The reaction mechanism of plasmonic photocatalytic NO oxidation on Bi-metal/BiPO&lt;sub&gt;4&lt;/sub&gt;

Abstract A process capable of NOx control by ozone injection gained wide attention as a possible alternative to proven post combustion technologies such as selective catalytic (and non-catalytic) reduction. The purpose of the work was to develop a numerical model of NO oxidation with O3 that would be capable of providing guidelines for process optimisation during different design stages. A Computational Fluid Dynamics code was used to simulate turbulent reacting flow. In order to reduce computation expense a 11-step global NO - O3 reaction mechanism was implemented into the code. Model performance was verified by the experiment in a tubular flow reactor for two injection nozzle configurations and for two O3/NO ratios of molar fluxe. The objective of this work was to estimate the applicability of a simplified homogeneous reaction mechanism in reactive turbulent flow simulation. Quantitative conformity was not completely satisfying for all examined cases, but the final effect of NO oxidation was predicted correctly at the reactor outlet.

Download Full-text

Influence of NH3 and NO oxidation on the SCR reaction mechanism on copper/nickel and vanadium oxide catalysts supported on alumina and titania

Catalysis Today ◽

10.1016/s0920-5861(02)00055-x ◽

2002 ◽

Vol 75 (1-4) ◽

pp. 331-338 ◽

Cited By ~ 56

Author(s):

Silvia Suárez ◽

Seong Moon Jung ◽

Pedro Avila ◽

Paul Grange ◽

Jesús Blanco

Keyword(s):

Reaction Mechanism ◽

Vanadium Oxide ◽

Oxide Catalysts ◽

No Oxidation ◽

Copper Nickel

Download Full-text

A quantum chemical study of the structure of O=NO-ON=O peroxide and the reaction mechanism of no oxidation in the gas phase

Journal of Structural Chemistry ◽

10.1134/s0022476612010015 ◽

2012 ◽

Vol 53 (1) ◽

pp. 1-11 ◽

Cited By ~ 4

Author(s):

I. I. Zakharov ◽

B. F. Minaev

Keyword(s):

Reaction Mechanism ◽

Gas Phase ◽

Quantum Chemical ◽

Quantum Chemical Study ◽

Chemical Study ◽

No Oxidation

Download Full-text

Catalytic performance and reaction mechanism of NO oxidation over Co3O4 catalysts

Applied Catalysis B Environmental ◽

10.1016/j.apcatb.2019.118371 ◽

2020 ◽

Vol 267 ◽

pp. 118371 ◽

Cited By ~ 7

Author(s):

Lei Ma ◽

Wei Zhang ◽

Yang-Gang Wang ◽

Xiaoyin Chen ◽

Weiting Yu ◽

...

Keyword(s):

Reaction Mechanism ◽

Catalytic Performance ◽

No Oxidation

Download Full-text

In-Situ DRIFTS for Reaction Mechanism and SO2 Poisoning Mechanism of NO Oxidation Over γ-MnO2 with Good Low-Temperature Activity

Catalysis Letters ◽

10.1007/s10562-018-2635-6 ◽

2018 ◽

Vol 149 (3) ◽

pp. 753-765 ◽

Cited By ~ 4

Author(s):

Hu Chen ◽

Ying Wang ◽

Yong-Kang Lyu

Keyword(s):

Reaction Mechanism ◽

Low Temperature ◽

No Oxidation ◽

In Situ Drifts ◽

So2 Poisoning

Download Full-text

Arylation of enelactams using TIPSOTf: reaction scope and mechanistic insight

Organic Chemistry Frontiers ◽

10.1039/d0qo01396j ◽

2021 ◽

Author(s):

Tomasz J. Idzik ◽

Zofia M. Myk ◽

Łukasz Struk ◽

Magdalena Perużyńska ◽

Gabriela Maciejewska ◽

...

Keyword(s):

Reaction Mechanism ◽

Multinuclear Nmr ◽

Mechanistic Insight ◽

Nmr Study ◽

Wide Range

Triisopropylsilyltrifluoromethanesulfonate can be effectively used for the arylation of a wide range of enelactams. The multinuclear NMR study provided deep insights into the reaction mechanism.

Download Full-text