NOVEL ANODE Li-ION SECONDARY BATTERIES DERIVED FROM NANOCRYSTALLINE Li4Ti5O12/POLYACENE MATERIALS

2009 ◽  
Vol 08 (04n05) ◽  
pp. 333-336
Author(s):  
ABRAHAM F. JALBOUT ◽  
HAI-MING XIE ◽  
RONG-SHUN WANG ◽  
LING-YUN ZHANG ◽  
HAI-YING YU ◽  
...  

Spinel lithium titanate ( Li4Ti5O12 ), shown to be a superior anode material for energy storage battery, has attracted a great deal of attention because of the excellent Li-ion insertion and extraction reversibility. The high rate characteristics must be amplified before large scale production. A method to overcome this is to prepare electrode materials coated with carbon. A Li4Ti5O12 /Polyacene (PAS) composite were first prepared via an in situ carbonization of phenol-formaldehyde (PF) resin route using TiO2 -anatase, Li2CO3 , and PF resin as precursors by a solid-state reaction. With increasing the current density, the sample still keeps the excellent cycle performance.

2011 ◽  
Vol 15 (1) ◽  
pp. 5-10
Author(s):  
Jie Xu ◽  
Chunju Lv ◽  
Guanglei Tian

Spinel lithium titanate (Li4Ti5O12) materials were synthesized by a hydrolysis precipitation-assisted solid-state method in the temperature range from 600 to 900℃ for large-scale production. DSC/TGA, XRD and SEM were used to characterize the as-prepared samples. The optimum synthesis condition was examined in relation to the charge–discharge performance. It was found that when the dry hydrolysis precipitation precursor with 8% Li excess was calcined at 700–800℃ for 12 h in air, a pure Li4Ti5O12 phase was obtained. The as-obtained material has the best electrochemical performance due to its narrow size distribution and precise stoichiometry of the oxide.


2018 ◽  
Vol MA2018-01 (31) ◽  
pp. 1840-1840
Author(s):  
Xiaobo Chen

Hydrogen production through electrolysis has been regarded as one of the most promising solutions for large-scale production of clean fuels. However, most electrodes have large overpotentials in the HER and OER reactions during the water splitting process. Many approaches and methods have been developed to enhance the electrodes' performance. Here, we would like to present our studies on the hydrogenation of various electrode materials for HER and OER applications. We aim to reveal the structure-property-performance relationship for those electrodes after hydrogenation treatment. We wish our work could provide useful information and will be honored if our work can inspire new discovery and finding in the related fields to advance our understanding and technologies for efficient hydrogen production through electrolysis.


RSC Advances ◽  
2015 ◽  
Vol 5 (47) ◽  
pp. 37830-37836 ◽  
Author(s):  
Wei Wei ◽  
Linlin Guo ◽  
Xiaoyang Qiu ◽  
Peng Qu ◽  
Maotian Xu ◽  
...  

Although many routes have been developed that can efficiently improve the electrochemical performance of LiFePO4 cathodes, few of them meet the urgent industrial requirements of large-scale production, low cost and excellent performance.


2014 ◽  
Vol 07 (06) ◽  
pp. 1440008 ◽  
Author(s):  
Linlin Wang ◽  
Kaibin Tang ◽  
Min Zhang ◽  
Xiaozhu Zhang ◽  
Jingli Xu

Particle size effects on the electrochemical performance of the CuO particles toward lithium are essential. In this work, a low-cost, large-scale production but simple approach has been developed to fabricate CuO nanoparticles with an average size in ~ 130 nm through thermolysis of Cu ( OH )2 precursors. As anode materials for lithium ion batteries (LIBs), the CuO nanoparticles deliver a high reversible capacity of 540 mAh g-1 over 100 cycles at 0.5 C. It also exhibits a rate capacity of 405 mAh g-1 at 2 C. These results suggest that the facile synthetic method of producing the CuO nanoparticles can enhance cycle performance, superior to that of some different sizes of the CuO nanoparticles and many reported CuO -based anodes.


ChemSusChem ◽  
2013 ◽  
Vol 6 (6) ◽  
pp. 1084-1090 ◽  
Author(s):  
Haitao Zhang ◽  
Xiong Zhang ◽  
Xianzhong Sun ◽  
Dacheng Zhang ◽  
He Lin ◽  
...  

2021 ◽  
Vol 9 (38) ◽  
pp. 21981-21994
Author(s):  
Haruki Kaneda ◽  
Yuki Furuichi ◽  
Atsunori Ikezawa ◽  
Hajime Arai

Nano-scale Al-rich layers on the surface of LiNi0.92Al0.08O2 and substituted-Al in the crystal suppress both the surface degradation and bulk degradation, resulting in the excellent cycling performance Ni-rich electrode material.


Nanoscale ◽  
2016 ◽  
Vol 8 (3) ◽  
pp. 1413-1420 ◽  
Author(s):  
Bingna Zheng ◽  
Zhen Xu ◽  
Chao Gao

The large scale production of high quality graphene nanoscrolls (GNS) is achieved using a spray-freeze-drying method. With the intercalation of GNS, the all-graphene films exhibit high specific capacitance together with excellent rate performance.


2019 ◽  
Vol 7 (40) ◽  
pp. 22958-22966 ◽  
Author(s):  
Shenghui Shen ◽  
Shengzhao Zhang ◽  
Shengjue Deng ◽  
Guoxiang Pan ◽  
Yadong Wang ◽  
...  

Herein, we firstly proposed multidimensional titanium niobium oxides (1D/2D/3D-TNO) via a versatile bioinspired template method, which employed as high-performance anodes for both liquid and solid state lithium ion batteries


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