Effect of Operation Conditions on Soot Formation in SOFC Stacks

Effects of initial ambient temperatures on combustion and soot emission characteristics of diesel fuel were investigated through experiment conducted in optical constant volume chamber and simulation using phenomenological soot model. There are four difference initial ambient temperatures adopted in our research: 1000 K, 900 K, 800 K and 700 K. In order to obtain a better prediction of soot behavior, phenomenological soot model was revised to take into account the soot oxidation feedback on soot number density and good agreement was observed in the comparison of soot measurement and prediction. Results indicated that ignition delay prolonged with the decrease of initial ambient temperature. The heat release rate demonstrated the transition from mixing controlled combustion at high ambient temperature to premixed combustion mode at low ambient temperature. At lower ambient temperature, soot formation and oxidation mechanism were both suppressed. But finally soot mass concentration reduced with decreasing initial ambient temperature. Although the drop in ambient temperature did not cool the mean in-cylinder temperature during the combustion, it did shrink the total area of local high equivalence ratio, in which soot usually generated fast. At 700 K initial ambient temperature, soot emissions were almost negligible, which indicates that sootless combustion might be achieved at super low initial temperature operation conditions.

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Engine Performance and Emissions Formation for RME and Conventional Diesel Oil: A Comparative Study

ASME 2009 Internal Combustion Engine Division Spring Technical Conference ◽

10.1115/ices2009-76121 ◽

2009 ◽

Cited By ~ 4

Author(s):

Junfeng Yang ◽

Monica Johansson ◽

Valeri Golovitchev

Keyword(s):

Diesel Engine ◽

Comparative Study ◽

Soot Formation ◽

Engine Performance ◽

Oxidation Mechanism ◽

Diesel Oil ◽

Engine Operation ◽

Operation Conditions ◽

Performance And Emissions ◽

Engine Performance And Emissions

A comparative study on engine performance and emissions (NOx, soot) formation has been carried out for the Volvo D12C diesel engine fueled by Rapeseed Methyl Ester, RME and conventional diesel oil. The combustion models, used in this paper, are the modifications of those described in [1–2]. After the compilation of liquid properties of RME specified as methyl oleate, C19H36O2, making up 60% of RME. The oxidation mechanism has been compiled based on methyl butanoate ester, mb, C5H10O2 oxidation model [3] supplemented by the sub-mechanisms for two proposed fuel constituent components, methyl decanoate, md, C11H22O2, n-heptane, C7H16, and soot and NOx formations reduced and “tuned” by using the sensitivity analysis. A special global reaction was introduced to “crack” the main fuel into constituent components, md, mb and propyne, C3H4, to reproduce accurately the proposed RME chemical formula. The sub-mechanisms were collected in the general one consisting of 99 species participating in 411 reactions. The combustion mechanism was validated using shock-tube ignition-delay data at diesel engine conditions and flame propagation speeds at atmospheric conditions. The engine simulations were carried out for Volvo D12C engine fueled both RME and conventional diesel oil. The numerical results illustrate that in the case of RME, nearly 100% combustion efficiency was predicted when the cumulative heat release, was compared with the RME LHV, 37.2 kJ/g.. To minimize NOx emissions, the effects of 20–30% EGR levels depending on the engine loads and different injection strategies were analyses. To confirm the optimal engine operation conditions, a special technique based on the time-transient parametric φ-T maps [4] has been used.

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