The influence of blowing agents type on foaming process and properties of rigid polyurethane foams

Polimery ◽  
2018 ◽  
Vol 63 (10) ◽  
pp. 672-678 ◽  
Author(s):  
Maria Kuranska ◽  
Aleksander Prociak ◽  
Slawomir Michalowski ◽  
Karolina Zawadzinska
Polimery ◽  
2003 ◽  
Vol 48 (07/08) ◽  
pp. 565-567
Author(s):  
ALEKSANDER PROCIAK ◽  
MARCIN FIGURA

2011 ◽  
Vol 374-377 ◽  
pp. 1563-1566
Author(s):  
An Zhen Zhang ◽  
Yi He Zhang

Rigid polyurethane foams were excellent thermal insulation materials with widely used, which was highly flammable at the same time. In order to obtain safe application, flame retarded polyurethane foams were needed. In this paper, series flame retarded rigid polyurethane foams were prepared with loading different flame retardants such as ammonium polyphosphate, expandable graphite, red phosphorus, Tri (2-chloroethyl) phosphate and dimethyl methylphosphonate. The effects of flame retardants on the foaming-process and flame retardant property of the rigid polyurethane foams were investigated by otary viscometer and limiting oxygen index. The results showed that the combination of solid and liquid flame retardants was necessary to improve the flame retardant and different flame retardants played synergistic roles in rigid polyurethane foams. The limiting oxygen indexes of the foams could be up to 30wt% and 29.6% with 25wt% solid flame retardants and 10wt% liquid retardants, respectively.


2004 ◽  
Vol 36 (5) ◽  
pp. 368-373 ◽  
Author(s):  
Kun Hyung Choe ◽  
Dong Soo Lee ◽  
Won Jin Seo ◽  
Woo Nyon Kim

2020 ◽  
Vol 135 ◽  
pp. 109884
Author(s):  
Paula Cimavilla-Román ◽  
Saul Pérez-Tamarit ◽  
Mercedes Santiago-Calvo ◽  
Miguel Ángel Rodríguez-Pérez

1994 ◽  
Vol 30 (2) ◽  
pp. 126-143 ◽  
Author(s):  
P.L. Bartlett ◽  
J.A. Creazzo ◽  
H.S. Hammel

Polymer ◽  
2002 ◽  
Vol 43 (24) ◽  
pp. 6471-6479 ◽  
Author(s):  
Zhong Tang ◽  
M.Mercedes Maroto-Valer ◽  
John M Andrésen ◽  
John W Miller ◽  
Mark L Listemann ◽  
...  

Polymers ◽  
2021 ◽  
Vol 14 (1) ◽  
pp. 102
Author(s):  
Marcin Zemła ◽  
Aleksander Prociak ◽  
Sławomir Michałowski

Rigid polyurethane foams (RPURF) containing a bio-polyol from rapeseed oil and different phosphorus-based flame retardants were obtained. Triethyl phosphate (TEP), dimethyl propane phosphonate (DMPP) and cyclic phosphonates Addforce CT 901 (20 parts per hundred polyol by weight) were used in the synthesis of RPURF. The influence of used flame retardants on foaming process, cell structure, and physical–mechanical properties as well as flammability of RPURF were examined. The addition of flame retardants influenced the parameters of the cellular structure and decreased compressive strength. All obtained foam materials had a low thermal conductivity coefficient, which allows them to be used as thermal insulation. The research results of bio-based RPURF were compared with foams obtained without bio-polyol. All modified materials had an oxygen index above 21 vol%; therefore, they can be classified as self-extinguishing materials. The analysis of parameters obtained after the cone calorimeter test showed that the modified RPURF have a lower tendency to fire development compared to the reference foams, which was particularly noticeable for the materials with the addition of DMPP.


2017 ◽  
Vol 134 (48) ◽  
pp. 45582 ◽  
Author(s):  
Guangyu Zhang ◽  
Qinqin Zhang ◽  
Yumin Wu ◽  
Huan Zhang ◽  
Jingqiang Cao ◽  
...  

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