Bimodal Reaction Sequences Occurring through the Active Intermediates

Author(s):  
Robert Bakhtchadjian
Keyword(s):  
Joule ◽  
2021 ◽  
Vol 5 (4) ◽  
pp. 757-759
Author(s):  
Sophie H. van Vreeswijk ◽  
Bert M. Weckhuysen
Keyword(s):  

2016 ◽  
Vol 306 ◽  
pp. 483-509 ◽  
Author(s):  
Maria Oszajca ◽  
Alicja Franke ◽  
Małgorzata Brindell ◽  
Grażyna Stochel ◽  
Rudi van Eldik

2017 ◽  
Vol 4 (8) ◽  
pp. 1636-1639 ◽  
Author(s):  
Bin Cheng ◽  
Bian Bao ◽  
Yanhe Chen ◽  
Ning Wang ◽  
Yun Li ◽  
...  

A new route to arylhydrazides involving the reaction of two highly active intermediates, the 1,3-zwitterion generated in situ from the Mitsunobu reagent and arynes, under mild conditions has been developed.


Author(s):  
E. Bagyaraj ◽  
E. Vakees ◽  
M. Aboobucker Sithique

Versatile hybrid organic polymers are prepared using two active intermediates such as cynuric chloride and chitosan derivatives. The prepared chalcones are characterized by using FT-IR, UV, and proton NMR, thermal analysis and Minimum inhibitory Concentration. Thermal stability of the synthesized hybrid polymer is found using TGA and the hybrid chitosan derivative chalcone is thermally stable up to 270 °C. The antimicrobial activity of the prepared chitosan containing chalcone moiety are find out using Minimum Inhibitory Concentration (MIC) method. The synthesized versatile chalcone shows excellent antimicrobial activity against gram-negative bacteria such as Pseudomonas aeruginosa; and Gram-positive bacteria Chalcone containing halogen moiety shows high activity (MIC 7.8 µg/mL) than the hydroxyl containing chalcone. Cytotoxicity activity of the synthesized composites shows high activity.


2005 ◽  
Vol 24 (23) ◽  
pp. 5660-5664 ◽  
Author(s):  
Konstantin P. Bryliakov ◽  
Evgenii A. Kravtsov ◽  
Dale A. Pennington ◽  
Simon J. Lancaster ◽  
Manfred Bochmann ◽  
...  

2007 ◽  
Vol 2007 (6) ◽  
pp. 852-857 ◽  
Author(s):  
Eduard A. Duban ◽  
Konstantin P. Bryliakov ◽  
Evgenii P. Talsi

1969 ◽  
Vol 111 (4) ◽  
pp. 395-399 ◽  
Author(s):  
P. S. Dimick ◽  
N. J. Walker ◽  
Stuart Patton

1. Specific radioactivities of milk triglyceride fatty acids and γ- and δ-hydroxy fatty acids were measured after the intramammary infusion of [1−14C]acetate, δ-hydroxy[1−14C]laurate and [1−14C]laurate as their sodium salts into fed lactating goats. 2. Net incorporations of the radioactive tracer into the total milk lipids were comparable, being 16, 17 and 21% of the label infused respectively. 3. The specific radioactivities of the C4–C8 fatty acids after [1−14C]acetate infusion were lower than those of the C10–C14 fatty acids. 4. After δ-hydroxy[1−14C]laurate administration the milk triglyceride fatty acids were labelled and their specific radioactivities were characterized by decreasing values with increasing chain length of the fatty acids, implicating C4 unit incorporation. 5. The γ- and δ-hydroxy fatty acids isolated after [1−14C]laurate infusion were highly labelled and the milk triglyceride fatty acids, other than laurate, exhibited a labelling pattern similar to that of the fatty acids derived from the radioactive δ-hydroxy fatty acid. 6. Evidence is presented for the existence of saturated fatty acid δ-oxidation in the mammary gland, in which the γ- and δ-hydroxy fatty acids are active intermediates.


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