High thermally conductive epoxy composite inks cured by infrared laser irradiation for two-dimensional/three-dimensional printing technology

2020 ◽  
Vol 54 (29) ◽  
pp. 4635-4643
Author(s):  
Gi-Tae Park ◽  
Sung Jun Lee ◽  
Byeong Guk Kim ◽  
Sang Hun Lee ◽  
Jae Wook Kang ◽  
...  

We propose a new fabrication method of high thermally conductive epoxy composites for 3 D printing technology, which is based on a thermosetting epoxy system containing graphene nanoplate (GNP) as an IR-absorbing material. Firstly, we developed highly heat-dissipating inks based on bisphenol A diglycidyl ether (DGEBA) type epoxy resins containing graphene nanoplate (GNP) which was used as a heat dissipating filler and, simultaneously, an IR-absorbing material for heat induced rapid curing of printed layer. h-BN was also added as a heat dissipating filler in order to increase the thermal conductivity and to decrease the electrical conductivity of the composite. Secondly, by using a micro dispenser equipped with an IR laser, 2D/3D line patterns of thermally conductive epoxy composites were printed and cured in-situ. Thermal and electrical conductivities of the resulting composites were discussed with respect to the resin compositions and the irradiation conditions. The highest thermal conductivity of 2.77 W/m·K was achieved when the contents of GNP and h-BN were 15.0 and 20.0 phr, respectively.

2021 ◽  
Vol 49 (6) ◽  
pp. 030006052110285
Author(s):  
Kai Xiao ◽  
Bo Xu ◽  
Lin Ding ◽  
Weiguang Yu ◽  
Lei Bao ◽  
...  

Objective To assess the outcomes of traditional three-dimensional (3D) printing technology (TPT) versus mirror 3D printing technology (MTT) in treating isolated acetabular fractures (IAFs). Methods Consecutive patients with an IAF treated by either TPT or MTT at our tertiary medical centre from 2012 to 2018 were retrospectively reviewed. Follow-up was performed 1, 3, 6, and 12 months postoperatively and annually thereafter. The primary outcome was the Harris hip score (HHS), and the secondary outcomes were major intraoperative variables and key orthopaedic complications. Results One hundred fourteen eligible patients (114 hips) with an IAF (TPT, n = 56; MTT, n = 58) were evaluated. The median follow-up was 25 months (range, 21–28 months). At the last follow-up, the mean HHS was 82.46 ±14.70 for TPT and 86.30 ± 13.26 for MTT with a statistically significant difference. Significant differences were also detected in the major intraoperative variables (operation time, intraoperative blood loss, number of fluoroscopic screenings, and anatomical reduction number) and the major orthopaedic complications (loosening, implant failure, and heterotopic ossification). Conclusion Compared with TPT, MTT tends to produce accurate IAF reduction and may result in better intraoperative variables and a lower rate of major orthopaedic complications.


Polymers ◽  
2021 ◽  
Vol 13 (8) ◽  
pp. 1302
Author(s):  
Younggi Hong ◽  
Munju Goh

Epoxy resin (EP) is one of the most famous thermoset materials. In general, because EP has a three-dimensional random network, it possesses thermal properties similar to those of a typical heat insulator. Recently, there has been substantial interest in controlling the network structure of EP to create new functionalities. Indeed, the modified EP, represented as liquid crystalline epoxy (LCE), is considered promising for producing novel functionalities, which cannot be obtained from conventional EPs, by replacing the random network structure with an oriented one. In this paper, we review the current progress in the field of LCEs and their application to highly thermally conductive composite materials.


2018 ◽  
Vol 222 ◽  
pp. 01013 ◽  
Author(s):  
Katarzyna Pacewicz ◽  
Anna Sobotka ◽  
Łukasz Gołek

Three dimensional printing is a promising new technology to erect construction objects. Around the world in every moment a new prototypes constructions are made by using this method. Three dimensional printing is taken into account as technology which can be used to print constructions in automated way on the Moon or Mars. The raw materials, which can be used with three dimensional printing have to fulfil basic requirements for those which are used in construction. That means that components of printing mortars are made from ingredients easily accessible in area nearby construction site and can be reusable. The cost of printing building objects due to that requirements is comparable to costs of traditional building, which are currently available. However additive techniques of printing needs a dedicated mortars for printer supplying. Characteristic for such mortars is: setting time, compressive strength, followability in the printing system, shape stability of every printed layer, controlling the hydration rate to ensure bonding with the subsequent layer, reusable capabilities, easily accessible raw materials, cost of such mixtures shouldn’t be too high in order to keep 3D printing competitive for traditional ways of building, mortar components should be recyclable and printing process should not influence negatively on an environment and people. All properties of printing mortars are determined by the device for additive application method. In this paper review of available materials used for three dimensional printing technology at construction site is presented. Presented materials were analysed in terms of requirements for building materials technology. Due to the lack of detailed information’s in available literature, regarding to the properties of raw materials, the results of this analysis may be used in the designing of new concrete mixtures for the use in three-dimensional printing technology for construction.


2019 ◽  
Vol 327 ◽  
pp. 108399
Author(s):  
Chun-Cheng Huang ◽  
Yi-Ying Chen ◽  
Yi-Ting Fang ◽  
Yu-Chi Chen ◽  
Chih-Ming Hung

2018 ◽  
Vol 9 ◽  
pp. 204173141877090 ◽  
Author(s):  
Alaa Aldaadaa ◽  
Nazanin Owji ◽  
Jonathan Knowles

Three-dimensional printing technology is getting more attention recently, especially in the craniofacial region. This is a review of literature enlightening the materials that have been used to date and the application of such technology within the scope of maxillofacial surgery.


2020 ◽  
Vol 57 (21) ◽  
pp. 213301
Author(s):  
王丹琦 Wang Danqi ◽  
袁群 Yuan Qun ◽  
殷长俊 Yin Changjun ◽  
高志山 Gao Zhishan ◽  
李新华 Li Xinhua

2019 ◽  
Vol 9 (1) ◽  
Author(s):  
Kai-Han Su ◽  
Cherng-Yuh Su ◽  
Cheng-Ta Cho ◽  
Chung-Hsuan Lin ◽  
Guan-Fu Jhou ◽  
...  

Abstract The issue of electronic heat dissipation has received much attention in recent times and has become one of the key factors in electronic components such as circuit boards. Therefore, designing of materials with good thermal conductivity is vital. In this work, a thermally conductive SBP/PU composite was prepared wherein the spherical h-BN@PMMA (SBP) composite powders were dispersed in the polyurethane (PU) matrix. The thermal conductivity of SBP was found to be significantly higher than that of the pure h-BN/PU composite at the same h-BN filler loading. The SBP/PU composite can reach a high thermal conductivity of 7.3 Wm−1 K−1 which is twice as high as that of pure h-BN/PU composite without surface treatment in the same condition. This enhancement in the property can be attributed to the uniform dispersion of SBP in the PU polymer matrix that leads to a three-dimensional continuous heat conduction thereby improving the heat diffusion of the entire composite. Hence, we provide a valuable method for preparing a 3-dimensional heat flow path in polyurethane composite, leading to a high thermal conductivity with a small amount of filler.


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