Improved Resilience by Formation of Elastomers inside Cotton Fibers

1969 ◽  
Vol 39 (6) ◽  
pp. 560-567 ◽  
Author(s):  
D. Meimoun ◽  
A. Parisot

The introduction of elastomeric substances between the cellulose fibrils and/or histological elements of cotton fibers could lead to wrinkle-resistant cottons. Such substances, polyenes obtained by polymerization in situ after inclusion within the structure, are unable to penetrate the intermolecular structure, but are able to link together the elements of the fiber. This might result in a fiber with greater delayed elastic recovery and reduced permanent set, permitting wrinkle recovery of cotton fabrics to be increased. The study of optimum reaction parameters resulted in a reproducible process for including the polymer. The location of the polymer has been determined through the development of a new method for revealing the structure of cellulose. The desired mechanical properties of woven treated fabrics are improved, as indicated by various measurements. The first results concerning single fibers seem to corroborate the preceding.

2017 ◽  
Vol 21 (2) ◽  
pp. 146-158 ◽  
Author(s):  
Pragnya Kanade ◽  
Bharat H. Patel

Purpose The main purpose of taking up this work was to see the influence of metallic nanoparticles on various fabric properties. This paper emphasizes on mechanical, aesthetic and anti-bacterial properties of the polyester, cotton and polyester cotton-blended fabric samples. Design/methodology/approach Three fabrics, 100 per cent polyester, 100 per cent cotton and polyester cotton-blended (50:50), were procured from the market. They were subjected to mild washing treatment so that the fabrics could be impregnated with copper (Cu) nanoparticles following standard procedure. The characterization of Cu nano-loaded textiles has been done using various techniques such as scanning electron microscopy for surface morphology, X-ray fluorescence spectrometer for elemental analysis and Fourier transform infrared spectroscopy for chemical composition. However in this paper, the focus is on various fabric properties and influence of this treatment on them. Antimicrobial activity was measured as per AATCC 100 quantitative method. Findings The structural properties showed changes but not major ones. The impregnation of Cu nanoparticles is nothing but a chemical treatment, and it is not uncommon to find reduction in the mechanical properties of the specimen. Here also, the mechanical properties were studied but did not reveal any significant change. The aesthetic properties for cotton fabrics showed an improvement. Improvement in the anti-bacterial activity was observed for all the fabric samples but the improvement in cotton fabric is worth mentioning. Thus, nano treatment imparts anti-bacterial property without hampering the mechanical properties of the parent textiles. Research limitations/implications It is usual to find changes in the various properties of the materials subjected to nano treatment or treatment of any sort. Though the fabric samples were subjected to similar treatment, the quantity of nanoparticles taken up by each of them was different. The reason behind this could be the difference in the crystallinity of the fabric samples. Polyester fabric showed the highest resistance, as it was least affected by the nano treatment given. Cotton fabrics composed of cotton fibers are amorphous in nature, hence showed better take-up and hence were more affected by the said treatment. Practical implications Cotton fabrics are the most favored fabric, especially in regions with hot climatic conditions. Even though these fabrics are very sought after, they have a major drawback related to the aesthetic appeal of the fabric. These fabrics have very poor resistance to the crease formation, as well as their ability to recover from the external deformation. But the study conducted on the fabric samples has shown favorable results for the cotton fabric. A significant improvement in their aesthetic and anti-bacterial activity was found. At present, textiles with nano finishing fall in niche market due to its higher cost. But finishing with in-house Cu nanoparticles may open up hygiene textiles for consumers at affordable rates. Social implications Cotton is still the most popular natural fiber in most of the tropical and sub-tropical regions. People located in these places have a natural urge to wear fabrics made from cotton fibers. Due to the hot weather, sweating is natural. However, this tends to keep the skin in humid state resulting in various skin problems, as cotton is also prone to bacterial attack. But this work has shown positive results, meaning to say that cotton fabrics show improved resistance to the bacterial activity. Hence, its suitability for hygiene applications may soon become a reality. Originality/value It is true that a lot of work is being reported on nano materials and their application to textiles for various reasons. Recently, many reports are available related to finishing of textiles using nanoparticles. However, most of the researchers are using silver nanoparticles for the same. In this work, use of in-house Cu nanoparticles has been done to treat fabric samples, which is more economical than silver nano. Also quantity required to meet desired property with Cu nanoparticles is less than the conventional treatment. This work is a sincere attempt to prepare hygienic common textiles at economical rates using continuous application technique which offers durable efficacy against human pathogenic bacterium.


2018 ◽  
Vol 89 (12) ◽  
pp. 2376-2394 ◽  
Author(s):  
Suhyun Lee ◽  
Chung Hee Park

In this study, polypyrrole deposition and a superhydrophobic coating were applied to cotton fabrics to develop a self-cleaning and conductive fabric with electric heating performance. The binary oxidants ammonium peroxodisulfate and ferric chloride were introduced during the polymerization to adjust the size of the polypyrrole particles for creating diverse nano-scale roughness on the surface of the cotton fabrics and to prevent degradation in the mechanical properties of textiles. The in-situ polymerization of polypyrrole that introduced the binary oxidants succeeded in depositing polypyrrole particles on the surface of the cotton fabrics. Binary oxidants formed small polypyrrole particles contrary to the single oxidants. In terms of conductivity, the surface resistivity decreased as the FeCl3 ratio in the oxidants increased. The binary oxidants led to a similar level of conductivity even though the amount of polypyrrole deposition was less than that in the case of the single oxidant. The electrical heating performance improved as the surface resistance was decreased, resulting in an up to 20℃ increase in the surface temperature. On the other hand, the duration of the electro-heating effect was shorter with higher surface temperature. In terms of wettability, a superhydrophobicity with a contact angle of 150° or higher and a shedding angle of less than 10° was achieved under all oxidant conditions because of the nano-scale roughness caused by polypyrrole. Polypyrrole deposition reduced the tensile strength of the cotton fabric and increased its stiffness. The binary oxidants exhibited smaller changes in the mechanical properties of the textile than the single oxidants.


2020 ◽  
Vol 12 (5) ◽  
pp. 672-679
Author(s):  
Akepogu Prasad ◽  
Mallavarapu Umamahesh ◽  
Gopiredddy Venkata Subba Reddy ◽  
Seetha Jaswanth ◽  
Gollapudi Venkata Ramanamurthy ◽  
...  

Copper nanoparticles (CuNPs) were bio synthesized instantaneously in nanocomposite cotton fabrics (NCFs), utilizing aqueous Senna auriculata (SA) plant leaves solution as reductant. These NCFs with in situ generation of CuNPs were analyzed with different spectrophotometers such as Scanning Electron Microscope (SEM) combined with electron dispersive X-ray (EDX), Fourier transform infrared (FTIR), Thermogravimetric and Derivative thermogravimetric analysis (TGA and DTA), X-ray diffractometer (XRD) and Differential scanning calorimeter (DSC). The formed CuNPs were tested for their antibacterial and mechanical properties. The SEM results revealed that the bio synthesized CuNPs were spherical in shape and most of them with a mean size of 100 nm. The XRD studies explained the crystalline nature of CuNPs. These NCFs exhibited high thermal stability, good induced mechanical properties and acted as pathogenic killing agent against Gram positive and Gram negative bacteria. The Young's modulus value was found to be 65.81 MPa. The enhanced properties and immediate generation of CuNPs in NCFs can be utilized in medical applications such as antibacterial beds in hospitals, napkins and to make packing materials.


2015 ◽  
Vol 671 ◽  
pp. 285-292
Author(s):  
Wei Gou Dong ◽  
Qi Cui ◽  
Shu Dong Wang

ZnO nanoparticles were synthesized directly onto the surfaces, lumina, and cell walls of the cotton fibers at low temperature. Studies showed that the nanoZnO particles grown in cell walls of cotton fibers were globose particles with diameters around 40 nm, but those existing on the surfaces of cotton fibers were hexagonal sheeted crystalline solids and had higher crystallinity. Furthermore, UV-blocking characterization and the fastness to washing of the treated cotton fabrics were estimated. The results showed the treated fabrics provided an excellent UV protection factor rating of 50+ , and exhibited a high fastness to washing because nanoZnO particles were assembled in fibrous interiors .


2003 ◽  
Vol 778 ◽  
Author(s):  
Rajdip Bandyopadhyaya ◽  
Weizhi Rong ◽  
Yong J. Suh ◽  
Sheldon K. Friedlander

AbstractCarbon black in the form of nanoparticle chains is used as a reinforcing filler in elastomers. However, the dynamics of the filler particles under tension and their role in the improvement of the mechanical properties of rubber are not well understood. We have studied experimentally the dynamics of isolated nanoparticle chain aggregates (NCAs) of carbon made by laser ablation, and also that of carbon black embedded in a polymer film. In situ studies of stretching and contraction of such chains in the transmission electron microscope (TEM) were conducted under different maximum values of strain. Stretching causes initially folded NCA to reorganize into a straight, taut configuration. Further stretching leads to either plastic deformation and breakage (at 37.4% strain) or to a partial elastic behavior of the chain at small strains (e.g. 2.3% strain). For all cases the chains were very flexible under tension. Similar reorientation and stretching was observed for carbon black chains embedded in a polymer film. Such flexible and elastic nature of NCAs point towards a possible mechanism of reinforcement of rubber by carbon black fillers.


2018 ◽  
Vol 60 (12) ◽  
pp. 1221-1224 ◽  
Author(s):  
Balachandran Gobalakrishnan ◽  
P. Ramadoss Lakshminarayanan ◽  
Raju Varahamoorthi

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