Review—Concept and Application of Thermal Phenomena at 4f Electrons of Trivalent Lanthanide Ions in Organic/Inorganic Hybrid Nanostructure

Bond-length distributions for ions bonded to oxygen: Results for the lanthanides and actinides and discussion of the f-block contraction

10.26434/chemrxiv.5410924.v3 ◽

2017 ◽

Author(s):

Olivier Charles Gagné

Keyword(s):

Bond Length ◽

Coordination Number ◽

Lanthanide Ions ◽

Lanthanide Contraction ◽

Trivalent Lanthanide ◽

Actinide Ions

Bond-length distributions have been examined for eighty-four configurations of the lanthanide ions and twenty-two configurations of the actinide ions bonded to oxygen. The lanthanide contraction for the trivalent lanthanide ions bonded to O<sup>2-</sup> is shown to vary as a function of coordination number and to diminish in scale with increasing coordination number.

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A fluorescence study on the complexation of Sm(iii), Eu(iii) and Tb(iii) with tetraalkyldiglycolamides (TRDGA) in aqueous solution, in solid state, and in solvent extraction

Dalton Transactions ◽

10.1039/c6dt02930b ◽

2016 ◽

Vol 45 (46) ◽

pp. 18484-18493 ◽

Cited By ~ 15

Author(s):

Fei Kou ◽

Suliang Yang ◽

Hongjuan Qian ◽

Lihua Zhang ◽

Christine M. Beavers ◽

...

Keyword(s):

Aqueous Solution ◽

Solid State ◽

Solvent Extraction ◽

Lanthanide Ions ◽

Tridentate Ligand ◽

Fluorescence Study ◽

Trivalent Lanthanide

Trivalent lanthanide ions form 1 : 1, 1 : 2, and 1 : 3 complexes with tridentate ligand TMDGA in 1 M H/NaNO3 and form 1 : 3 extracted complexes with DMDODGA during solvent extraction.

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Determination of stability constants of some substituted 4-pyrazolone dyes containingo-methoxy,o-carboxy, ando-nitro groups with trivalent lanthanide ions

Monatshefte für Chemie - Chemical Monthly ◽

10.1007/bf00811283 ◽

1987 ◽

Vol 118 (10) ◽

pp. 1101-1111 ◽

Cited By ~ 4

Author(s):

B. A. El-Shetary ◽

S. L. Stefan ◽

F. I. Zidan ◽

S. B. El-Maraghy

Keyword(s):

Stability Constants ◽

Lanthanide Ions ◽

Trivalent Lanthanide

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Structure-stability relationships of some meta- and para-hydrazopyrazolone derivatives with trivalent lanthanide ions

Microchemical Journal ◽

10.1016/0026-265x(87)90073-7 ◽

1987 ◽

Vol 35 (2) ◽

pp. 186-195 ◽

Cited By ~ 2

Author(s):

Shaker Labib Stefan

Keyword(s):

Lanthanide Ions ◽

Structure Stability ◽

Trivalent Lanthanide

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Synthesis and Luminescence Properties of Lanthanide (III)-Doped YF3 Nanoparticles

Journal of Nanoscience and Nanotechnology ◽

10.1166/jnn.2006.119 ◽

2006 ◽

Vol 6 (3) ◽

pp. 830-836 ◽

Cited By ~ 23

Author(s):

Yang Cui ◽

Xianping Fan ◽

Zhanglian Hong ◽

Minquan Wang

Keyword(s):

Upconversion Luminescence ◽

Resonance Energy Transfer ◽

Resonance Energy ◽

Lanthanide Ions ◽

Luminescence Properties ◽

Synthesis Process ◽

Second Phase ◽

Trivalent Lanthanide ◽

Xrd Patterns ◽

Luminescence Concentration Quenching

Synthesis process and luminescence properties of trivalent lanthanide ions (Ln3+) doped YF3 nanoparticles have been investigated. To synthesis Ln3+-doped YF3 nanoparticles, the mixture of (YCl3·nH2O + LnCl3·nH2O), and NH4F was hydrothermal treated at 180 °C in a Teflon-liner auto-clave or heated at higher temperatures (400 °C ∼ 600 °C) in a stove. The XRD patterns showed that the Ln3+-doped orthorhombic YF3 nanoparticles with no second phase have been prepared. The solid solution Y1−xEuxF3 (x = 0 ∼ 0.4) nanoparticles have been synthesized. The luminescence concentration quenching resulted from resonance energy transfer between neighboring Eu3+ ions occurred at higher Eu3+ concentrations (30 mol%). The upconversion luminescence of Er3+−Yb3+ codoped YF3 nanoparticles under 980 nm excitation has also been observed. With increase of heated temperature, the size of the Er3+−Yb3+ codoped YF3 nanoparticles increased gradually, and upconversion luminescence intensity increased significantly.

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New Complexes of Pr(III), Sm(III), Gd(lll), Gd(III), La(III) 1-(2-Benzthyazolyl)-3-methyl-4-azo-(4-nitrophenyl)-Pyrazolyn-5-one

Southern Brazilian Journal of Chemistry - Southern Brazilian Journal of Chemistry, Volume 28, No. 28, 2020 ◽

10.48141/sbjchem.v6.n6.1998.55_1998.pdf ◽

1998 ◽

Vol 6 (6) ◽

pp. 53-62

Author(s):

Anca Emandi ◽

Mariana Balasoiu ◽

Tudor Rosu

Keyword(s):

Molecular Weight ◽

Molar Conductance ◽

Lanthanide Ions ◽

X Ray ◽

Visible Spectra ◽

Elemental Analyses ◽

Trivalent Lanthanide

1-(2-Benzthyazolyl)-3-methyl-4-azo-(4-nitrophenyl)-Pyrazolyn-5-one (HL) possesses a chelating behavior. Its chelates with a number of trivalent lanthanide ions Pr(III), Sm(III),Gd(III), Ho(III), La(III) of the type Na3[Ln(L)2(OH)4] have been isolated and characterized on the basis of their elemental analyses, IR and visible spectra, magnetic and molar conductance studies, thermal and X-ray analysis and molecular weight determinations. All chelates have a monomeric octa-coordinated stn1cture and square antiprismatic (C2) symmetry.

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Radiationless transitions in trivalent lanthanide ions embedded in solids

Proceedings of the Indian Academy of Sciences - Section A ◽

10.1007/bf02840336 ◽

1984 ◽

Vol 93 (6) ◽

pp. 905-916

Author(s):

Deb Shankar Ray ◽

Mihir Chowdhury

Keyword(s):

Lanthanide Ions ◽

Radiationless Transitions ◽

Trivalent Lanthanide

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Five-fold twinned β-PbF2 nanocrystals in oxyfluoride glass ceramics

RSC Advances ◽

10.1039/c8ra06194g ◽

2018 ◽

Vol 8 (71) ◽

pp. 40787-40793 ◽

Cited By ~ 2

Author(s):

Yuao Guo ◽

Lijuan Zhao ◽

Yuting Fu ◽

Pan Dong ◽

Liying Guo ◽

...

Keyword(s):

Glass Ceramics ◽

Lanthanide Ions ◽

X Ray Diffraction ◽

Oxyfluoride Glass ◽

X Ray ◽

Trivalent Lanthanide ◽

Quenching Method

Oxyfluoride glass ceramics (GCs) doped with trivalent lanthanide ions (Ln3+) have been prepared using a conventional melting–quenching method and studied by X-ray diffraction (XRD).

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