystals either by gapped optical-like modes and/or by anharmonic diffusive (Akhiezer) damping.

2021 ◽  
Vol 7 (20) ◽  
pp. eabe3392
Author(s):  
Erin G. Teich ◽  
K. Lawrence Galloway ◽  
Paulo E. Arratia ◽  
Danielle S. Bassett

The nature of yield in amorphous materials under stress has yet to be fully elucidated. In particular, understanding how microscopic rearrangement gives rise to macroscopic structural and rheological signatures in disordered systems is vital for the prediction and characterization of yield and the study of how memory is stored in disordered materials. Here, we investigate the evolution of local structural homogeneity on an individual particle level in amorphous jammed two-dimensional (athermal) systems under oscillatory shear and relate this evolution to rearrangement, memory, and macroscale rheological measurements. We define the structural metric crystalline shielding, and show that it is predictive of rearrangement propensity and structural volatility of individual particles under shear. We use this metric to identify localized regions of the system in which the material’s memory of its preparation is preserved. Our results contribute to a growing understanding of how local structure relates to dynamic response and memory in disordered systems.


1987 ◽  
Vol 56 (2) ◽  
pp. 227-236 ◽  
Author(s):  
A. Avogadro ◽  
S. Aldrovandi ◽  
F. Borsa ◽  
G. Carini
Keyword(s):  

2008 ◽  
Vol 42 (1) ◽  
pp. 69-84 ◽  
Author(s):  
J. R. Stewart ◽  
P. P. Deen ◽  
K. H. Andersen ◽  
H. Schober ◽  
J.-F. Barthélémy ◽  
...  

The technique of longitudinal neutron polarization analysis on a multi-detector neutron spectrometer (so-called `xyz'-polarization analysis) is presented. This technique allows the simultaneous and unambiguous determination of the nuclear, magnetic and nuclear spin-incoherent scattering cross sections as a function of both momentum transfer and energy transfer. The implementation ofxyz-polarization analysis on the recently upgraded D7 spectrometer at the Institut Laue–Langevin in Grenoble is described. Several examples of neutron polarization analysis studies of disordered systems on D7 are given, illustrating the valuable information which can be retrieved from the analysis of neutron diffraction patterns between the Bragg peaks.


2020 ◽  
Vol 12 (4) ◽  
pp. 529-544
Author(s):  
Gennady V. Mishinsky ◽  

The discoveries of new low-energy nuclear reactions and a new resonant interference exchange interaction explaining the course of these reactions give grounds to assert that a necessary and inevitable process of changing the paradigm is currently taking place.


Science ◽  
2018 ◽  
Vol 360 (6396) ◽  
pp. 1455-1458 ◽  
Author(s):  
Saikat Mukhopadhyay ◽  
David S. Parker ◽  
Brian C. Sales ◽  
Alexander A. Puretzky ◽  
Michael A. McGuire ◽  
...  

Solids with ultralow thermal conductivity are of great interest as thermal barrier coatings for insulation or thermoelectrics for energy conversion. However, the theoretical limits of lattice thermal conductivity (κ) are unclear. In typical crystals a phonon picture is valid, whereas lowest κ values occur in highly disordered materials where this picture fails and heat is supposedly carried by random walk among uncorrelated oscillators. Here we identify a simple crystal, Tl3VSe4, with a calculated phonon κ [0.16 Watts per meter-Kelvin (W/m-K)] one-half that of our measured κ (0.30 W/m-K) at 300 K, approaching disorder κ values, although Raman spectra, specific heat, and temperature dependence of κ reveal typical phonon characteristics. Adding a transport component based on uncorrelated oscillators explains the measured κ and suggests that a two-channel model is necessary for crystals with ultralow κ.


1988 ◽  
Vol 37 (10) ◽  
pp. 5787-5805 ◽  
Author(s):  
Werner Uhler ◽  
Rolf Schilling

1997 ◽  
Vol 478 ◽  
Author(s):  
D. Mandrus ◽  
B. C. Sales ◽  
V. Keppens ◽  
B. C. Chakoumakos ◽  
P. Dai ◽  
...  

AbstractAfter a brief review of the transport and thermoelectric properties of filled skutterudite antimonides, we present resonant ultrasound, specific heat, and inelastic neutron scattering results that establish the existence of two low-energy vibrational modes in the filled skutterudite LaFe3CoSb12. It is likely that at least one of these modes represents the localized, incoherent vibrations of the La ion in an oversized atomic “cage.” These results support the usefulness of weakly bound, “rattling” ions for the improvement of thermoelectric performance.


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