Heat Release Rate and Effective Heat of Combustion Measurements: A Comparative Study of Thermal and Oxygen Consumption Techniques

1995 ◽  
Vol 13 (6) ◽  
pp. 482-499 ◽  
Author(s):  
Fatima Moussan ◽  
Jean-Louis Delfau ◽  
Christian Vovelle ◽  
Christian Pham Van Cang ◽  
Gérard Bosseboeuf

A new calorimeter especially built for the measurement of the heat release rate and effective heat of combustion of composite materials is pre sented. Two procedures can be used to obtain these data: the first one is based on the direct measurement of the convective and radiant heat liberated by the flame, the second involves oxygen consumption measurement. Preliminary ex periments were carried out with a gas burner to calibrate and check the inertia of the thermal method. In a second step, measurements were performed on PMMA and PVC samples. The results obtained with both methods are very similar and in agreement with literature values.

Author(s):  
Jozef Martinka ◽  
Peter Rantuch ◽  
Igor Wachter ◽  
Karol Balog

Abstract This paper deals with the fire risk of a selected halogen-free electrical cable. The research was objected to a three-core power electric cable for a fixed installation CHKE J3x1.5 (cross section of each copper core was 1.5 mm2) with a declared class of reaction to fire B2ca, s1, d1, a1. The electrical cable was manufactured and supplied by VUKI, a. s., Slovakia. The fire risk of the electric cable was evaluated based on the heat release rate, total heat release, smoke release rate, total smoke release and effective heat of combustion. These parameters were measured using a cone calorimeter at 50 kW m−2 (specimens and cone emitter were placed horizontally during the test). The measured electrical cable showed a maximum heat release rate of nearly 150 kW m−2, a maximum average heat emission rate of almost 100 kW m−2, a total heat release of almost 130 MJ m−2, a maximum smoke release rate of almost 2.5 s−1, a total smoke release of more than 800 m2 m−2, an effective heat of combustion (cable as a whole) of nearly 9 MJ kg−1 and an effective heat of emission (polymeric parts of the cable) of 26.5 MJ kg−1.


Polymers ◽  
2021 ◽  
Vol 13 (8) ◽  
pp. 1297
Author(s):  
Marouane El El Gazi ◽  
Rodolphe Sonnier ◽  
Stéphane Giraud ◽  
Marcos Batistella ◽  
Shantanu Basak ◽  
...  

In this study, a representative set of thermally thin materials including various lignocellulosic and synthetic fabrics, dense wood, and polypropylene sheets were tested using a cone calorimeter at different heat fluxes. Time-to-ignition, critical heat flux, and peak of heat release rate (pHRR) were the main parameters considered. It appears that the flammability is firstly monitored by the sample weight. Especially, while the burning rate of thermally-thin materials does never reach a steady state in cone calorimeter, their pHRR appears to be mainly driven by the fire load (i.e., the product of sample weight and effective heat of combustion) with no or negligible influence of textile structure. A simple phenomenological model was proposed to calculate the pHRR taking into account only three parameters, namely heat flux, sample weight, and effective heat of combustion. The model allows predicting easily the peak of heat release rate, which is often considered as the main single property informing about the fire hazard. It also allows drawing some conclusions about the flame retardant strategies to reduce the pHRR.


Author(s):  
Jiann C. Yang

The derivations of the formulas for heat release rate calculations are revisited based on the oxygen consumption principle. A systematic, structured, and pedagogical approach to formulate the problem and derive the generalized formulas with fewer assumptions is used. The operation of oxygen consumption calorimetry is treated as a chemical flow process, the problem is formulated in matrix notation, and the associated material balances using the tie component concept commonly used in chemical engineering practices are solved. The derivation procedure described is intuitive and easy to follow. Inclusion of other chemical species in the measurements and calculations can be easily implemented using the generalized framework developed here.


1984 ◽  
Vol 2 (5) ◽  
pp. 380-395 ◽  
Author(s):  
W.J. Parker

The calculation of heat release rate by oxygen consumption is based on the assumption that all materials release approximately the same amount of heat per unit mass of oxygen consumed. This technique is now being employed to determine the heat release rate of materials in various heat release rate cal orimeters. Other uses include the heat release rate of assemblies in the fire en durance furnaces and the total heat release rate in room fire tests. These dif ferent applications lead to different experimental procedures which require dif ferent formulas. The experimental choices or constraints include open or closed systems, paramagnetic or high temperature oxygen analyzers, CO2 analyzers or CO2 traps, and the use of a gas burner whose heat release rate must be deducted from the total. Various assumptions about CO levels in the exhaust duct and vitiation and humidity in the incoming air are made. General formulas for the heat release rate by oxygen consumption are developed in this paper from which the formulas for specific applications can easily be derived.


Wood Research ◽  
2021 ◽  
Vol 66 (6) ◽  
pp. 933-942
Author(s):  
ZHIGANG WU ◽  
XUE DENG ◽  
LIFEN LI ◽  
LIPING YU ◽  
JIE CHEN ◽  
...  

A high-efficiency fire retardant composition was prepared with dicyandiamide, phosphoric acid, boric acid, borax, urea and magnesium sulfate and it was used to process veneers which were then to prepare the plywood. Meanwhile, heat release and smoke release from combustion of plywood were tested by a cone calorimeter, including heat release rate, mass loss rate, CO yield, CO2 yield and oxygen consumption. Results showed that the plywood with this fire retardant treatment had the better flame-retardant performance and smoke suppression effect as well as the stronger char-forming capability compared to plywood without fire retardant treatment. The average heat release rate, total heat release, average effective heat of combustion, total smoke release, CO yield and oxygen consumption of the plywood with fire retardant treatment were decreased by 63.72%, 91.94%, 53.70%, 76.81%, 84.99% and 91.86%, respectively. Moreover, the fire growth index of plywood treated by fire retardant was relatively low (3.454 kW·m-2·s-1) and it took longer time to reach the peak heat release rate, accompanied with slow fire spreading. The fire performance index was relatively high (0.136 s·m2·kW-1) and it took longer time to be ignited, thus leaving a long time for escaping at fire accidents. The fire hazard of plywood with fire retardant treatment was low, and its safety level was high.


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