Influence of the spacer in bis-porphyrinic tweezers on the association constant for host/guest complexes

2005 ◽  
Vol 09 (11) ◽  
pp. 779-787 ◽  
Author(s):  
Nathalie Solladié ◽  
Souhaila Bouatra ◽  
Sonja Merkas ◽  
Régis Rein ◽  
Jéröme Roeser
Keyword(s):  
Binding Constant ◽  
Association Constant ◽  
Association Constants ◽  
Synthesis And Characterization ◽  
Rapid Synthesis ◽  
High Association ◽  
Complexation Studies

Detailed complexation studies of two rigid tweezers bearing mono- or tris-anthracenic spacers is reported, along with the synthesis and characterization of two new tweezers bearing flexible nucleosidic linkers. For flexible tweezers bearing the two porphyrins at O -5' and O -3' positions of the ribose, the association constant for the complexation of DABCO increases, when compared to the association constant for the same base with a reference mono-porphyrin. The nucleoside seems to confer sufficient preorganization to this dimer to enhance the binding constant, documenting the fact that rigid dimers are not necessary for preorganization, and opening new routes to the rapid synthesis of flexible tweezers capable of complexing guests with high association constants.

Rapid Synthesis and Characterization of CuInS2 Prepared Using Microwave-Assisted Heating

2015 ◽  
Vol 775 ◽  
pp. 143-146
Author(s):  
Ming Kwen Tsai ◽  
Yueh Chien Lee ◽  
Chia Chih Huang ◽  
Sheng Yao Hu ◽  
Kwong Kau Tiong ◽  
...  
Keyword(s):  
Synthesis And Characterization ◽  
X Ray Diffraction ◽  
Structural And Optical Properties ◽  
Rapid Synthesis ◽  
X Ray ◽  
Sem Image ◽  
Microwave Assisted ◽  
Calcination Treatment ◽  
Scanning Electron

In this work, the CuInS2 nanoparticles are successfully synthesized by microwave-assisted heating technique and further calcined at 400 °C. The morphological, structural, and optical properties of the synthesized CuInS2 nanoparticles are investigated by scanning electron microscope (SEM), X-ray diffraction (XRD), Raman scattering, and transmittance measurement, respectively. The SEM image shows the clear particle shape of the calcined CuInS2 nanoparticles. After calcination treatment, the fundamental (112) peak of the XRD spectrum and a broad Raman peak mixed with chalcopyrite and CuAu structures support the improved crystallinity of the calcined CuInS2 nanoparticles.

Rapid synthesis and characterization of aluminophosphate molecular sieve: EMM-8

2008 ◽  
Vol 62 (6-7) ◽  
pp. 929-931 ◽  
Author(s):  
Shivanand M. Pai ◽  
Bharat L. Newalkar ◽  
Nettem V. Choudary
Keyword(s):  
Molecular Sieve ◽  
Synthesis And Characterization ◽  
Rapid Synthesis

Self-propagating rapid synthesis and characterization of LaCrO3 powder

2020 ◽  
Vol 259 ◽  
pp. 126873 ◽  
Author(s):  
Dayan Xie ◽  
Kuibao Zhang ◽  
Weiwei Li ◽  
Baozhu Luo ◽  
Haibin Zhang
Keyword(s):  
Synthesis And Characterization ◽  
Rapid Synthesis

Rapid synthesis and characterization of micro and nanostructures of molybdenum trioxide

2013 ◽  
Author(s):  
Viorel Trofim ◽  
Vasilii Cretu ◽  
Oleg Lupan ◽  
Mihai Enachi ◽  
Eduard Monaico ◽  
...  
Keyword(s):  
Molybdenum Trioxide ◽  
Synthesis And Characterization ◽  
Rapid Synthesis

Rapid synthesis and characterization of monolithic ambient pressure dried MTMS aerogels in pure water

2020 ◽  
Vol 27 (4) ◽  
pp. 1241-1251 ◽  
Author(s):  
Siqi Huang ◽  
Xiaoxu Wu ◽  
Zhi Li ◽  
Long Shi ◽  
Yan Zhang ◽  
...  
Keyword(s):  
Ambient Pressure ◽  
Pure Water ◽  
Synthesis And Characterization ◽  
Rapid Synthesis

Rapid synthesis and characterization of hybrid ZnO@Au core–shell nanorods for high performance, low temperature NO 2 gas sensor applications

2015 ◽  
Vol 355 ◽  
pp. 726-735 ◽  
Author(s):  
Dinesh Veeran Ponnuvelu ◽  
Biji Pullithadathil ◽  
Arun K. Prasad ◽  
Sandip Dhara ◽  
Anuradha Ashok ◽  
...  
Keyword(s):  
Low Temperature ◽  
Gas Sensor ◽  
High Performance ◽  
Synthesis And Characterization ◽  
Core Shell ◽  
Rapid Synthesis ◽  
Sensor Applications
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