(Invited) Time Resolved EPR Study on Photoinduced Charge-Transfer Trap States in Thiophene-Thiazolothiazole Copolymers Films

2018 ◽  
Keyword(s):  
Charge Transfer ◽  
Trap States ◽  
Photoinduced Charge Transfer ◽  
Time Resolved ◽  
Photoinduced Charge

Synthesis and photophysical properties of extended π conjugated naphthalimides

2017 ◽  
Vol 16 (4) ◽  
pp. 539-546 ◽  
Author(s):  
C. Rémy ◽  
C. Allain ◽  
I. Leray
Keyword(s):  
Charge Transfer ◽  
Dft Calculations ◽  
Photophysical Properties ◽  
Photoinduced Charge Transfer ◽  
Time Resolved ◽  
Time Resolved Spectroscopy ◽  
Td Dft ◽  
Photoinduced Charge

A series of π conjugated naphthalimide derivatives were prepared. Compounds display efficient photoinduced charge transfer in solution which was rationalized by time-resolved spectroscopy and modelled by TD-DFT calculations.

scholarly journals Time-resolved infrared-absorption study of photoinduced charge transfer in a polythiophene-methanofullerene composite film

2000 ◽  
Vol 61 (15) ◽  
pp. 9917-9920 ◽  
Author(s):  
S. C. J. Meskers ◽  
P. A. van Hal ◽  
A. J. H. Spiering ◽  
J. C. Hummelen ◽  
A. F. G. van der Meer ◽  
...  
Keyword(s):  
Charge Transfer ◽  
Composite Film ◽  
Infrared Absorption ◽  
Absorption Study ◽  
Photoinduced Charge Transfer ◽  
Time Resolved ◽  
Photoinduced Charge

scholarly journals Probing Transient Photoinduced Charge Transfer in Prussian Blue Analogues with Time-Resolved XANES and Optical Spectroscopy

2017 ◽  
Vol 2018 (3-4) ◽  
pp. 272-277 ◽  
Author(s):  
Serhane Zerdane ◽  
Marco Cammarata ◽  
Lodovico Balducci ◽  
Roman Bertoni ◽  
Laure Catala ◽  
...  
Keyword(s):  
Charge Transfer ◽  
Prussian Blue ◽  
Optical Spectroscopy ◽  
Photoinduced Charge Transfer ◽  
Time Resolved ◽  
Prussian Blue Analogues ◽  
Photoinduced Charge

Dynamics of photoinduced charge-transfer in dimethylamino-substituted triphenylphosphines

1996 ◽  
Vol 93 ◽  
pp. 1697-1713 ◽  
Author(s):  
P Changenet ◽  
P Plaza ◽  
MM Martin ◽  
YH Meyer ◽  
W Rettig
Keyword(s):  
Charge Transfer ◽  
Photoinduced Charge Transfer ◽  
Photoinduced Charge

Photoinduced Charge Transfer Dynamics in Carotenoid-Porphyrin-C60 Triad via the Linearized Semiclassical Nonequilibrium Fermi's Golden Rule

2020 ◽  
Author(s):  
Zhengqing Tong ◽  
Margaret S. Cheung ◽  
Barry D. Dunietz ◽  
Eitan Geva ◽  
Xiang Sun
Keyword(s):  
Charge Transfer ◽  
Golden Rule ◽  
Time Dependent ◽  
Rate Coefficients ◽  
Initial State ◽  
Photoinduced Charge Transfer ◽  
Transfer Rates ◽  
Fermi's Golden Rule ◽  
Photoinduced Charge ◽  
Fermi’S Golden Rule

The nonequilibrium Fermi’s golden rule (NE-FGR) describes the time-dependent rate coefficient for electronic transitions, when the nuclear degrees of freedom start out in a <i>nonequilibrium</i> state. In this letter, the linearized semiclassical (LSC) approximation of the NE-FGR is used to calculate the photoinduced charge transfer rates in the carotenoid-porphyrin-C<sub>60</sub> molecular triad dissolved in explicit tetrahydrofuran. The initial nonequilibrium state corresponds to impulsive photoexcitation from the equilibrated ground-state to the ππ* state, and the porphyrin-to-C<sub>60</sub> and the carotenoid-to-C<sub>60</sub> charge transfer rates are calculated. Our results show that accounting for the nonequilibrium nature of the initial state significantly enhances the transition rate of the porphyrin-to-C<sub>60</sub> CT process. We also derive the instantaneous Marcus theory (IMT) from LSC NE-FGR, which casts the CT rate coefficients in terms of a Marcus-like expression, with explicitly time-dependent reorganization energy and reaction free energy. IMT is found to reproduce the CT rates in the system under consideration remarkably well.

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