Model for Nickel‐Iron Alloy Electrodeposition on a Rotating Disk Electrode

1997 ◽  
Vol 144 (3) ◽  
pp. 960-969 ◽  
Author(s):  
Till Krause ◽  
Lazar Arulnayagam ◽  
Mark Pritzker
Author(s):  
F.I. Danilov ◽  
◽  
I.V. Sknar ◽  
Yu.E. Sknar ◽  
L.M. Pavlenko ◽  
...  

The kinetics of сodeposition of nickel and iron in an electrolyte based on a deep eutectic solvent (ethaline) was studied by voltammetry method. It was established that the partial voltammograms of iron ions reduction during alloy electrodeposition correspond to the region of electrode potentials, which is more than 100 mV positive in comparison with the electrodeposition potentials of pure iron. It was shown that the acceleration of iron ion electroreduction is associated with the gain in energy due to the alloy formation and a decrease in the overvoltage of iron electrodeposition during alloying. The change in the kinetics of iron electrodeposition can be explained by both a change in the mechanism of its electrodeposition in conjunction with nickel and a change in the state of the electrode surface in the potential region of the alloy formation. Comparison between the ratio of the content of the alloy components in the metal and the corresponding ions in the electrolyte showed that nickel and iron electrodeposit into the alloy in quantities that are proportional to their content in the electrolyte. Thus, electrodeposition of nickel-iron alloy from ethaline with a water content of up to 3% occurs by the so-called normal mechanism.


Alloy Digest ◽  
1975 ◽  
Vol 24 (6) ◽  

Abstract ALLOY 48 is a vacuum-melted, 48% nickel-iron alloy designed for high permeability, and low core losses. It is ideal in applications requiring efficient magnetic core materials, such as audio and instrument transformers, instrument relays, and many other communication equipment devices. It is excellent for rotor and stator laminations, and is also a very effective magnetic shielding material. This datasheet provides information on composition, physical properties, hardness, elasticity, and tensile properties. It also includes information on corrosion resistance as well as forming, heat treating, machining, and joining. Filing Code: Fe-52. Producer or source: Magnetics Specialty Metals Division. See also Alloy Digest Fe-96, April 1992.


Alloy Digest ◽  
1969 ◽  
Vol 18 (10) ◽  

Abstract Niromet 46 is a 46% nickel-iron alloy having low and controlled coefficient of expansion. It is recommended for metal-to-glass seals and terminal bands in vitreous enameled resistors. This datasheet provides information on composition, physical properties, hardness, and tensile properties. It also includes information on corrosion resistance as well as forming, heat treating, machining, and joining. Filing Code: Fe-39. Producer or source: Wilbur B. Driver Company.


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