Overscreening Induced by Ionic Adsorption at the Ionic Liquid/Electrode Interface Detected Using Neutron Reflectometry with a Rational Material Design

2021 ◽  
Author(s):  
Naoya Nishi ◽  
Junya Uchiyashiki ◽  
Tatsuro Oda ◽  
Masahiro Hino ◽  
Norifumi L. Yamada
Keyword(s):  
Ionic Liquid ◽  
Material Design ◽  
Neutron Reflectometry ◽  
Liquid Electrode ◽  
Ionic Adsorption ◽  
Electrode Interface

scholarly journals Simulation of a Solvate Ionic Liquid at a Polarisable Electrode with a Constant Potential

2018 ◽  
Author(s):  
Samuel W. Coles ◽  
Vladislav Ivanistsev
Keyword(s):  
Boundary Condition ◽  
Ionic Liquid ◽  
Ionic Liquids ◽  
Surface Charge ◽  
Computational Studies ◽  
Lithium Ions ◽  
Liquid Electrode ◽  
Constant Potential ◽  
Electrode Interface ◽  
Insight Into

<div>In this article we discuss the nanostructure and calculated the capacitance of a solvate ionic liquid–electrode interfaces, where the electrode has a constant potential, and is thus inherently polarisable. Lithium ions from the lithium</div><div>glyme solvate ionic liquid are found within 0.5 nm of the electrode at all voltages studied, however, their solvation environment varies with voltage. Our study provides molecular insight into the electrode interface of solvate ionic liquids, with many features similar to pure ionic liquids. A comparison with previous studies of the same electrolyte using the fixed surface charge boundary condition is also illuminating, informing future computational studies of electrolyte–electrode interfaces.</div>

Potential-Dependent Structure of the Ionic Layer at the Electrode Interface of an Ionic Liquid Probed Using Neutron Reflectometry

2019 ◽  
Vol 123 (14) ◽  
pp. 9223-9230 ◽  
Author(s):  
Naoya Nishi ◽  
Junya Uchiyashiki ◽  
Yoichi Ikeda ◽  
Seiji Katakura ◽  
Tatsuro Oda ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Neutron Reflectometry ◽  
Electrode Interface ◽  
Ionic Layer

scholarly journals Revealing the interfacial nanostructure of a deep eutectic solvent at a solid electrode

2020 ◽  
Vol 22 (21) ◽  
pp. 12104-12112 ◽  
Author(s):  
Nebojša Zec ◽  
Gaetano Mangiapia ◽  
Mikhail L. Zheludkevich ◽  
Sebastian Busch ◽  
Jean-François Moulin
Keyword(s):  
Molecular Dynamics ◽  
Ionic Liquid ◽  
Molecular Dynamics Simulations ◽  
Deep Eutectic Solvent ◽  
Neutron Reflectometry ◽  
Solid Electrode ◽  
Electrode Interface ◽  
Dynamics Simulations

The structure of an ionic liquid at an electrode interface was studied by a combination of neutron reflectometry measurements and molecular dynamics simulations.

Slow and fast capacitive process taking place at the ionic liquid/electrode interface

2012 ◽  
Vol 154 ◽  
pp. 303-311 ◽  
Author(s):  
Bernhard Roling ◽  
Marcel Drüschler ◽  
Benedikt Huber
Keyword(s):  
Ionic Liquid ◽  
Liquid Electrode ◽  
Electrode Interface
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