scholarly journals Synthesis and Spectral Characterization of Some New Novel Schiff bases Derived from Hydroxy Propiophenone

2021 ◽  
Vol 37 (3) ◽  
pp. 759-762
Author(s):  
Shaila Wagh ◽  
B.R. Patil
Keyword(s):  
Schiff Bases ◽  
Aromatic Amines ◽  
Uv Spectroscopy ◽  
Spectral Characterization ◽  
Resonance Spectroscopy ◽  
Melting Points ◽  
Schiff Base Ligands ◽  
Azomethine Group ◽  
New Novel

New Schiff bases derived by the condensation of methyl, chloro, and bromo substituted 2' hydroxy propiophenones with aliphatic and aromatic amines have been synthesized. The Schiff bases are yellow solids with sharp melting points. Schiff bases The spectral characterization of these newly synthesized Schiff base ligands has been done.These Schiff bases were characterized by IR spectroscopy, Nuclear magnetic resonance spectroscopy, UV spectroscopy, and Mass spectroscopy. IR spectra confirmed the presence of the phenolic OH group and azomethine group.

Synthesis and Spectral Characterization of Hydrazone Schiff Bases Derived from 2,4-Dinitrophenylhydrazine. Crystal Structure of Salicylaldehyde-2,4-Dinitrophenylhydrazone

2007 ◽  
Vol 62 (5) ◽  
pp. 717-720 ◽  
Author(s):  
Hassan Hosseini Monfared ◽  
Omid Pouralimardan ◽  
Christoph Janiak
Keyword(s):  
Crystal Structure ◽  
Schiff Base ◽  
Schiff Bases ◽  
Molecular Packing ◽  
Spectral Characterization ◽  
Monoclinic Space Group ◽  
Schiff Base Ligands ◽  
Space Group

Abstract Reactions of 2,4-dinitrophenylhydrazine with salicylaldehyde, pyridine-2-carbaldehyde and 2- aminobenzophenone in methanol result in the hydrazone Schiff base ligands salicylaldehyde-, pyridine- 2-carbaldehyde-, and 2-aminobenzophenone-2,4-dinitrophenylhydrazone, respectively. Crystals of salicylaldehyde-2,4-dinitrophenylhydrazone are monoclinic, space group P21/c, a = 13.820(3), b = 4.3515(9), c = 25.159(7) Å , β = 123.01(2)° with Z = 4. The molecular packing is mostly a zigzag or herring-bone pattern.

Synthesis and structural characterization of m-terphenyl Schiff base ligands and their aluminum complexes

2004 ◽  
Vol 82 (9) ◽  
pp. 1346-1352 ◽  
Author(s):  
Diane A Dickie ◽  
Hanifa Jalali ◽  
Rahul G Samant ◽  
Michael C Jennings ◽  
Jason AC Clyburne
Keyword(s):  
Schiff Base ◽  
Schiff Bases ◽  
Structural Characterization ◽  
Condensation Reaction ◽  
Schiff Base Ligands ◽  
X Ray ◽  
X Ray Crystallography ◽  
Aluminum Complexes

2,4,6-Triphenylbenzaldehyde 1 undergoes a condensation reaction with 2-aminophenol to give N-(2′,4′,6′-triphenylbenzylidene)-2-iminophenol (TPIP) 2. The imine 2 can be reduced with NaBH4 in ethanol to form N-(2′,4′,6′-triphenylbenzyl)-2-aminophenol (TPAP) 3. Addition of trimethylaluminum to 2 or 3 results in the formation of the complexes TPIP-AlMe2·AlMe3 (4) or TPAP-AlMe2 (5). Compounds 2, 3, and 4 have been crystallographically characterized.Key words: N,O ligands, aluminum, m-terphenyl, Schiff bases, X-ray crystallography.

scholarly journals Synthesis and Characterization of Five, Sevene Heterocyclic Membered Rings

2013 ◽  
Vol 10 (3) ◽  
pp. 803-817
Author(s):  
Baghdad Science Journal
Keyword(s):  
Biological Activity ◽  
Schiff Bases ◽  
13C Nmr ◽  
Starting Material ◽  
Synthesis And Characterization ◽  
Melting Points ◽  
Vis Spectroscopy ◽  
Ft Ir ◽  
New Compounds

New compounds containing heterocyclic units have been synthesized. These compounds include 2-amino 5- phenyl-1,3,4-thiadiazole (1) as starting material to prepare the Schiff bases 2N[3-nitrobenzylidene -2 hydroxy benzylidene and 4-N,N-dimethyl aminobenzylidene] -5-phenyl-1,3,4-thiadiazole (2abc) , 2N[3-nitrophenyl, 2-hydroxyphenyl or 4-N,N-dimethylaminophenyl] 3-]2-amino-5-phenyl-1,3,4-thiadiazole]-2,3-dihydro-[1,3]oxazepine-benzo-4,7-dione] (3abc), 2N[3-nitrophenyl,2-hydroxyphenyl,4-N,N-dimethylaminophenyl]-3-[2-amino-5-phenyl-1,3,4-thiadiazole-2-yl]-2,3-dihydro-[1,3]oxazepine-4,7-dione[(4abc), 2-N-[3-nitrophenyl, 2-hydroxyphenyl or 4-N,N-dimethylaminophenyl]-3-[2-amino-5-phenyl-1,3,4-thiadiazole-2yl]-1,2,3-trihydro-benzo-[1,2-e][1,3] diazepine-4,7-dione (5abc) ,2N[2-(3-nitrophenyl,2-hydroxyphenyl or 4-N,N-dimethylaminophenyl)]-4-oxo-1,3-thiazolidine-3-yl]-2-amino-5-phenyl-1,3,4-thiadiazole (6abc), 2-N-[5-(3-nitrophenyl,2-hydroxyphenyl or 4-N,N-dimethylaminophenyl)-tetrazolo-1-yl]-2-amino-5-phenyl-1,3,4-thiadiazole (7abc) , 2-N-[5-(3-nitrophenyl,2-hydroxyphenyl or 4-N,N-dimethylaminophenyl)-3-[2-amino-5-phenyl-1,3,4-thiadiazole-2-yl]-2,3-dihydro-[1,3]oxazepine-benzo-4,7-dithione (8abc) , 2-N-[5-(3-nitrophenyl,2-hydroxyphenyl or 4-N,N-dimethylaminophenyl)-3-[2-amino-5-phenyl-1,3,4-thiadiazole-2-yl]-2,3-dihydro-[1,3]oxazepine -4,7-dithione -5-ene (9abc) and 2-N-[5-(3-nitrophenyl,2-hydroxyphenyl or 4-N,N-dimethylaminophenyl)-3-[2-amino-5-phenyl-1,3,4-thiadiazole-2-yl] -1,2,3-trihydro-benzo-[1,2-e][1,3] diazepine -4,7-dithione - (10abc) . the structures of these compounds were characterized by FT-IR, 1H,13C-NMR,Uv/vis spectroscopy and the melting points were determined besides the evaluation of its biological activity.

Synthesis, spectral characterization of Co(II), Ni(II), Cu(II) and Zn(II) complexes of Schiff bases derived from 3-formyl quinoline and 2,6-diaminopyridine and their biological studies

2013 ◽  
Vol 12 (1) ◽  
pp. 87-104 ◽  
Author(s):  
Narayanachar ◽  
Shreedhar D. Dhumwad ◽  
Srinivas Mutalik ◽  
Mallinath H. Hugar ◽  
Praveen N. Naik
Keyword(s):  
Schiff Bases ◽  
Spectral Characterization ◽  
Biological Studies
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