Optimization study on wet electrostatic powder coating process to manufacture UHMWPE/LDPE towpregs

In the present study, an attempt has been made to coat the non-conductive Ultra-high Molecular Weight Polyethylene (UHMWPE) fibers with Low-Density Polyethylene (LDPE) powder. In order to enable the deposition of electrostatically charged LDPE powder onto the fiber surface, UHMWPE fibers are dipped into a surface modification bath to impart momentary conductivity. Further, Box Behnken’s experimental design is used to optimize the processing parameters for Fiber Volume Fraction (Vf) for this wet electrostatic spray coating process. An experimental multi-parametric equation is acquired through response surface methodology to ascertain the association amid the process parameters such as processing temperature (A), conveying air pressure (B), and gun nozzle angle (C) on the output response of Vf. The process parametric values for A, B, and C are varied from 225°C to 245°C, 0.2 bar to 0.4 bar, and 0° to 120° respectively. The Vf obtained is in the range of 37.02%–56.28% depending on the combination of process parametric values. Powder pick-up increases with an increase in the gun nozzle angle. An increase in conveying air pressure and temperature of the hot air oven leads to an increase in powder deposition. The values predicted from the model are observed to be in close proximity (94.59%) to the experimental results. Gun nozzle angle is the principal parameter affecting the matrix deposition on the fiber surface in comparison to other process parameters.

Hybrid fibrous (PVDF-BaTiO3)/ PA-11 piezoelectric patch as an energy harvester for pacemakers

Lithium batteries have been widely used to power up implantable medical devices such as pacemakers that are often designed to treat, diagnose, and prevent different diseases. However, due to their limited capacity and lifetime, patients have to undergo a surgical procedure to replace the discharged battery. Recently, nanogenerators have been emerged and are broadly accepted since they can convert tiny biomechanical forces, such as heartbeats, into electrical energy. This study aims to manufacture a biocompatible and high-performance piezoelectric energy harvester (PEH) that is capable to be charged by the energy received from the heartbeat and store the generated voltage. In this research, a hybrid structure of poly (vinylidene fluoride) (PVDF) coupling with polyamide-11 (PA-11) was fabricated using dual electrospinning to enhance the piezoelectric properties of the intended PEH. The piezoelectric test results show an acceptable increase in nanofibers’ piezoelectric sensitivity from 62.87 mV/N to 75.75 mV/N by adding 25% (v/v) of PA-11 to PVDF, indicating the synergistic effect of PVDF and PA-11. The specimen PVDF (75% v/v)-PA-11 (25% v/v) also showed the highest mechanical strength and consequently is suggested as the optimum sample. To further enhance the efficacy and sensitivity of PEH to convert the small mechanical forces into an acceptable voltage, 15% (w/w) of barium titanate (BaTiO3) nanoparticles were added to the hybrid structure. The crystallinity and mechanical strength were noticeably increased by incorporating BaTiO3 nanoparticles into the fibrous structure, leading to a piezoelectric sensitivity of 107.52 mV/N. This result lays the groundwork for producing an effective piezoelectric patch that could be used as pacemaker batteries.

Oxidative removal of As(III) by polyacrylonitrile@Ag-Ag2O/schwertmannite nanofiber under visible light

Visible light response PAN@Ag-Ag2O/Sch (PAN@AS, schwertmannite and polyacrylonitrile abbreviated as Sch and PAN) nanofibers with different mass ratios were synthesized by electrospinning technology and pH-induced precipitation reaction. X-Ray diffraction, X-ray photoelectron spectroscopy and transmission electron microscopy analysis showed that the formation of Ag-Ag2O/Sch heterojunction and Ag-Ag2O nanoparticles were evenly distributed on the surface of Sch. The prepared nanofibers have high oxidative removal performance for As(III) under visible light. In the [email protected] system, the total As removal percent can reach 90.96% after 120 min irradiation at pH 4.0. The scavenger experiments confirmed that the main active substances of the [email protected] system were h+ and •OH. The high oxidation and removal performance of the [email protected] composite for As(III) was attributed to the effective separation of photogenerated electron-hole pairs and high adsorption capacity of Sch for As under acidic conditions. This research provides a new material for the oxidation and removal of pollutants in water [such as As(III)] and also provides a research basis for the preparation of recyclable photocatalysts.

Coaxial electrospinning preparation and antibacterial property of polylactic acid/tea polyphenol nanofiber membrane

The polylactic acid (PLA)/tea polyphenol (TP) nanofiber membranes were prepared by coaxial electrospinning. The physical properties, antibacterial agent release, degradation, and antibacterial properties were investigated. Results demonstrated that stepwise and controlled antibacterial agent release profiles were achieved based on the core-shell configuration and disparate degradation rate of PLA and TP. The mechanical performance decreased with the increase of the TP content in the shell layer. The cumulative antibacterial agent release rate of nanofiber membranes with different TP content was different, while the antibacterial agent release trend was the same. The antibacterial agent release rate of the sample was the fastest at the initial stage from 2 h to 8 h, and then gradually slowed down after 24 h. In addition, the antibacterial activity of the PLA/TP nanofiber membranes was confirmed by the inhibition zone method against both Gram-positive ( Staphylococcus aureus) and Gram-negative ( Escherichia coli). Results showed that the antibacterial performance of PLA/TP nanofiber was intensified with the increasing content of TP, especially had better antibacterial performance against S. aureus.

Optimization of electromagnetic shielding of three-dimensional orthogonal woven hybrid fabrics in ku band frequency region by response surface methodology

Electromagnetic shielding (EMS) has become the necessity of the present era due to enormous expansion in electronic devices accountable to emit electromagnetic radiation. The principal target of this paper is to originate three-dimensional (3D) orthogonal fabrics with conductive hybrid weft yarn and to determine their electromagnetic shielding. DREF-III core-spun yarn using copper filament in the core and polyphenylene sulfide (PPS) fiber on the sheath and fabric constructed of such yarn has a promising electromagnetic shielding characteristic. Box–Behnken experimental design has been employed to prepare various samples to investigate the electromagnetic shielding efficiency of 3D orthogonal woven structures. The orthogonal fabric samples were tested in an electromagnetic Ku frequency band using free space measurement system (FSMS) to estimate absorbance, reflectance, transmittance, and electromagnetic shielding. The increase in copper core filament diameter and hybrid yarn linear density enhances the EMS of orthogonal fabric. Statistical analysis has been done to bring out the effect and interaction of various yarn and fabric variables on EMS. Metal filament diameter, orientation, sheath fibers percentage, and fabric constructional parameters significantly affected electromagnetic shielding efficiency. The inferences of this study can be applied in other 3D structures like angle interlock, spacer fabrics for curtains, and coverings for civilians and military applications.

Multilayer nonwoven lining materials made of wool and cotton for clothing and footwear

Five types of multilayer nonwovens for clothing and footwear parts were obtained by the adhesive bonding method. The thickest middle layer of the material consists of evenly laid coarse camel or sheep fibers or of reconstituted cotton fibers from flaps, the upper and lower layers consist of knitwear, and polymer adhesive is located between the layers. The layers are bonded by thermal pressing at a temperature of 150 ± 5°C for 2.0 ± 0.2 min. The microstructure and morphology of fibers, polymer adhesive, and multilayer nonwoven fabric were investigated by FT-IR spectroscopy, SEM, and X-ray phase analysis. The chemical interaction between wool fibers and polymer adhesive, the geometric dimensions and shape of the fibers, the structure and morphology of the cross section of the layers of the material, and the change in the degree of crystallinity of the material have been established. The investigated coarse and thick fibers of camel and sheep wool are more suitable for the production of nonwoven textile material. In the process of thermal exposure, the molten polymer diffuses into the structure of the nonwoven layer and knitted fabric. The diffusion and excellent adhesion of the molten polymer to the fibers ensures the solidity and strength of the composite. The developed design provides high strength of the material as a whole and adhesive strength between layers, high heat-retaining properties, and the use of a mesh adhesive film provides sufficient air and vapor permeability.

Thermoelectrical properties of graphene knife-coated cellulosic fabrics for defect monitoring in Joule-heated textiles

Knife-coating can confer new properties on different textile substrates efficiently by integrating various compounds into the coating paste. Graphene nanoplatelets (GNP) is one of the most used elements for the functionalization of fabrics in recent years, providing electrical and thermal conductivity to fabrics, later used to develop products such as sensors or heated garments. This paper reports thermoelectrically conductive textiles fabrication through knife-coating of cellulosic fabrics with a GNP load from 0.4 to 2 wt% within an acrylic coating paste. The fabric doped with the highest GNP content reaches a temperature increase of 100°C in few seconds. Besides, it is found out that the thermographic images obtained during the electrical voltage application provide maps of irregularities in the dispersion of conductive particles of the coating and defects produced throughout their useful life. Therefore, the application of a low voltage on the coated fabrics allows fast and effective heating by Joule’s effect, whose thermographic images, in turn, can be used as structural maps to check the quality of the GNP doped coating. The temperature values and the heating rate obtained make these fabrics suitable for heating devices, anti-ice and de-ice systems, and protective equipment, which would be of great interest for industrial applications.

Electroless plating process for the manufacture of radiation protection suits for pregnant woman: Effect of bending on its electromagnetic shielding performance

Multi-ion fabrics (especially silver ion fabrics) have special advantages as electromagnetic radiation, but the use of noble metals enhances its cost. Electroless nickel plating (EP-Ni) has great potential application in fabricating low-cost metallized material. Here, EP-Ni on pure cotton surface to fabricate radiation protection suits for pregnant woman was established to replace traditional protection suits with silver film. The active groups on the cotton/polyester blend fiber surface could absorb tin and palladium ions, acting as catalytic centers, which can catalyze the reduction of Ni2+ in the plating solution. Ni particle with (111) crystal plane preferential oriented crystal structure deposited on cotton surface with a coarse microstructure. The Ni deposited amount is about 19%. The fabricated material exhibited a shielding effectiveness of 29.5 dB. Studies also shown that bending has no negative effect on crystallinity and electrical property. But more bending times could lead to crack, which would decline electromagnetic shielding performance by 24%.

Stab resistance of flexible composite reinforced with warp-knitted fabric like scale structure at quasi-static loading

The stab-resistant fabric like scale structure has a promising application prospect for areas of stab prevention owing to its great flexibility and excellent stab-resistance performance. In this paper, a kind of novel stab-resistant fabric has been designed by coating with epoxy resin (ER) and silicon carbide (SiC) particles, which was based on the warp-knitted fabric like scale structure (WKFS). The uniformity of dispersion has been investigated with different diameter and mass fraction of SiC, and polymerization degree of polyglycols (PEG); the flexibility and quasi-static properties of different kinds of WKFS treated with different coating solution has been studied, and the coating solution was prepared by mixing SiC particles and ER at different ratios. The results showed that the dispersion uniformity of the dispersion was the best when the diameter of SiC is 1 μm, the content is 50%, and the polymerization degree of PEG is 600. The longitudinal flexibility of the stab-resistant fabric is greater than that of transverse due to the gap between the longitudinal scales, and the addition of SiC particles can increase the transverse and longitudinal flexibility of stab-resistant fabric, and the flexible properties were the greatest when SiC:ER = 50:30. In addition, the WKFS treated with SiC of 16.7% has fatigue resistance; the damage mechanism of the fabric treated with pure ER is thankful to the brittleness of the resin; the added SiC particles hinder the further crack propagation of the resin, and the failure mode is mainly in stretch.

Development and mechanical properties of three-dimensional flat-knitted fabrics with reinforcement yarns

Three-dimensional (3D) flat-knitted fabrics have become a topic of interest in the field of composites in recent years because of the growing need for rapid preparation of complicated shape preforms. In order to improve the mechanical properties of 3D flat-knitted fabrics, two types of 3D flat-knitted fabrics with reinforcement yarn (FKFR) were developed using ultra-high molecular weight polyethylene (UHMWPE) yarn. Their basic structures were composed of plain structure and interlock structure with tuck stitch, respectively, and the reinforcement yarn was integrated into the fabric as the weft inlay. The tensile, bending, drape, and bursting properties of the two fabrics were characterized. Results showed that the basic structure of the fabric has impacted on the mechanical properties of the fabric significantly. The tensile and bending properties of the fabric with interlock structure were better than that of the fabric with plain structure. During the transverse stretching process, the surface structure of the fabric with interlock structure was more stable. Moreover, transverse yarn strength utilization of the fabric with interlock structure was 1.05, which reached the level of ordinary woven fabric. In addition, the bursting force of the fabric with excellent tensile properties was lower than that of the fabric with a plain structure because the latter has better extensibility.