Stability Constants of Lanthanide Metal Ions Chelates with Substituted Pyrazoles in Different Solvents
2011 ◽
Vol 8
(1)
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pp. 131-136
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Keyword(s):
The reaction of Pr (III) and Nd (III) metal ions with some substituted pyrazoles, at 0.1M ionic strength and at 30 ± 0.10C in 70% acetone-water mixture and 70% propanol-water mixture have been studied pH-metrically. The data obtained were used to estimate the values of proton-ligand (pK) and metal-ligand (logK) stability constants in different solvents. It is observed that the pK and logK values in 70% propanol-water mixture are grater than in 70% acetone -water mixture. Pr (III) and Nd (III) metal ions formed 1:1 and 1:2 complexes with all the ligands in both solvent medium.
2012 ◽
Vol 6
(2)
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pp. 559-563
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Keyword(s):
2009 ◽
Vol 35
(12)
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pp. 932-937
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Keyword(s):
2003 ◽
Vol 68
(10)
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pp. 729-749
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1973 ◽
Vol 35
(3)
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pp. 849-854
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Keyword(s):
Keyword(s):
2015 ◽
Vol 89
(13)
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pp. 2346-2348
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1967 ◽
Vol 22
(9)
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pp. 922-924
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Keyword(s):