Investigation of the Effect of the Flow Rate Control on Capacity Decay in Vanadium Redox Flow Battery

2014 ◽  
Energies ◽  
2019 ◽  
Vol 12 (15) ◽  
pp. 3005 ◽  
Author(s):  
Meng ◽  
Xiong ◽  
Lim

The safe, efficient and durable utilization of a vanadium redox flow battery (VRB) requires accurate monitoring of its state of charge (SOC) and capacity decay. This paper focuses on the unbiased model parameter identification and model-based monitoring of both the SOC and capacity decay of a VRB. Specifically, a first-order resistor-capacitance (RC) model was used to simulate the dynamics of the VRB. A recursive total least squares (RTLS) method was exploited to attenuate the impact of external disturbances and accurately track the change of model parameters in realtime. The RTLS-based identification method was further integrated with an H-infinity filter (HIF)-based state estimator to monitor the SOC and capacity decay of the VRB in real-time. Experiments were carried out to validate the proposed method. The results suggested that the proposed method can achieve unbiased model parameter identification when unexpected noises corrupt the current and voltage measurements. SOC and capacity decay can also be estimated accurately in real-time without requiring additional open-circuit cells.


2017 ◽  
Vol 13 (1) ◽  
Author(s):  
Murali Mohan Seepana ◽  
Sreedevi Samudrala ◽  
P. V. Suresh ◽  
Ramsagar Vooradi

AbstractVanadium redox flow battery (VRFB) is one of the promising technologies for large scale renewable energy storage due to its long life time and flexible design. Electrolyte flow rate, electrolyte concentration, electrode porosity, temperature and applied magnitude of current have significant effect on the efficiency of VRFB. In the present work, a simplified dynamic lumped parameter model is developed in MATLAB to provide accurate results at unit cell level which can be used to control and optimize the parameters. The proposed model is based on the mass balance and charge conservation of various vanadium species and hydrogen ion concentration in the electrolyte. Major losses such as ohmic losses and activation losses are included in the cell potential. Recirculation of the electrolyte through external reservoirs is also considered. Numerical simulation demonstrates the effect of change in initial vanadium concentration and operating temperature on unit cell performance. It is shown that variations in electrolyte flow rate, magnitude of applied current substantially alter the charge/discharge characteristics and efficiency.


2012 ◽  
Vol 203 ◽  
pp. 153-158 ◽  
Author(s):  
Xiangkun Ma ◽  
Huamin Zhang ◽  
Chenxi Sun ◽  
Yi Zou ◽  
Tao Zhang

Sign in / Sign up

Export Citation Format

Share Document