Facile solvothermal synthesis of single-crystalline anatase nanorods for efficient dye-sensitized solar cells

2012 ◽  
Vol 85 (2) ◽  
pp. 417-425 ◽  
Author(s):  
Xiao Wang ◽  
Feng Hao ◽  
Huiyuan Chen ◽  
Gang Wang ◽  
Jianbao Li ◽  
...  

Single-crystalline anatase TiO2 nanorods (TiO2-SANRs) were synthesized through a facile solvothermal method and successfully applied as the photoanodes for efficient dye-sensitized solar cells (DSCs). The prepared samples were characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), and X-ray diffraction (XRD). The power conversion efficiencies of TiO2-SANRs decorated Degussa P25 nanoparticle solar cells increased by 13.5 % compared with commercial Degussa P25 TiO2 solar cells under standard illumination conditions (AM 1.5G, 100 mW/cm–2). The improved performance of the TiO2-SANRs decorated Degussa P25 nanoparticle solar cells was primarily ascribed to the enhanced short-circuit photocurrent density (Jsc) despite a declined dye-loading capacity. The light-scattering effect in the long-wavelength region, as evidenced from the incident photon-to-current conversion efficiency (IPCE) response and the diffuse reflectance spectroscopy was recognized as the main reason for the photocurrent enrichment.

2010 ◽  
Vol 1270 ◽  
Author(s):  
Xu Wang ◽  
Haiyou Yin ◽  
Bao Wang ◽  
Lifeng Liu ◽  
Yi Wang ◽  
...  

AbstractA novel ZnO/TiO2 assorted photoelectrode for dye-sensitized solar cells (DSSCs) is proposed. The impacts of the ZnO/TiO2 assorted photoelectrode on the photovoltaic performance of dye-sensitized solar cells (DSSCs) were investigated. The measurements of the light transmission spectra showed the higher transmittance through ZnO/FTO than through FTO during the effective wavelength region of 536nm˜800nm for DSSCs, indicating that ZnO/TiO2 assorted photoelectrode is beneficial for the photovoltaic performance of DSSCs. The measurements on the photovoltaic characteristics of the DSSC cell indicate that the inserted ZnO layer can cause the increased open circuit voltage (Voc) more than 70 mV and fill factor (FF) but the decreased short circuit current. The enhanced Voc and FF could be attributed to the suppressed the recombination of photon-generated carriers between the ZnO/TiO2 assorted photoelectrode and electrolyte (dye) compared to TiO2 photoelectrode. However, the additional series resistance of inserted ZnO layer causes the reduced short circuit current. The optimized conversion efficiency can be achieved in the DSSC with ZnO/TiO2 assorted photoelectrode by using low series resistance of ZnO layer.


2011 ◽  
Vol 2011 ◽  
pp. 1-8 ◽  
Author(s):  
Chanu Photiphitak ◽  
Pattana Rakkwamsuk ◽  
Pennapa Muthitamongkol ◽  
Chaiyuth Sae-Kung ◽  
Chanchana Thanachayanont

Titanium dioxide/silver (TiO2/Ag) composite films were prepared by incorporating Ag in pores of mesoporous TiO2films using a photoreduction method. The Ag nanoparticle sizes were in a range of 4.36–38.56 nm. The TiO2/Ag composite films were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The TiO2and TiO2/Ag composite films were then sensitized by immersing in a 0.3 mM N719 dye solution and fabricated for conventional dye-sensitized solar cells (DSCs).J-Vcharacteristics of the TiO2/Ag DSCs showed that the Ag nanoparticle size of 19.16 nm resulted in the short circuit current density and efficiency of 8.12 mA/cm2and 4.76%.


Author(s):  
Jinchu I ◽  
Jyothi R ◽  
N Pandurangan ◽  
Sreelatha KS ◽  
Krishnashree Achuthan ◽  
...  

<p>Natural dye sensitized solar cells are a promising class of photovoltaic cells with the capacity of generating green energy at low production cost since no expensive equipment is required in their fabrication. Photovoltaics are a precious technology in the hasty world where energy prices are goes on increasing within seconds. Researchers are focusing to facilitate for producing eco-friendly, low cost and more efficient dye sensitized solar cells. In the present work we discuss the comparative photovoltaic studies of Lawsone, a natural dye from henna plant and Alizarin, a natural dye from the root of madder for fabricating the Dye sensitized solar cells (DSSCs). The absorption spectrum of Lawsone and Alizarin is found to be shifted to the longer wavelength region after the complex formation. As a result there is a significant increase in short circuit current density and conversion efficiency. This result compares with the standard dye i.e. N719 dye.</p>


Author(s):  
Jinchu I ◽  
Jyothi R ◽  
N Pandurangan ◽  
Sreelatha KS ◽  
Krishnashree Achuthan ◽  
...  

<p>Natural dye sensitized solar cells are a promising class of photovoltaic cells with the capacity of generating green energy at low production cost since no expensive equipment is required in their fabrication. Photovoltaics are a precious technology in the hasty world where energy prices are goes on increasing within seconds. Researchers are focusing to facilitate for producing eco-friendly, low cost and more efficient dye sensitized solar cells. In the present work we discuss the comparative photovoltaic studies of Lawsone, a natural dye from henna plant and Alizarin, a natural dye from the root of madder for fabricating the Dye sensitized solar cells (DSSCs). The absorption spectrum of Lawsone and Alizarin is found to be shifted to the longer wavelength region after the complex formation. As a result there is a significant increase in short circuit current density and conversion efficiency. This result compares with the standard dye i.e. N719 dye.</p>


RSC Advances ◽  
2016 ◽  
Vol 6 (87) ◽  
pp. 83802-83807 ◽  
Author(s):  
Yu Hou ◽  
Shuang Yang ◽  
Chunzhong Li ◽  
Huijun Zhao ◽  
Hua Gui Yang

An energy conversion efficiency of 8.31% is reached by using a cemented photoanode for dye-sensitized solar cells, attaining a 31.1% improvement over the standard Degussa P25 sample.


2018 ◽  
Vol 382 ◽  
pp. 369-373
Author(s):  
Usana Mahanitipong ◽  
Preeyapat Prompan ◽  
Rukkiat Jitchati

The four thiocyanate free ruthenium(II) complexes; [Ru(N^N)2(C^N)]PF6were synthesized and characterized for dye sensitized solar cells (DSSCs). The results showed that the broad absorptions covered the visible region from metal to ligand charge transfer (MLCT) were obtained with the main peaks at 560, 490 and 400 nm. The materials were studied DSSC performance under standard AM 1.5. Compound PP1 showed the power conversion efficiency (PCE) at 3.10%, with a short-circuit photocurrent density (Jsc) of 7.99 mA cm-2, an open-circuit photovoltage (Voc) of 563 mV and a high fill factor (ff) of 0.690.


Solar Energy ◽  
2011 ◽  
Vol 85 (11) ◽  
pp. 2697-2703 ◽  
Author(s):  
Jiang Sheng ◽  
Linhua Hu ◽  
Wenxin Li ◽  
Li’e Mo ◽  
Huajun Tian ◽  
...  

Energies ◽  
2018 ◽  
Vol 11 (11) ◽  
pp. 2922 ◽  
Author(s):  
Zainal Arifin ◽  
Suyitno Suyitno ◽  
Syamsul Hadi ◽  
Bayu Sutanto

In this study, dye-sensitized solar cells (DSSCs) were fabricated using double-layer photoanodes consisting of TiO2 nanoparticles (NPs) and Zn-doped TiO2 hollow fibers (HFs). The TiO2 HFs were prepared by co-axial electrospinning and used as the light-scattering layer in the DSSC. The thickness variations of the TiO2 NP and Zn-doped TiO2 HF photoanode layers affect the performance of the DSSC, especially the short-circuit photocurrent density. The thickness of the TiO2 NP layer significantly affected the absorbance of photons and N719 dye molecules in the double-layer photoanode, while that of the Zn-doped TiO2 HF layer affected the scattering of light, as indicated by the low light transmittance in the photoanode. Conventional DSSCs consist of single-layer photoanodes, and exhibit relatively low efficiency, i.e., 1.293% and 0.89% for TiO2 NP and Zn-doped TiO2 HF, respectively. However, herein, the highest efficiency of the DSSC (3.122%) was achieved with a 15 μm NP-5 μm HF photoanode, for which the short-circuit photocurrent density, open-circuit photovoltage, and fill factor were 15.81 mA/cm2, 0.566 V, and 34.91%, respectively.


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