In-situ Monitoring the Formation of SEI Layer using Peak Force Tapping Mode AFM

2017 ◽  
Vol 8 ◽  
pp. 968-974 ◽  
Author(s):  
Horacio V Guzman

Analytical equations to estimate the peak force will facilitate the interpretation and the planning of amplitude-modulation force microscopy (tapping mode) experiments. A closed-form analytical equation to estimate the tip–sample peak forces while imaging soft materials in liquid environment and within an elastic deformation regime has been deduced. We have combined a multivariate regression method with input from the virial–dissipation equations and Tatara’s bidimensional deformation contact mechanics model. The equation enables to estimate the peak force based on the tapping mode observables, probe characteristics and the material properties of the sample. The accuracy of the equation has been verified by comparing it to numerical simulations for the archetypical operating conditions to image soft matter with high spatial resolution in tapping-mode AFM.


2021 ◽  
Author(s):  
Cai Shen

In this paper, the structural stability of graphene and Mexene was compared by peak force tapping mode of AFM. When in-situ scanning of two-dimensional material of reduced graphene oxide (rGO), the morphology of rGO did not change with time, which indicated that peak force tapping mode had no damage effect on the stable structure surface; while when in-situ scanning of two-dimensional material V2C, nano-etching occurred on the surface of V2C, and the morphology surface area decreased with scanning time. The data processing software was used to analyze the area change and calculate the nano etching rate. It was found that the average nano-etching rate increased with the increase of the peak force, and the etching rate in the atmospheric environment was higher than that in the glove box (Ar atmosphere, the H2O and O2 content was less than 1 ppm), which indicated that the moisture in the atmosphere had an impact on the stability of the material and would accelerate the nano-etching. This study shows that the peak force tapping mode of AFM can be used to qualitatively characterize the stability of two-dimensional materials


2013 ◽  
Vol 2 (1) ◽  
pp. 21045 ◽  
Author(s):  
Julie Hardij ◽  
Francesca Cecchet ◽  
Alexandre Berquand ◽  
Damien Gheldof ◽  
Christian Chatelain ◽  
...  

2009 ◽  
Vol 71-73 ◽  
pp. 341-344 ◽  
Author(s):  
N. Gorham ◽  
T. Becker ◽  
Denis W. Shiers ◽  
Helen R. Watling

Ex-situ and in-situ Tapping Mode AFM were used to investigate responses of attached bacteria to stressful conditions. For ex-situ measurements, the AFM was equipped with a customised re-positioning stage and sample mount to permit re-examination of the same surface area. For in-situ measurements, the inoculated pyrite coupon was immersed in solution in a flow through cell. Initial experiments using Sulfobacillus thermosulfidooxidans indicated that increased acidity promoted EPS production but increased salinity resulted in cell detachment.


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