Effect of Bismuth Oxide as Sintering Aid for Gadolinia-doped Ceria at 1050 C

2015 ◽  
Vol 68 (1) ◽  
pp. 413-420 ◽  
Author(s):  
V. De Marco ◽  
V. M. Sglavo
2018 ◽  
Vol 57 (3) ◽  
pp. 119-123 ◽  
Author(s):  
María-José Sánchez-Rivera ◽  
Ana Gozalbo ◽  
Valentín Pérez-Herranz ◽  
Sergio Mestre

Author(s):  
Kahkashanan Ansari ◽  
Saurabh Dalela ◽  
Sudhish Kumar ◽  
Neelu Chouhan

A series of carbon-doped solid solutions of ceria bismuth oxide (CBO) was prepared by solid solution method. Highly porous solid solutions crystallized in a fluorite phase and exhibited the enhanced...


Inorganics ◽  
2019 ◽  
Vol 7 (10) ◽  
pp. 118 ◽  
Author(s):  
Grazia Accardo ◽  
Luca Spiridigliozzi ◽  
Gianfranco Dell’Agli ◽  
Sung Pil Yoon ◽  
Domenico Frattini

The reduction of the sintering temperature of doped ceria ceramics remains an open challenge for their real exploitation as electrolytes for intermediate temperature solid oxide fuel cell (IT-SOFCs) at the industrial level. In this work, we have used Bi (0.5 and 2 mol %) as the sintering aid for Gd (20 mol %)-doped ceria. Nano-sized powders of Bi/Gd co-doped ceria were easily synthesized via a simple and cheap sol-gel combustion synthesis. The obtained powders showed high sinterability and very good electrochemical properties. More importantly, even after prolonged annealing at 700 °C, both of the powders and of the sintered pellets, no trace of structural modifications, phase instabilities, or Bi segregation appeared. Therefore, the use of a small amount of Bi can be taken into account for preparing ceria-based ceramic electrolytes at low sintering temperatures.


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