AbstractThe separation of Am(III) and Cm(III) by countercurrent chromatography (CCC) was achieved using the liquid phase systems "diamide–hydrogenated tetrapropylene (TPH)–HNOThe following diamide extractants have been studied: (i) N,N´-dimethyl-N,N´-dibutyltetradecylmalonamide (DMDBTDMA), (ii) N,N´-dimethyl-N,N´-dioctylhexyl-ethoxymalonamide (DMDOHEMA) and (iii) N,N´-dimethyl-N,N´-dibutyldodecylethoxymalonamide (DMDBDDEMA). It is shown that these diamides can be used for the separation of Am(III) and Cm(III) by CCC. Increasing the column length leads to an increase of the stationary phase retention on the column while improving the Am/Cm separation. Increasing the speed of rotation of the centrifuge from 660 to 950 rpm also results in increasing the stationary phase retention but does not influence the resolution of the Am/Cm separation. Decreasing the flow rate of the mobile phase from 1.0 to 0.5 mL/min leads to a better resolution of Am and Cm separation. The best Am/Cm separation was achieved with systems based on DMDBDDEMA and DMDOHEMA in TPH using a two-layer coil column and an isocratic elution mode. The application of CCC makes it possible to separate the elements within 100 min: the Cm fraction contains 99.5% of Cm(III) and 0.6% of Am(III) inventories and the Am fraction contains 99.4% of Am(III) and 0.5% of Cm(III).
Adsorption Studies of Metal Cations on a Silica Static Flat Bed Using Anionic Micellar Mobile-Phase Systems Containing Carboxylic Acids: Separation of Co-Existing Iron(III), Copper(II) and Nickel(II) Cations
