New class of magenta dyestuffs based on azomethine pyrazolone disperse dyes: Synthesis, characterization, and dyeing performance on polyester fabrics with ultraviolet protection and pH-dependent properties

2021 ◽  
pp. 004051752110246
Author(s):  
Seham A Ibrahim ◽  
Hala F Rizk
Keyword(s):  
Disperse Dyes ◽  
Light Fastness ◽  
Protection Factor ◽  
Polyester Fabrics ◽  
Color Representation ◽  
Ultraviolet Protection Factor ◽  
Dyeing Performance ◽  
Colorimetric Data ◽  
Ultraviolet Protection ◽  
Dyed Fabrics

Eight azomethine pyrazolone magenta dyes with iminodiethanol groups have been synthesized from 1,3-disubstituted- 1H-pyrazol-5( 4H)-ones in good yield. The newly synthesized dyes were characterized using spectroscopic data and elemental analyses techniques. All dyes have been successfully applied to polyester fabrics as disperse dyes where their dyeing performances have been discussed and evaluated in detail. The shades of these dyes ranged from red violet, purple and dark purple colors with good depth, brightness and good leveling properties. Multifunctional properties such as color representation, colorimetric data (L*, a*, b*, C*, h*, K/S), fastness properties of the dyed samples with respect to washing, perspiration, rubbing and light fastness have been discussed and evaluated in detail. The degree of exhaustion and fixation was also achieved after establishing the optimal dyeing conditions at 130°C, high pressure, 2% shade, and pH ≈5. As well, the influence of the dye bath pH on the K/S percentage and color intensity was estimated and discussed. Furthermore, the dyed fabrics were tested for ultraviolet protection factor and the results showed that these dyes gave excellent ultraviolet protection.

Synthesis of 4-arylazo-2-(N-pyrazolylcarboxamido)thiophene disperse dyes for dyeing of polyester and their antibacterial evaluation

2020 ◽  
Vol 90 (23-24) ◽  
pp. 2795-2805
Author(s):  
Amal Al-Azmi ◽  
Elizabeth John
Keyword(s):  
Antibacterial Activities ◽  
Antimicrobial Activities ◽  
Disperse Dyes ◽  
Bacterial Strains ◽  
Light Fastness ◽  
Polyester Fabrics ◽  
Nuclear Magnetic Resonance Spectra ◽  
Current Article ◽  
Dyed Fabrics ◽  
Dyed Fabric

The current article aims to synthesize some new arylazo-thiophenes for dyeing polyester fabrics and screen their antimicrobial activities. The new 4-arylazo-2-( N-pyrazolylcarboxamido)-thiophene dyes 4a–e were prepared by the reaction of 2-acetyl-2-arylazo-thioacetanilide derivative 1 with 2-chloro- N-(3-methyl-1 H-pyrazol-5-yl)acetamide derivative 2. The structures of these prepared analogues were established via Fourier-transform infrared and 1H/13C nuclear magnetic resonance spectra. The synthesized dyestuffs were applied to polyester fabrics after establishing the optimal dyeing conditions at 130 ºC, high pressure, 3% shade, and liquor ratio 20:1 at pH 5. Furthermore, the dyed fabrics obtained under these optimal conditions resulted in proper colorfastness toward washing, rubbing, sublimation and perspiration, and were adequate for light fastness. They showed respectable antibacterial effectiveness against two bacterial strains, Staphylococcus aureus (Gram-positive) and Salmonella typhimurium (Gram-negative) bacteria. The dyed fabric with dye 4d displayed the best antibacterial activities with percentage reduction of 88% and 76% against S. aureus and S. typhimurium bacteria, respectively.

Synthesis, Characterization, and Dyeing Performance of UV Protective Mono Azo Acid Dyes Based on 4-Hydroxybenzophenone

2020 ◽  
Vol 7 (2) ◽  
pp. 19-26
Author(s):  
Smita Bait ◽  
Suvidha Shinde ◽  
Ravindra Adivarekar ◽  
Sekar Nagaiyan Nethi
Keyword(s):  
Diazonium Salt ◽  
Acid Dyes ◽  
Light Fastness ◽  
Protection Factor ◽  
Ultraviolet Protection Factor ◽  
Dyeing Performance ◽  
Uv Absorbers ◽  
Functional Dyes ◽  
Silk Fabrics ◽  
Dyed Fabric

A key element in reducing human UV exposure is making proper UV protective goods with good ultraviolet protection factor (UPF) protection. The current research is focused on the synthesis of UV-protective functional dyes containing benzophenone-based UV absorbers and its application on wool and silk fabrics. Novel mono azo acid dyes were synthesized by the coupling of diazonium salt solutions of different aromatic amines with 4-hydroxybenzophenone, and these were applied on wool and silk. The fabrics dyed with the synthesized dyes showed less than 5% UVA and UVB transmission, indicating good protection against UV radiation. Dyed fabric also gave good to excellent washing, rubbing, and light fastness, and UV protection properties, even after ten washing cycles.

Synthesis and Application of New Benzotriazole Derivatives as UV Absorbers for Polyester Fabrics

2011 ◽  
Vol 233-235 ◽  
pp. 219-224 ◽  
Author(s):  
Yan Yan Yang ◽  
Hong Qi Li ◽  
Xue Dan He ◽  
Bing Nan Mu ◽  
Yi Jun Chen ◽  
...  
Keyword(s):  
Uv Light ◽  
Protection Factor ◽  
Polyester Fabrics ◽  
Ultraviolet Protection Factor ◽  
Uv Absorbers ◽  
Ultraviolet Protection ◽  
Dyeing Method ◽  
Uv Transmittance ◽  
The Relationship ◽  
Benzotriazole Derivatives

2-(2′-Hydroxyphenyl)-5-amino-2H-benzotriazole was synthesized and subjected to acylamidation to yield three new ultraviolet (UV) absorbers. The largest absorption wavelength and the relationship between the concentration and the maximum absorbance of the UV absorbers were measured in dimethylsulfoxide. Then the four benzotriazole type UV absorbers were dispersed and applied onto polyester fabrics with the high temperature and pressure dyeing method. The stabilizing effect against UV light of the finished fabrics was studied by ultraviolet protection factor (UPF) and UV transmittance measurement.

scholarly journals Synthesis and Structural-reactivity Studies of Bifunctional MCT/SES (Monochlorotriazine/ Sulphatoethylsulphone) Azo Reactive Disperse Dyes Applied to Wool and Polyester Fabric

2019 ◽  
pp. 1-10
Author(s):  
Ishegbe Joyce Eko ◽  
Bello Kasali Ademola ◽  
Nkeonye Peter Obinna ◽  
A. A. Kogo
Keyword(s):  
Polyester Fabric ◽  
Cyanuric Chloride ◽  
Disperse Dyes ◽  
Fastness Properties ◽  
Light Fastness ◽  
Dyeing Performance ◽  
Wool Fabrics ◽  
Dyed Fabrics ◽  
Monoazo Dyes

Reactive disperse dyes containing monochlorotriazine/sulphatoethylsulphone reactive moieties were synthesized by condensing aniline with cyanuric chloride and further reacting it with a series of monoazo dyes obtained by diazotising 1-aminobenzene-4-β-sulphatoethylsulphone and coupling with various substituted 2-amino-4-phenylthiazole derivatives. The dyeing performance of the dyes was evaluated on polyester and wool fabrics. The dyes obtained gave various shades ranging from reddish to bright red colours. They had good depth and good levelling properties. They dyed fabrics showed moderate to good light fastness properties and very good to excellent fastness to washing and perspiration. The dye bath exhaustion on the polyester and wool fabrics were found to be very good and their fixation values were moderate.

scholarly journals Synthesis and dyeing performance of some amphiphilic naphthalimide azo disperse dyes on polyester fabrics

2020 ◽  
Vol 85 (10) ◽  
pp. 1253-1264
Author(s):  
Umar Ameuru ◽  
Mohammed Yakubu ◽  
Kasali Bello ◽  
Peter Nkeonye ◽  
Azim Halimehjani
Keyword(s):  
Absorption Spectra ◽  
Electronic Absorption Spectra ◽  
Polyester Fabric ◽  
Disperse Dyes ◽  
Light Fastness ◽  
Visible Absorption ◽  
Polyester Fabrics ◽  
Dyeing Performance ◽  
Azo Disperse Dyes ◽  
Monoazo Disperse Dyes

A series of monoazo disperse dyes were synthesized by coupling diazotized 4-amino-N-dodecyl-1,8-naphthalimide with N,N-dialkyl anilines and naphthol derivatives. The synthesized intermediates and the dyes were characterized using FTIR, 1H-NMR, 13C-NMR, mass spectroscopy and elemental analysis (CHN). Visible absorption spectra of the dyes were examined in solvents of different polarities. The electronic absorption spectra cover a wavelength (?max) range of 515-535 nm in DMF at uniformly absorption intensity between 1.59-3.00?104 L mol-1 cm-1. The dyes gave deep and bright intense hues of light violet, maroon, pink and neon red on polyester fabrics. The dyes generally showed good washing and perspiration rating but poor to moderate light fastness properties on woven polyester fabric and could be recommended for commercial outlets.

Anti-ultraviolet properties of β-cyclodextrin-grafted cotton fabrics dyed by broadleaf holly leaf extract

2020 ◽  
Vol 90 (21-22) ◽  
pp. 2441-2453 ◽  
Author(s):  
Jinshu Liu ◽  
Xiaoyan Ma ◽  
Wenzhao Shi ◽  
Jianwei Xing ◽  
Chaoqun Ma ◽  
...  
Keyword(s):  
Tensile Strength ◽  
Leaf Extract ◽  
Cotton Fabrics ◽  
Sodium Hypophosphite ◽  
Crosslinking Reaction ◽  
Ultraviolet Spectrophotometry ◽  
Protection Factor ◽  
Ultraviolet Protection Factor ◽  
Ultraviolet Protection ◽  
Macerated Extract

The aim of the study was to investigate the anti-ultraviolet properties of β-cyclodextrin-grafted cotton fabrics dyed with broadleaf holly leaf extract. Flavonoids were extracted from broadleaf holly leaf by maceration and a stoichiometry of 1:1 inclusion complex with β-cyclodextrin was formed. Characterized by the fluorescence spectrum and ultraviolet spectrophotometry, the fluorescence intensities and ultraviolet absorption of the macerated extract were enhanced by increasing the amount of cyclodextrin. Cotton fabrics were grafted with β-cyclodextrin through a crosslinking reaction based on citric acid in the presence of sodium hypophosphite then dyed with the macerated extract of broadleaf holly leaf used as a natural ultraviolet absorbent. The anti-ultraviolet property of fabrics dyed by a macerated extract was characterized in terms of the ultraviolet protection factor. It was noted that the cotton fabrics grafted with β-cyclodextrin exhibit enhanced anti-ultraviolet and wrinkle recovery properties compared to the unmodified samples and show an excellent durability against 30 washing cycles, accompanied by a loss of tensile strength.

scholarly journals A new development for determining the ultraviolet protection factor

2015 ◽  
Vol 45 (6) ◽  
pp. 1571-1586 ◽  
Author(s):  
J Campos Payá ◽  
P Díaz-García ◽  
I Montava ◽  
P Miró-Martínez ◽  
M Bonet
Keyword(s):  
Protection Factor ◽  
Ultraviolet Protection Factor ◽  
New Development ◽  
Ultraviolet Protection

scholarly journals Ultraviolet Protection by Fabric Engineering

2013 ◽  
Vol 2013 ◽  
pp. 1-6 ◽  
Author(s):  
Mukesh Kumar Singh ◽  
Annika Singh
Keyword(s):  
Areal Density ◽  
Woven Fabrics ◽  
Uv Protection ◽  
Comfort Level ◽  
Protection Factor ◽  
Ultraviolet Protection Factor ◽  
Wear Comfort ◽  
Ultraviolet Protection ◽  
Multifilament Yarns ◽  
Fabric Structures

Background. The increasing emission of greenhouse gases has evoked the human being to save the ozone layer and minimize the risk of ultraviolet radiation (UVR). Various fabric structures have been explored to achieve desired ultraviolet protection factor (UPF) in various situations. Objective. In this study, the effect of various filament configurations like twisted, flat, intermingled, and textured in multifilament yarns on fabric in different combinations is assessed in order to engineer a fabric of better ultraviolet protection factor (UPF). Methods. In order to engineer a fabric having optimum UV protection with sufficient comfort level in multifilament woven fabrics, four different yarn configurations, intermingled, textured, twisted, and flat, were used to develop twelve different fabric samples. The most UV absorbing and most demanding fibre polyethylene terephthalate (PET) was considered in different filament configuration. Results. The combinations of intermingled warp with flat, intermingled, and textured weft provided excellent UVR protection comparatively at about 22.5 mg/cm2 fabric areal density. The presence of twisted yarn reduced the UV protection due to enhanced openness in fabric structure. Conclusion. The appropriate combination of warp and weft threads of different configuration should be selected judiciously in order to extract maximum UV protection and wear comfort attributes in multifilament woven PET fabrics.

Influence of Metal Mordants Concentration to Improve UV Protection and Fastness Properties of Silk Fabric Dyed with Purple Corn Cob

2014 ◽  
Vol 1030-1032 ◽  
pp. 430-433
Author(s):  
Rattanaphol Mongkholrattanasit ◽  
Charoon Klaichoi ◽  
Pannarai Rug-Ngam ◽  
Monthon Nakpathom ◽  
Manat Paengsai ◽  
...  
Keyword(s):  
Uv Protection ◽  
Silk Fabric ◽  
Fastness Properties ◽  
Protection Factor ◽  
Ultraviolet Protection Factor ◽  
Metallic Salts ◽  
Ultraviolet Protection ◽  
Purple Corn ◽  
Protection Property ◽  
Silk Fabrics

In the present study, natural dye from cob of purple corn and various metallic salts have been used to identify the proper dyeing condition for attaining high quality natural dyeing along with imparting UV protection property to the dyed silk fabric. Silk fabrics dyed with cob of purple corn extract showed a violetish-pink shade, while those dyed with alum light violetish-pink shade colour. Silk substrates dyed with CuSO4 and FeSO4 gave a yellowish grey and violetish-gray colour, respectively. The fastness properties ranged from fair to good. The ultraviolet protection factor (UPF) values of silk fabric dyed with and without metal mordants ranged between very good and excellent.

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