scholarly journals Removal of Nickel(II) from Aqueous Solutions by Adsorption with Modified ZSM- 5 Zeolites

2009 ◽  
Vol 6 (3) ◽  
pp. 729-736 ◽  
Author(s):  
P. Panneerselvam ◽  
V. Sathya Selva Bala ◽  
N. Thinakaran ◽  
P. Baskaralingam ◽  
M. Palanichamy ◽  
...  

The sorptive removal of nickel ion from aqueous solutions using modified ZSM-5 zeolites was investigated. Experiments were carried out as a function of solute concentration and different temperatures. Mesoporous material of ZSM-5 zeolite was modified with phosphoric acid by wet method. The modified zeolite was converted to Na+form using aqueous NaHCO3solution. The Na+form of modified zeolite, represented as PNa2--ZSM-5 was characterized by XRD, BET, SEM and AAS techniques. It was then tested for ion exchange with aqueous Ni(SO4) solution. The Ni2+content of the solution was analyzed by AAS. Phosphoric acid modified PNa2--ZSM-5 zeolite shows higher adsorption capacity than the parent Na-Y zeolite. Equilibrium modeling data were fit to linear Langmuir model then the Freundlich model. These parameter confirmed that sorption of Ni2+is feasible spontaneous and endothermic.

2013 ◽  
Vol 9 (2) ◽  
pp. 1943-1952
Author(s):  
Khouloud Nasri ◽  
Chaker Chtara ◽  
Hassen Chekir ◽  
Hafed EL Feki

Triple Superphosphate (TSP) is a chemical fertilizer, acknowledged by its important content of phosphorus, necessary element for plants. It’s obtained by adding phosphoric acid to phosphate ore, consisting of calcium phosphate containing many impurities. TSP was dissolved at different temperatures and in various amounts of water, filtered to remove insoluble compounds. Then the ionic conductivity was monitored for each solution as a function of the added amount of TSP. Aqueous solutions were evaporated to dryness and analyzed the P2O5. The starting materials and final products were analyzed by several methods (XRD, IR, NMR, SEM) confirming that after dissolution the product was purified.


1992 ◽  
Vol 57 (7) ◽  
pp. 1393-1404 ◽  
Author(s):  
Ladislav Svoboda ◽  
Jan Uhlíř ◽  
Zdeněk Uhlíř

The properties of Ostsorb DETA, a selective ion exchanger based on modified bead cellulose with chemically bonded diethylenetriamine functional groups, were studied, and its applicability to the preconcentration of trace amounts of lead from aqueous solutions was verified. The conditions of the preconcentration procedure in the column and batch modes were optimized for this purpose. The results obtained were applied to the determination of lead in phosphoric acid.


Data in Brief ◽  
2021 ◽  
Vol 35 ◽  
pp. 106869
Author(s):  
Behzad Rahimi ◽  
Nayereh Rezaie-Rahimi ◽  
Negar Jafari ◽  
Ali Abdolahnejad ◽  
Afshin Ebrahimi

2014 ◽  
Vol 70 (6) ◽  
pp. 964-971
Author(s):  
Xu Chen ◽  
Zhen-hu Xiong

Magnetic multi-wall carbon nanotubes (M-MWCNTs) were used as an adsorbent for removal of furaltadone from aqueous solutions, and the adsorption behaviors were investigated by varying pH, sorbent amount, sorption time and temperature. The results showed that the adsorption efficiency of furaltadone reached 97% when the dosage of M-MWCNT was 0.45 g · L−1, the pH was 7 and the adsorption time was 150 min. The kinetic data showed that the pseudo-second-order model can fit the adsorption kinetics. The sorption data could be well explained by the Langmuir model under different temperatures. The adsorption process was influenced by both intraparticle diffusion and external mass transfer. The experimental data analysis indicated that the electrostatic attraction and π–π stacking interactions between M-MWCNT and furaltadone might be the adsorption mechanism. Thermodynamic analysis reflected that adsorption of furaltadone on the M-MWCNT was spontaneous and exothermic. Our study showed that M-MWCNTs can be used as a potential adsorbent for removal of furaltadone from water and wastewater.


Cold neutron inelastic scattering experiments have been performed on dilute aqueous solutions of (CD 3 ) 3 COH and of solutions of (CH 3 ) 3 COH in D 2 O at 21 °C. From the broadening of the quasi-elastic peak and independently determined self-diffusion coefficients ( D ), diffusive lifetimes ( c ) of H 2 O molecules have been calculated as functions of solute concentration. The product Dc is insensitive to concentration, giving a mean diffusion step length of 0.14 nm. The inelastic portion of the spectrum, reflecting lattice-like hydrogen bonding modes indicates that the solute enhances the water ‘structure’ but that such structure bears no resemblance to ice.


2010 ◽  
Vol 38 (4) ◽  
pp. 361-369 ◽  
Author(s):  
K. Anoop Krishnan ◽  
K. G. Sreejalekshmi ◽  
Sumol Varghese ◽  
T. S. Anirudhan

2021 ◽  
Vol 224 ◽  
pp. 187-196
Author(s):  
Bahman Banaei ◽  
Amir Hessam Hassani ◽  
Farhang Tirgir ◽  
Abdolmajid Fadaei ◽  
Seyed Mehdi Borghaei

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