scholarly journals Normal Vibrations of Benzenesulfonate and Benzene-d5-sulfonate Ions

1975 ◽  
Vol 48 (8) ◽  
pp. 2231-2235 ◽  
Author(s):  
Toyozo Uno ◽  
Akio Kuwae ◽  
Yutaka Saito ◽  
Katsunosuke Machida
Keyword(s):  
1963 ◽  
Vol 19 (3) ◽  
pp. 669-674 ◽  
Author(s):  
G. Varsányi ◽  
S. Holly ◽  
T. Faragó

1979 ◽  
Vol 52 ◽  
pp. 1-11 ◽  
Author(s):  
Hiromu Murata ◽  
Hiroatsu Matsuura ◽  
Keiichi Ohno ◽  
Tsutomu Sato

2021 ◽  
pp. 1-14
Author(s):  
Ihor Vrublevskyi

Abstract Vibratory conveying of a material point by harmonic longitudinal and polyharmonic normal vibrations of an inclined conveying surface is considered. The dependence of dimensionless conveying velocity – a ratio of velocity to the product of frequency and amplitude of longitudinal vibration – on several dimensionless parameters is investigated in the moving modes without hopping. Maximal conveying velocity is achieved at the certain values of normal vibration amplitudes and phase difference angle between the longitudinal and normal vibrations, which are called optimal. Their values are dependent on two dimensionless parameters: the inclination angle parameter – a ratio of an inclination angle tangent to a frictional coefficient, the intensive vibration coefficient – a ratio of the longitudinal amplitude of vibration to the amplitude of the first harmonic of normal vibration and frictional coefficient. In a condition of the intensive longitudinal vibration, when its amplitude significantly greater than amplitudes of normal vibration, dimensionless velocity is almost independent of the intensive vibration parameter and it depends only on inclination angle parameter, i.e. on inclination angle and frictional coefficient. The optimal values of harmonics' amplitudes of polyharmonic normal vibration are determined in dependence of inclination angle parameter with the number of harmonics from 2 to 7. The graphs of considered dependencies are presented and the most important values of parameters are presented in the table. Conclusions are made to determine the optimal vibration parameters and the problems of further research are indicated. The considered vibrations can be used in different vibratory conveying devices with electromagnetic drives.


2020 ◽  
Vol 128 (8) ◽  
pp. 1077
Author(s):  
В.П. Булычев ◽  
М.В. Бутурлимова ◽  
К.Г. Тохадзе

The frequencies and intensities of IR absorption bands of symmetric and asymmetric H-bonded complexes [FL1FL2F]- (L1, L2 = K-meson Ka, proton H, deuton D, and triton T) are calculated. The equilibrium configuration and potential energy and dipole moment surfaces of isotopologues [FL1FL2F]- were calculated by the MP2/6-311++G(3df,3pd) method with the basis set superposition error taken into account. The calculations of spectral parameters with allowance for anharmonic interactions of all vibrations were carried out using the second-order vibrational perturbation theory. Variation of Li and L2 masses in wide regions allowed significant changes in the forms of normal vibrations and values of anharmonic interaction constants upon isotopic substitution to be obtained. The trends in the changes of spectral parameters were determined upon transition from one symmetric isotopologue to another and upon transition from symmetric to asymmetric isotopologues. The D-F stretching band frequency predicted for [FHFDF]- is in good agreement with the experimental value. The assignment of this band was improved.


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