Charge Order Breaks Magnetic Symmetry in Molecular Quantum Spin Chains
2012 ◽
Vol 2012
◽
pp. 1-13
◽
Keyword(s):
Charge order affects most of the electronic properties but is believed not to alter the spin arrangement since the magnetic susceptibility remains unchanged. We present electron-spin-resonance experiments on quasi-one-dimensional(TMTTF)2Xsalts (X=PF6, AsF6, and SbF6), which reveal that the magnetic properties are modified belowTCOwhen electronic ferroelectricity sets in. The coupling of anions and organic molecules rotates the g-tensor out of the molecular plane creating magnetically nonequivalent sites on neighboring chains at domain walls. Due to anisotropic Zeeman interaction a novel magnetic interaction mechanism in the charge-ordered state is observed as a doubling of the rotational periodicity ofΔH.
2002 ◽
Vol 145
◽
pp. 243-252
◽
Keyword(s):
Keyword(s):
Keyword(s):
2016 ◽
Keyword(s):
Keyword(s):