Characterization of Solid Acid Catalysts

2015 ◽  
pp. 97-156
2012 ◽  
Vol 509 ◽  
pp. 321-327 ◽  
Author(s):  
Zi Li Liu ◽  
Cui Xia Xu ◽  
Qian Wen Dai ◽  
Chao Xiang ◽  
Jian Jie Zhang

Supported H3PW12O40 (HPW) and supported Cesium-Substituted dodecatungsto-phosphate are eco-friendly solid acid catalysts. A series of different loading H3PW12O40/SiO2 and HPW/diatomite were prepared by a typical incipient wetness impregnation of methanol, meanwhile SiO2 and diatomite supported Cs-salt catalysts were prepared via two-step impregnating method. The catalysts were investigated by X-ray diffraction (XRD) and Fourier transform infrared spectroscopy (FT-IR). The results indicate that the Keggin structure of HPW is intact in the SiO2-supported HPW and SiO2-supported CsHPW. HPW and CsHPW are highly dispersed in the SiO2 at the low loading, while the loading is more than 40% the catalyst grains increase and gather on the surface of the carrier. What's more, diatomite is not a suitable support. HPW and CsHPW have better distribution in the SiO2 than in the diatomite. The activity of catalyst was tested in probe experiment of the alkylation of thiopene (TH) with 1-hexene.


1998 ◽  
Vol 37 (10) ◽  
pp. 3869-3878 ◽  
Author(s):  
Ajay K. Dalai ◽  
R. Sethuraman ◽  
Sai P. R. Katikaneni ◽  
R. O. Idem

2019 ◽  
Vol 12 (2) ◽  
pp. 433-442 ◽  
Author(s):  
Azeem Rana ◽  
Mohammed S. M. Alghazal ◽  
Mohammed M. Alsaeedi ◽  
Rashed S. Bakdash ◽  
Chanbasha Basheer ◽  
...  

2017 ◽  
Vol 727 ◽  
pp. 438-444
Author(s):  
Xiang Ying Hao ◽  
Yu Li Zhang ◽  
Guan Hua Shen ◽  
Wen Sheng Wu

SO42-/ Al-Fe-activated solid acid catalysts had been prepared in different conditions using cross-linking method, and characterized by XRD, BET, FTIR spectra and TG-DTA. The catalyst performed highly catalytic activity in the hydration of turpentine to α-terpineol.


ChemCatChem ◽  
2010 ◽  
Vol 3 (6) ◽  
pp. 1045-1050 ◽  
Author(s):  
Wu Zhou ◽  
Kevin F. Doura ◽  
Masashi Watanabe ◽  
Andrew A. Herzing ◽  
Eiji Okunishi ◽  
...  

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