Complex Dynamics at the Aqueous Zinc-Ion Battery Cathode Interface

John Milnor, best known for his work in differential topology, K-theory, and dynamical systems, is one of only three mathematicians to have won the Fields medal, the Abel prize, and the Wolf prize, and is the only one to have received all three of the Leroy P. Steele prizes. In honor of his eightieth birthday, this book gathers together surveys and papers inspired by Milnor's work, from distinguished experts examining not only holomorphic dynamics in one and several variables, but also differential geometry, entropy theory, and combinatorial group theory. The book contains the last paper written by William Thurston, as well as a short paper by John Milnor himself. Introductory sections put the papers in mathematical and historical perspective, color figures are included, and an index facilitates browsing.

Download Full-text

Matrix metalloproteinases: structure, functions and genetic polymorphism

Nauchno-prakticheskii zhurnal «Patogenez» ◽

10.25557/gm.2017.2.7297 ◽

2017 ◽

pp. 14-23

Author(s):

А.С. Шадрина ◽

И.В. Терешкина ◽

Я.З. Плиева ◽

Д.Н. Кушлинский ◽

Д.О. Уткин ◽

...

Keyword(s):

Genetic Polymorphism ◽

Matrix Metalloproteinases ◽

Active Center ◽

Human Body ◽

Enzymatic Catalysis ◽

Structure Functions ◽

Zinc Ion ◽

Etiological Factors ◽

Mmp Genes

Матриксные металлопротеиназы (ММП) - ферменты класса гидролаз, осуществляющие ферментативный катализ с помощью связанного в активном центре иона цинка. Функции ММП разнообразны, и нарушение баланса их активности может быть одним из этиологических факторов различных заболеваний. В данном обзоре рассмотрена классификация ММП человека, особенности их структуры и регуляции, а также роль в физиологических и патологических процессах в организме человека. Приведен перечень наиболее изученных на настоящий момент полиморфных вариантов генов MMП, описаны их функциональные эффекты и представлены результаты ассоциативных исследований. Matrix metalloproteinases (MMPs) are enzymes of the hydrolase class that carry out enzymatic catalysis with the help of a zinc ion bound in the active center. MMP functions are diverse, and a disturbance in the balance of their activity may be one of the etiological factors of various diseases. In this review, the classification of human MMP, the features of their structure and regulation, as well as the role in physiological and pathological processes in the human body are considered. A list of the most studied polymorphic versions of MMP genes has been given, their functional effects have been described, and the results of associative studies have been presented.

Download Full-text

1285 - Minimal concentrations of zinc ion promoted conjugative transfer of kanamycin resistance gene mediated by a plasmid isolated from chicken manure

10.26226/morressier.5b5199c2b1b87b000ecee381 ◽

2018 ◽

Author(s):

Chengjun Pu

Keyword(s):

Resistance Gene ◽

Zinc Ion ◽

Kanamycin Resistance ◽

Chicken Manure ◽

Conjugative Transfer ◽

Kanamycin Resistance Gene

Download Full-text

Restriction of Access to Dark State: A New Mechanistic Model for Heteroatom-Containing AIE Systems

10.26434/chemrxiv.8275325.v1 ◽

2019 ◽

Author(s):

Yujie Tu ◽

Junkai Liu ◽

Haoke Zhang ◽

Qian Peng ◽

Jacky W. Y. Lam ◽

...

Keyword(s):

Excited States ◽

Radiative Decay ◽

Molecular Design ◽

Mechanistic Model ◽

Zinc Ion ◽

Easy Access ◽

Triplet States ◽

Dark State ◽

Ion Probe ◽

Π State

Aggregation-induced emission (AIE) is an unusual photophysical phenomenon and provides an effective and advantageous strategy for the design of highly emissive materials in versatile applications such as sensing, imaging, and theragnosis. "Restriction of intramolecular motion" is the well-recognized working mechanism of AIE and have guided the molecular design of most AIE materials. However, it sometimes fails to be workable to some heteroatom-containing systems. Herein, in this work, we take more than one excited state into account and specify a mechanism –"restriction of access to dark state (RADS)" – to explain the AIE effect of heteroatom-containing molecules. An anthracene-based zinc ion probe named APA is chosen as the model compound, whose weak fluorescence in solution is ascribed to the easy access from the bright (π,π*) state to the closelying dark (n,π*) state caused by the strong vibronic coupling of the two excited states. By either metal complexation or aggregation, the dark state is less accessible due to the restriction of the molecular motion leading to the dark state and elevation of the dark state energy, thus the emission of the bright state is restored. RADS is found to be powerful in elucidating the photophysics of AIE materials with excited states which favor non-radiative decay, including overlap-forbidden states such as (n,π*) and CT states, spin-forbidden triplet states, which commonly exist in heteroatom-containing molecules.

Download Full-text

An Alternative Approach To User Fee Policy In The Primary Health Care Setting Of Bangladesh.

10.31219/osf.io/n5j8k ◽

2020 ◽

Author(s):

Nazneen Akhter

Keyword(s):

Health Care ◽

Primary Health Care ◽

Complex Dynamics ◽

Quality Care ◽

Secondary Data ◽

User Fees ◽

Primary Health ◽

Alternative Approach ◽

Benefit Principle ◽

User Fee

The concept of ascribing user fee in health care settings always remained a policy struggle and countries experienced different learning in this regards while implementing user fee at different tiers of health settings. The most exquisite learning among the many country specific evidences related to user fee are the match and mismatch between the equity principle and benefit principle while considering the client perspective. There is an added dimension of quality care which also add more complex dynamics into this concept since the quality care consideration has a double edged perspective both for clients and providers, where which one will get superiority over whom is a great question in health care, especially in the Primary Health care (PHC) of the country. In this reality the appropriate implementation guideline, followed by an appropriate practice of the administrative and management both service oriented and financial are of great importance in this user fee implementation consideration which always remained a challenge in the health care specially in remote care of PHC. This paper attempted a secondary data searching and scoping the available documents of Bangladesh and across the world to find an alternative approach to user fees policy where equity and benefit principle and quality - these three have to be placed in a well-constructed triad in PHC implementation which has been recommended as an alternative policy imperative in approaching user fees for Bangladesh PHC settings.

Download Full-text