Kinetics and Mechanism of Oxidation of Isobutylamine and 1,4-Butanediamine by Potassium Ferrate
Keyword(s):
The kinetics of oxidation of isobutylamine and 1,4-butanediamine by home-made potassium ferrate(VI) at different conditions has been studied spectrophotometrically in the temperature range of 288.2 -303.2 K. The results show first order dependence on potassium ferrate(VI) and on each reductant. The observed rate constant (kobs) decreases with the increase of [OH-], the reaction was negative fraction order with respect to [OH-]. A plausible mechanism was proposed and the rate equations derived from the mechanism can explain all the experimental results. The rate constants of the rate-determining step and the thermodynamic activation parameters were calculated.
2005 ◽
Vol 70
(4)
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pp. 585-592
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1985 ◽
Vol 63
(12)
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pp. 3317-3321
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Keyword(s):
2008 ◽
Vol 2008
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pp. 1-4
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1992 ◽
Vol 57
(7)
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pp. 1451-1458
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