Synthesis and Adsorption Property of Calixarene-p-sulfonate-intercalated Layered Double Hydroxides

2004 ◽  
Vol 33 (7) ◽  
pp. 790-791 ◽  
Author(s):  
Satoru Sasaki ◽  
Sumio Aisawa ◽  
Hidetoshi Hirahara ◽  
Akira Sasaki ◽  
Eiichi Narita
Keyword(s):  
Layered Double Hydroxides ◽  
Adsorption Property ◽  
Double Hydroxides

Adsorption Property of MgAl-NO3 Layered Double Hydroxides to Methyl Orange

2013 ◽  
Vol 750-752 ◽  
pp. 1738-1741
Author(s):  
Jian Hui Yan ◽  
Lu Hong Zhang ◽  
You Gen Tang ◽  
Li Zhang
Keyword(s):  
Methyl Orange ◽  
Adsorption Capacity ◽  
Hydrothermal Method ◽  
Layered Double Hydroxides ◽  
Adsorption Property ◽  
Molar Ratio ◽  
Adsorption Performance ◽  
Ft Ir ◽  
Double Hydroxides

MgAl-NO3 LDHs were prepared by hydrothermal method. The as-prepared samples were characterized by SEM, XRD and FT-IR. The adsorption performance of MgAl-NO3 LDHs to methyl orange (MO) was studied. The effects of Mg/Al molar ratio on the adsorption performance of MgAl-NO3 LDHs were investigated. The results showed that the highest adsorption capacity of 499.98mg/g was obtained when the Mg/Al molar ratio was at 2.5:1.

Study on Mn-Fe-LDH Material for Remediation of Arsenic Contaminated Water

2017 ◽  
Vol 730 ◽  
pp. 200-205 ◽  
Author(s):  
Wei Zhuo Wang ◽  
Jian Min Bian
Keyword(s):  
Layered Double Hydroxides ◽  
Arsenic Removal ◽  
Adsorption Property ◽  
Toxic Substances ◽  
Arsenic Adsorption ◽  
Exchange Method ◽  
Main Method ◽  
Series Of Experiments ◽  
Removal Of Arsenic ◽  
Double Hydroxides

Arsenical water pollution refers to the toxicity of arsenic. The form of trivalent arsenic has been seen as more toxic substances, which will be great improved by the manmade pollution. Compared with other technologies, adsorption is the main method of removal of arsenic pollution, for its higher efficiency and lower cost. Based on the adsorption theory and ion exchange method, the layered double hydroxides material containing ferric iron and manganese (Mn-Fe-LDH) was prepared to remove arsenic in this paper. We have designed some experiments for synthesis of this material. The reaction process and elemental compositions has been studied and the adsorption property of arsenic adsorption onto layered double hydroxides was verified through a series of experiments. Study shows that the Mn-Fe-LDH material can be used as a good adsorbent material for its high removal efficiency. The adsorption capacity of the Mn-Fe-LDH material is not affected by the interference of pH and Cl-/SO42- ion strength. It was a broad prospect for the development and application of arsenic removal materials.

Zn-Cr Layered Double Hydroxides Composites for Methyl Orange (MO) Absorption

2018 ◽  
Vol 281 ◽  
pp. 836-841
Author(s):  
Tao Zhou ◽  
Jian Ping Ai ◽  
Wei Xiu Liao ◽  
Li Hong Cheng ◽  
Yue Zhang ◽  
...  
Keyword(s):  
Methyl Orange ◽  
Layered Double Hydroxides ◽  
Adsorption Property ◽  
Bet Surface Area ◽  
Molar Ratio ◽  
Light Illumination ◽  
X Ray Diffraction ◽  
Anionic Dyes ◽  
Molar Ratios ◽  
Double Hydroxides

In this study, The Zn-Cr nanocomposite was synthesized using the hydrothermal method show good adsorption property. The as-prepared LDHs absorbent were characterized by Powder X-ray Diffraction (XRD), field emission scanning electron microscopy (FESEM), Fourier Transform Infrared (FT-IR), BET surface area, and simultaneously UV-visible spectrophotometer. The nanocomposites of Zn-Cr layered double hydroxides, the strong adsorptive adsorbents for anions. Zn-Cr LDHs with various Zn/Cr molar ratios for 2, 3, 4. The nanocomposites quickly adsorbed the anionic dyes such as methyl orange (MO) without the light illumination. The effects of Zn/Cr molar ratio on the adsorption performance of Zn-Cr LDHs were investigated.

Acceptorless amine dehydrogenation and transamination using Pd-doped layered double hydroxides

2018 ◽  
Author(s):  
Diana Ainembabazi ◽  
Nan An ◽  
Jinesh Manayil ◽  
Kare Wilson ◽  
Adam Lee ◽  
...  
Keyword(s):  
Layered Double Hydroxides ◽  
Oxidation States ◽  
Secondary Amines ◽  
Primary Amines ◽  
Acid Dissolution ◽  
Oxidative Amination ◽  
Strong Function ◽  
Excellent Activity ◽  
High Yields ◽  
Double Hydroxides

<div> <p>The synthesis, characterization, and activity of Pd-doped layered double hydroxides (Pd-LDHs) for for acceptorless amine dehydrogenation is reported. These multifunctional catalysts comprise Brønsted basic and Lewis acidic surface sites that stabilize Pd species in 0, 2+, and 4+ oxidation states. Pd speciation and corresponding cataytic performance is a strong function of metal loading. Excellent activity is observed for the oxidative transamination of primary amines and acceptorless dehydrogenation of secondary amines to secondary imines using a low Pd loading (0.5 mol%), without the need for oxidants. N-heterocycles, such as indoline, 1,2,3,4-tetrahydroquinoline, and piperidine, are dehydrogenated to the corresponding aromatics with high yields. The relative yields of secondary imines are proportional to the calculated free energy of reaction, while yields for oxidative amination correlate with the electrophilicity of primary imine intermediates. Reversible amine dehydrogenation and imine hydrogenation determine the relative imine:amine selectivity. Poisoning tests evidence that Pd-LDHs operate heterogeneously, with negligible metal leaching; catalysts can be regenerated by acid dissolution and re-precipitation.</p> </div> <br>

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