Structure and optical properties of fullerene C60 complex with dipyridinated iron(II) phthalocyanine [Fe(II)Pc(C5H5N)2]·C60·4C6H4Cl2: First structure of bisaxially coordinated iron(II) phthalocyanine complex with acetonitrile Fe(II)Pc(CH3CN)2

2014 ◽  
Vol 18 (01n02) ◽  
pp. 87-93 ◽  
Author(s):  
Dmitri V. Konarev ◽  
Alexey V. Kuzmin ◽  
Sergey V. Simonov ◽  
Salavat S. Khasanov ◽  
Rimma N. Lyubovskaya
Keyword(s):  
Optical Properties ◽  
Charge Transfer ◽  
Bond Length ◽  
Single Crystals ◽  
Fullerene C60 ◽  
Metal Phthalocyanine ◽  
Phthalocyanine Complex ◽  
Uv Visible ◽  
Center Distance ◽  
Molecular Solid

The complex of fullerene C 60 with dipyridinated iron(II) phthalocyanine [ Fe ( II ) Pc ( C 5 H 5 N )2]· C 60·4 C 6 H 4 Cl 2 (1) has been obtained as single crystals. According to the IR- and UV-visible-NIR spectra, 1 is molecular solid with no charge transfer from Fe ( II ) Pc ( C 5 H 5 N )2 to C 60· C 60 molecules form closely packed linear columns in 1 along the b axis with a uniform interfullerene center-to center distance of 9.99 Å and multiple short van der Waals (vdW) C … C contacts between fullerenes of 3.10–3.18 Å. Totally each Fe ( II ) Pc ( C 5 H 5 N )2 unit is surrounded by four C 60 molecules two of which form short vdW C … C contacts with the phthalocyanine plane locating near two adjacent phenylene substituents of Fe ( II ) Pc . The Fe ( II ) Pc ( C 5 H 5 N )2 geometry remains almost unchanged as compared with that of fullerene free Fe ( II ) Pc ( C 5 H 5 N )2. The iron(II) atoms are located exactly in the Pc plane, the Fe - N ( C 5 H 5 N ) bond length is 2.038(3) Å and the averaged of the Fe - N ( Pc ) bond length is 1.935(3) Å. Bisaxially coordinated iron(II) phthalocyanine complex with acetonitrile Fe ( II ) Pc ( CH 3 CN )2 does not cocrystallize with C 60. Nevertheless, good quality crystals of [ Fe ( II ) Pc ( CH 3 CN )2]·2 C 6 H 4 Cl 2 (2) were isolated in this synthesis. That is the first structure of bisaxially coordinated metal phthalocyanine complex with nitrile containing solvent. Acetonitrile unusually strongly coordinates to Fe ( II ) Pc with the Fe – N ( CH 3 CN ) bond length of 1.938(1) Å. The iron(II) atoms are located in the Pc plane and the averaged length of the Fe - N ( Pc ) bonds is 1.934(1) Å.

Optical properties of α-ZnAl2S4:Cr single crystals

1998 ◽  
Vol 84 (1) ◽  
pp. 533-540 ◽  
Author(s):  
I. Broussell ◽  
E. Fortin ◽  
L. Kulyuk ◽  
S. Popov ◽  
A. Anedda ◽  
...  
Keyword(s):  
Optical Properties ◽  
Single Crystals

Effect of Mn3+ doping on crystal structure, point defects, and optical properties in green Ca3(VO4)2 single crystals

2021 ◽  
pp. 111300
Author(s):  
Galina M. Kuz’micheva ◽  
Liudmila. I. Ivleva ◽  
Irina A. Kaurova ◽  
Evgeny V. Khramov ◽  
Victor B. Rybakov ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Optical Properties ◽  
Single Crystals ◽  
Point Defects

scholarly journals Polymer Composites with 0.98 Transparencies and Small Optical Energy Band Gap Using a Promising Green Methodology: Structural and Optical Properties

Polymers ◽  
2021 ◽  
Vol 13 (10) ◽  
pp. 1648
Author(s):  
Muaffaq M. Nofal ◽  
Shujahadeen B. Aziz ◽  
Jihad M. Hadi ◽  
Wrya O. Karim ◽  
Elham M. A. Dannoun ◽  
...  
Keyword(s):  
Refractive Index ◽  
Optical Properties ◽  
Polymer Composites ◽  
Amorphous Phase ◽  
Absorption Edge ◽  
Complex Form ◽  
Bandgap Energy ◽  
Optical Parameters ◽  
Visible Spectroscopy ◽  
Uv Visible

In this work, a green approach was implemented to prepare polymer composites using polyvinyl alcohol polymer and the extract of black tea leaves (polyphenols) in a complex form with Co2+ ions. A range of techniques was used to characterize the Co2+ complex and polymer composite, such as Ultraviolet–visible (UV-Visible) spectroscopy, Fourier transform infrared spectroscopy (FTIR), and X-ray diffraction (XRD). The optical parameters of absorption edge, refractive index (n), dielectric properties including real and imaginary parts (εr, and εi) were also investigated. The FRIR and XRD spectra were used to examine the compatibility between the PVA polymer and Co2+-polyphenol complex. The extent of interaction was evidenced from the shifts and change in the intensity of the peaks. The relatively wide amorphous phase in PVA polymer increased upon insertion of the Co2+-polyphenol complex. The amorphous character of the Co2+ complex was emphasized with the appearance of a hump in the XRD pattern. From UV-Visible spectroscopy, the optical properties, such as absorption edge, refractive index (n), (εr), (εi), and bandgap energy (Eg) of parent PVA and composite films were specified. The Eg of PVA was lowered from 5.8 to 1.82 eV upon addition of 45 mL of Co2+-polyphenol complex. The N/m* was calculated from the optical dielectric function. Ultimately, various types of electronic transitions within the polymer composites were specified using Tauc’s method. The direct bandgap (DBG) treatment of polymer composites with a developed amorphous phase is fundamental for commercialization in optoelectronic devices.

Scintillation and optical properties of Ce 3+ -doped CaGdAl 3 O 7 single crystals

2017 ◽  
Vol 186 ◽  
pp. 93-97 ◽  
Author(s):  
Masaki Mori ◽  
Daisuke Nakauchi ◽  
Go Okada ◽  
Yutaka Fujimoto ◽  
Noriaki Kawaguchi ◽  
...  
Keyword(s):  
Optical Properties ◽  
Single Crystals

Optical Properties of Ion Accumulation Areas in MAPbX 3 Single Crystals

2021 ◽  
pp. 2100850
Author(s):  
Ziqi Zhang ◽  
Ruyan Kang ◽  
Pengpeng Cheng ◽  
Zehan Liu ◽  
Zhiyuan Zuo
Keyword(s):  
Optical Properties ◽  
Single Crystals ◽  
Ion Accumulation

scholarly journals Twisted One-Dimensional Charge Transfer and Related Y-Shaped Chromophores with a 4H-Pyranylidene Donor: Synthesis and Optical Properties

2021 ◽  
Vol 86 (4) ◽  
pp. 3152-3163
Author(s):  
Víctor Tejeda-Orusco ◽  
Raquel Andreu ◽  
Jesús Orduna ◽  
Belén Villacampa ◽  
Santiago Franco ◽  
...  
Keyword(s):  
Optical Properties ◽  
Charge Transfer ◽  
One Dimensional

scholarly journals Synthesis and Photobehavior of a NewDehydrobenzoannulene-Based HOF with Fluorine Atoms: From Solution to Single Crystals Observation

2021 ◽  
Vol 22 (9) ◽  
pp. 4803
Author(s):  
Eduardo Gomez ◽  
Ichiro Hisaki ◽  
Abderrazzak Douhal
Keyword(s):  
Charge Transfer ◽  
Single Crystals ◽  
Parent Compound ◽  
Time Resolved ◽  
Strong Basis ◽  
Triplet Structure ◽  
Carboxylic Groups ◽  
Potential Applications ◽  
A Charge ◽  
Further Development

Hydrogen-bonded organic frameworks (HOFs) are the focus of intense scientific research due their potential applications in science and technology. Here, we report on the synthesis, characterization, and photobehavior of a new HOF (T12F-1(124TCB)) based on a dehydrobenzoannulene derivative containing fluorine atoms (T12F-COOH). This HOF exhibits a 2D porous sheet, which is hexagonally networked via H-bonds between the carboxylic groups, and has an interlayers distance (4.3 Å) that is longer than that of a typical π–π interaction. The presence of the fluorine atoms in the DBA molecular units largely increases the emission quantum yield in DMF (0.33, T12F-COOH) when compared to the parent compound (0.02, T12-COOH). The time-resolved dynamics of T12F-COOH in DMF is governed by the emission from a locally excited state (S1, ~ 0.4 ns), a charge-transfer state (S1(CT), ~ 2 ns), and a room temperature emissive triplet state (T1, ~ 20 ns), in addition to a non-emissive triplet structure with a charge-transfer character (T1(CT), τ = 0.75 µs). We also report on the results using T12F-ester. Interestingly, FLIM experiments on single crystals unravel that the emission lifetimes of the crystalline HOF are almost twice those of the amorphous ones or the solid T12F-ester sample. This shows the relevance of the H-bonds in the photodynamics of the HOF and provides a strong basis for further development and study of HOFs based on DBAs for potential applications in photonics.

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