Molten Carbonate Fuel Cell Performance for CO2 Capture from Natural Gas Combined Cycle Flue Gas

2020 ◽  
Vol 167 (6) ◽  
pp. 064505 ◽  
Author(s):  
Jonathan Rosen ◽  
Timothy Geary ◽  
Abdelkader Hilmi ◽  
Rodrigo Blanco-Gutierrez ◽  
Chao-Yi Yuh ◽  
...  
Author(s):  
Robert Flores ◽  
Jack Brouwer

Abstract Traditional carbon capture technology has been shown to effectively capture emissions, but at a cost of reducing power plant output. Molten carbonate fuel cell technology (MCFC) has the potential to be able to concentrate plant carbon emissions into a gas stream that is suitable for storage while boosting total plant power output. When considering this type of technology, the original purpose and function of the power plant must be considered. In particular, gas turbines (GT) based natural gas combined cycle (NGCC), which are capable of dynamic load following operation, are likely to need to maintain operational flexibility. This work explores the retrofit of an existing GT with MCFC technology for carbon capture when the plant is operated at part load. Physical models for major plant components are built and used to select optimal operating set points such that operating cost is minimized. Special attention is given to ensuring feasible operation across all engine components. The results show MCFC operational parameters that minimize change in fuel cell operating conditions when the gas turbine is operated at part load.


Author(s):  
Mehdi Mehrpooya ◽  
Parimah Bahramian ◽  
Fathollah Pourfayaz ◽  
Hadi Katooli ◽  
Mostafa Delpisheh

Abstract The production of liquefied natural gas (LNG) is a high energy-consuming process. The study of ways to reduce energy consumption and consequently to reduce operational costs is imperative. Toward this purpose, this study proposes a hybrid system adopting a mixed refrigerant for the liquefaction of natural gas that is precooled with an ammonia/water absorption refrigeration (AR) cycle utilizing the exhaust heat of a molten carbonate fuel cell, 700°C and 2.74 bar, coupled with a gas turbine and a bottoming Brayton super-critical carbon dioxide cycle. The inauguration of the ammonia/water AR cycle to the LNG process increases the cooling load of the cycle by 10%, providing a 28.3-MW cooling load duty while having a 0.45 coefficient of performance. Employing the hybrid system reduces energy consumption, attaining 85% overall thermal efficiency, 53% electrical efficiency and 35% fuel cell efficiency. The hybrid system produces 6300 kg.mol.h−1 of LNG and 146.55 MW of electrical power. Thereafter, exergy and sensitivity analyses are implemented and, accordingly, the fuel cell had an 83% share of the exergy destruction and the whole system obtained a 95% exergy efficiency.


2015 ◽  
Vol 41 ◽  
pp. 276-284 ◽  
Author(s):  
Richard Hill ◽  
Stephen Scott ◽  
David Butler ◽  
Song P. Sit ◽  
Dan Burt ◽  
...  

2022 ◽  
Vol 14 (1) ◽  
pp. 533
Author(s):  
Alberto Fichera ◽  
Samiran Samanta ◽  
Rosaria Volpe

This study aims to propose the repowering of an existing Italian natural-gas fired combined cycle power plant through the integration of Molten Carbonate Fuel Cells (MCFC) downstream of the gas turbine for CO2 capture and to pursuit an exergetic analysis of the two schemes. The flue gases of the turbine are used to feed the cathode of the MCFC, where CO2 is captured and transported to the anode while generating electric power. The retrofitted plant produces 787.454 MW, in particular, 435.29 MW from the gas turbine, 248.9 MW from the steam cycle, and 135.283 MW from the MCFC. Around 42.4% of the exergy destruction has been obtained, the majority belonging to the combustion chamber and, in minor percentages, to the gas turbine and the MCFC. The overall net plant efficiency and net exergy efficiency are estimated to be around 55.34 and 53.34%, respectively. Finally, the specific CO2 emission is around 66.67 kg/MWh, with around 2 million tons of carbon dioxide sequestrated.


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