Nonlinear model predictive control applied to multivariable thermal and chemical control of selective catalytic reduction aftertreatment

2019 ◽  
Vol 20 (10) ◽  
pp. 1017-1024 ◽  
Author(s):  
Jonathan Sowman ◽  
Dina Shona Laila ◽  
Peter Fussey ◽  
Anthony Truscott ◽  
Andrew J Cruden

Manufacturers of diesel engines are under increasing pressure to meet progressively stricter NO x emission limits. A key NO x abatement technology is selective catalytic reduction in which ammonia, aided by a catalyst, reacts with NO x in the exhaust stream to produce nitrogen and water. The conversion efficiency is temperature dependent: at low temperature, reaction rates are temperature limited, resulting in suboptimal NO x removal, whereas at high temperatures, they are mass transfer limited. Maintaining sufficiently high temperature to allow maximal conversion is a challenge, particularly after cold start, as well as during conditions in which exhaust heat is insufficient, such as periods of low load or idling. In this work, a nonlinear model predictive controller simultaneously manages urea injection and power to an electric catalyst heater, in the presence of constraints.

Author(s):  
Liping Sheng ◽  
Songda Li ◽  
Zhaoxia Ma ◽  
Fei Wang ◽  
Hu He ◽  
...  

O2 greatly affected the pathway for NO reduction over the Pd/CeO2 catalyst and resulted in a temperature-dependent NH3-SCR performance and formation of N2O.


2016 ◽  
Vol 138 (37) ◽  
pp. 12025-12028 ◽  
Author(s):  
Kirill A. Lomachenko ◽  
Elisa Borfecchia ◽  
Chiara Negri ◽  
Gloria Berlier ◽  
Carlo Lamberti ◽  
...  

2020 ◽  
pp. 146808742093312
Author(s):  
Benjamin Pla ◽  
Pau Bares ◽  
Enrique Sanchis ◽  
André Aronis

This work presents an optimized ammonia injection strategy for the Worldwide Harmonized Light Vehicles Test Cycle and its potential benefits in terms of NO x emissions and ammonia consumption in selective catalytic reduction. An optimization tool based on optimal control was used to improve the ammonia injection in the selective catalytic reduction with different NO x emission limits. This optimal control can be used in two ways: one to minimize NO x emission and another to reduce the ammonia consumption in the selective catalytic reduction. The optimized strategy and the standard ammonia injection strategy were tested and compared on a fully instrumented engine test bench when applied in a Worldwide Harmonized Light Vehicles Test Cycle. The results showed a considerable improvement in the use of the optimization tool. When compared to the standard calibration, the new injection strategy for the same amount of ammonia injection reduced NO x emissions by 13.7%, and for the same NO x concentration emissions 33.5% of ammonia consumption was saved.


RSC Advances ◽  
2016 ◽  
Vol 6 (8) ◽  
pp. 6300-6307 ◽  
Author(s):  
Bo Li ◽  
Zhennan Huang ◽  
Xiaodong Huang ◽  
Shengzhong Kou ◽  
Fu Liu ◽  
...  

Highly dispersed FexOy clusters loaded on Fe-ZSM-5 with a Fe3+ concentration up to 22 wt% promoted the de-NOX activity with an efficiency of 91%. The reaction route was temperature dependent.


2020 ◽  
Vol 10 (16) ◽  
pp. 5525-5534 ◽  
Author(s):  
Jialiang Gu ◽  
Bingjun Zhu ◽  
Rudi Duan ◽  
Yan Chen ◽  
Shaoxin Wang ◽  
...  

MnOx–FeOx-Loaded silicalite-1 catalysts exhibit high NOx conversion at low temperatures.


2020 ◽  
Vol 7 (21) ◽  
pp. 3515-3520
Author(s):  
Wubing Yao ◽  
Jiali Wang ◽  
Aiguo Zhong ◽  
Shiliang Wang ◽  
Yinlin Shao

The selective catalytic reduction of amides to value-added amine products is a desirable but challenging transformation.


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