scholarly journals The use of sodium polytungstate for conodont separations

1988 ◽  
Vol 7 (1) ◽  
pp. 39-40 ◽  
Author(s):  
Norman M. Savage

Abstract. Most conodont workers use heavy liquids that are carcinogenic or toxic in other ways. The use of the non-toxic water-based liquid sodium polytungstate has not been widely accepted because of reports that its high viscosity prevents the more delicate conodonts from settling, that it tends to crystallise during use, and that it is more expensive than traditional liquids. If used in the manner described below, viscosity, cystallisation and cost are no longer problems. The overwhelming advantage of safety then makes sodium polytungstate the heavy liquid of choice for conodont work.

1989 ◽  
Vol 145 ◽  
pp. 11-13
Author(s):  
P Schiøler

Density separation of mineral and sediment grains into fractions using heavy liquids traditionally employs organic compounds such as bromoform (density 2.89) and tetrabromoethane (density 2.96) which are known to be toxic even at very low concentrations (Van Haaften, 1969) and possibly carcinogenic. In addition, the separated grains are washed with organic solvents such as acetone which may be highly inflammable, and are also a health risk. In recent years, a new water soluble compound, sodium polytungstate (SPT), 3Na2WO4.9WO3.H2O, has become available as a medium for heavy liquid separations, offering an alternative to the heavy organic liquids. Hs use has been discussed by several workers (e.g. Plewinsky & Kamp, 1984; Krukowski, 1988) in a variety of geological settings. The present note summarises experience in GGU's palaeontological laboratory gained from working with SPT for a full year as a replacement for tetrabromoethane and bromoform in the separation of phosphatic microfossils from samples principally of Lower - Middle Cambrian age. Apart from improving the work environment by replacing high health-risk chernicals with water soluble products without known detrimental effects, SPT has proved to be both an economical and potentially efficient alternative to the organic heavy liquids. SPT is patented, and only available from Sometu, Falkenried 4, D 1000 Berlin 33, Federal Republic of Germany.


1989 ◽  
Vol 63 (2) ◽  
pp. 253-255 ◽  
Author(s):  
Zdzislaw Belka ◽  
Stanislaw Skompski ◽  
Boguslaw Waksmundzki

Conodonts display higher specific gravity (2.84-3.10) than common minerals in sedimentary rocks. For several decades this property has been exploited to separate these microfossils from sediment residues using density separation techniques. Two heavy liquids commonly used, bromoform and tetra-bromoethane, are toxic (Sax, 1979; HaufTand Airey, 1980) and constitute a danger to human health. Tetrabromoethane is a known carcinogen (Brem et al., 1974). Both of these liquids should be abandoned in favor of nontoxic sodium polytungstate (Callahan, 1987; Merrill, 1987b; Krukowski, 1988). There are, however, some technical problems with its use because of relatively high viscosity and a tendency to recrystallize during separation. Another big disadvantage is also its price at $100 per kilogram. These problems may be considerably overcome by using polytungstate in the way described by Savage (1988).


1891 ◽  
Vol 8 (6) ◽  
pp. 273-275
Author(s):  
W. B. D. Edwards

The high price of all heavy liquids, and the consequent care that has to be taken in using them, the latter of course entailing great expenditure of time, were the reasons which caused me to make experiments, with regard to the manufacture of Klein's solution (borotungstate of cadmium) on a small scale. The price quoted in a well-known chemical manufacturer's price-list is 3s. 6d. per oz. My experiments have shown me that it can be made for about 7d. per oz., plus the value of the time of the maker. The process is very simple, and not much time is necessary in making it. A rough outline of the method of preparation is given by Dr. Klein in the Comptes Rendus, vol. xciii. August, 1881.


Author(s):  
Cyprian Obinna Azinta ◽  
Gordian Onyebuchi Mbah ◽  
Monday Omotioma

This research compared the viscosity and other allied rheological properties of formulated water based drilling mud using local clay (that is modified with cheap and available additives) and foreign clay. These additives (such as xanthum gum, high viscosity polyanionic cellulose (PAC-R), modified natural polyanionic cellulose (PAC-L), potassium hydroxide (KOH), sodium carbonate (Na2CO3), and barite) are added to enhance/control the rheological properties (such as density, viscosity, yield point and gel strength) of the drilling mud. In this work, the viscosity and other allied rheological properties of water based mud were improved by the use of locally sourced clay from Awgu in Enugu State. The local clay was beneficiated/treated with hydrochloric acid (HCl) and characterized using x-ray fluorescence (XRF) spectrometer. The results of the characterization revealed that the local clay is more of silica which is typical of a kaolinitic clay. Local clay was examined as a possible replacement for foreign bentonite by comparing the rheological properties of water based mud (WBM) with bentonite and WBM with clay. Plastic viscosities (PV) of WBM with bentonite and WBM with clay were found to be 11.7 and 12.3 cP respectively. Other allied properties such as yield point, gel   strength, pH   and   mud   weight   of   WBM   with bentonite   and   WBM   with   clay    adequately   compared   closely.   Laboratory analyses   on the effects of three process variables (such as temperature, aging time and dosage of clay/bentonite) on the viscosity of the formulated muds were investigated. The laboratory results show that the readily available additives added to the local clay improved its viscosity and other allied rheological properties for effective drilling of oil and gas well when compared with foreign bentonite.


2020 ◽  
pp. 85-107
Author(s):  
Yulian R. Farkhodov ◽  
N. V. Yaroslavtseva ◽  
M. A. Yashin ◽  
S. F. Khokhlov ◽  
B. S. Iliyn ◽  
...  

One of the most justified and applied approaches to isolating pools of soil organic matter is fractionation in heavy liquids. The main problem with this approach is rather large losses in the separation of fractions at the stage of washing fractions from heavy liquids. The paper presents a densimetric fractionation protocol that can significantly reduce these losses. It is suggested to use 0.001 M HCl for washing. This approach, in comparison with distilled water, allows reducing losses of weight from 15 to 5% and of carbon from 7.5 to 2.5%. The paper provides a detailed protocol, used by the Laboratory of Soil Biochemistry of V.V. Dokuchaev Soil Science Institute, to isolate four densimetric fractions using sodium polytungstate solutions: free and occluded SOM with a density of <1.6 g/cm3, occluded SOM – of 1.6–2.0 g/cm3, and a mineral residue with a density >2.0 g/cm3. In the work we used samples of typical chernozems of different land use types. It was shown that the processes of soil restoration and degradation significantly affect the content of light occluded soil organic matter.


2009 ◽  
Vol 106 (6) ◽  
pp. 242-247
Author(s):  
C. Damerval ◽  
H. Tavernier ◽  
L. Avedian ◽  
P. Disant ◽  
P. Delfosse ◽  
...  

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