On the Use of Lie Group Homomorphisms for Treating Similarity Transformations in Nonadiabatic Photochemistry
Keyword(s):
A formulation based on Lie group homomorphisms is presented for simplifying the treatment of unitary similarity transformations of Hamiltonian matrices in nonadiabatic photochemistry. A general derivation is provided whereby it is shown that a similarity transformation acting on a traceless, Hermitian matrix through a unitary matrix ofSU(n)is equivalent to the product of a single matrix ofOn2-1by a real vector. We recall how Pauli matrices are the adequate tool whenn=2and show how the same is achieved forn=3with Gell-Mann matrices.
1955 ◽
Vol 7
◽
pp. 191-201
◽
2005 ◽
Vol 02
(01)
◽
pp. 111-125
◽
Keyword(s):
2012 ◽
Vol 182
(6)
◽
pp. 745-747
◽
2021 ◽
Vol 10
(2)
◽
pp. 658-667
2006 ◽
Vol 21
(11)
◽
pp. 907-910
◽
Keyword(s):
1999 ◽
Vol 14
(12)
◽
pp. 765-777
◽